• Title/Summary/Keyword: Liquefaction process

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Liquefaction and Saccharification of Starch Using $\alpha$-Amylase and Immobilized Glucoamylase ($\alpha$-아밀레이즈와 고정화된 글루코아밀레이즈를 이용한 전분의 액화 및 당화)

  • 안대희;장호남
    • Microbiology and Biotechnology Letters
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    • v.19 no.5
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    • pp.497-503
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    • 1991
  • The catalytic activities of immobilized gIucoamylase in a packed bed column and a continuous stirred tank reactor have been compared. Rapid production of glucose from liquefied starch have been studied through, the continuous liquefaction and saccharification using settling chamber. The immobilized glucoamylase with chitin gave the saccharification yield of 20% with the dextrin concentration of 100 g/l in a residence of 20 min. in a packed bed column. The half-life of immobilized glucoamylase with chitin was 19 days. The glucoamyalse immobilized in chitin and encapsulated with Ca-alginate gave the saccharification yield of 6% with the dextrin concentration of 50 g/l in a residence of 20 min. in a packed bed column. The Ca-alginate encapsulated and chitin immobilized glucomylase had a half-life of 25 days, which is 6 day larger than that of the immobilized glucoamylase with chitin only. In continuous liquefaction and saccharification, the glucose yield was 17% for the liquefied starch with naked barley concentration of 50gA in a residence of 20 min.

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Experimental Study on the Effect of Particle Size Distribution of Soil on the Liquefaction Resistance Strength (입도분포가 액상화 저항강도에 미치는 영향에 관한 실험적 연구)

  • Seo Kyung-Bum;Choi Mun-Gyu;Kim Soo-Il;Park Inn-Joon
    • Journal of the Korean Geotechnical Society
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    • v.21 no.7
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    • pp.13-20
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    • 2005
  • For experimental study on the effect of particle size distribution on the liquefaction resistance strength, particle size distribution curves of the dredged soil were investigated. In this process, four mean particle sizes and three uniformity coefficients were defined representatively and twelve representative particle size distribution curves which have different mean particle size and uniformity coefficient, were defined and manufactured by using the real dredged river soil. Cyclic triaxial tests and resonant column tests were carried out to analyze the effect of mean particle size and uniformity coefficient on the liquefaction resistance strength and dynamic characteristics.

Gas Hydrate Supply Chain analyses of economy for the natural gas transportation (천연가스 수송을 위한 Gas Hydrate Supply Chain의 경제성 분석)

  • Kim, Cheoulho;Lee, Jaeik;Jeong, Taeseok
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.151.1-151.1
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    • 2010
  • Natural gas hydrates (NGH) provide 170 gas volumes per unit volume of the medium and are easier to make with moderate pressure and temperature (40 bar at 3 C). Once they form, their preservation temperature is 20 C at 1 bar, which is much milder than the LNG preservation. In case of using the NGH, The small and medium sized gas well has advantages for development because of NGH's these characteristics. According to the cost evaluation report of Gudmundsson in Norway and the research of MES in Japan, the gas well that uses the NGH has a cost saving effect about 10~20% compared LNG. The effect depends on distance and production. However, cost saving and efficiency of liquefaction process is increased by the development of LNG liquefaction technology. Therefore, these factors have to be reflected in economic analysis. The purpose of this research is to compare the cost of Gas Supply Chain according to the transport type, distance and gas reserves. Especially, we consider not only the cost of facility but also the total cost (production cost, transport cost, etc).

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Analysis of Pure Refrigerant Cycle Design on C3MR Process through Driver Selection (동력 공급 장치 선택을 통한 C3MR 공정의 순수냉매 사이클 설계 분석)

  • Lee, Inkyu;Tak, Kyungjae;Lim, Wonsub;Moon, Il;Kim, Haksung;Choi, Kwangho
    • Journal of the Korean Institute of Gas
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    • v.17 no.3
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    • pp.27-32
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    • 2013
  • Natural gas liquefaction process which is operated under cryogenic condition spends large amount of energy. Most of energy in the natural gas liquefaction process is consumed by compressors. Therefore, minimizing energy consumption of compressors is an important issue in process design and operation. Among various natural gas liquefaction processes, propane pre-cooled mixed refrigerant (C3MR) process consists of mixed refrigerant system and pure refrigerant system. In this study, to find the optimal design of pure refrigerant system, pure refrigerant cycle is simulated on different number of pressure levels and the necessary energy of each design is compared. After that, the driver selection model is applied to analyse each processes, which has different number of equipments, in terms of cost. As the result, the design using many equipments spends lower energy. Using this result, this study suggests standard of process design selection by the cost term.

Economic Assessment of a Indirect Liquefaction Process using a Gasification with Petroleum Coke/Coal Mixtures (석유코크스/석탄 혼합 가스화를 이용하는 액화 공정의 경제성 평가)

  • Shin, Ji-Hoon;Lee, Lu-Se;Lee, See-Hoon
    • Korean Chemical Engineering Research
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    • v.54 no.4
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    • pp.501-509
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    • 2016
  • The economic feasibility of a commercial indirect liquefaction process with the co-gasification process of petroleum coke which has been recognized as hazardous waste because of high sulfur content and bituminous coal and sub-bituminous coal mixtures was assessed. The 2,000 ton/day scale indirect liquefaction process including co-gasification, clean up, Fischer-Tropsch conversion and so on was assumed and used to analyze economical efficiencies with various conditions. Financial data from previous studies were modified and used and economical sensitivities with various mixture ratios were evaluated in this study. As a result, economic values of petroleum coke were superior than those of coals because of increasing sulfur sale. Also, mixtures with petroleum coke and bituminous coal was more favorable that those with petroleum coke and sub-bituminous coal due to lower moisture content. In case of sub-bituminous coal, the mixture ratio with petroleum coke had to be over 40wt% for the IRR of mixture to surpass 10%.

Effect of Residual Shear Strain on the Relationship between Volumetric Strain and Effective Stress after Liquefaction (액상화 후 잔류전단변형률이 체적변형률과 유효응력 관계에 미치는 영향)

  • Kwon, Youngcheul
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.11
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    • pp.55-62
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    • 2010
  • The settlements by liquefaction seldom occur uniformly because of soil homogeneity, however differential settlements are major cause of the damages to structures. From the past researches, author paid attention to the fact that stress history during undrained cyclic shear process affects greatly on the volumetric strains of the post-liquefaction. Therefore, the effect of the residual shear strain in cyclic shear process was examined in this study. The experiment apparatus based on strain control with volumetric strain control device was used for the study to investigate the effect of the residual strain on the relationship between volumetric strain and effective stress of clean and granite sandy soil. It could be seen an insignificant difference in the volumetric strain after liquefaction under various residual shear strain conditions in the case of clean sand. On the other hand, in granite sandy soil, the volumetric strain after liquefaction was small when the lower level of the residual shear strain was applied. And, the residual shear strain during cyclic shear affected the shape of the relation curve between effective stress and volumetric strain as well.

Effect of Hardening of Granulated Blast Furnace Slag on the Liquefaction Strength (고로 수쇄슬래그의 경화가 액상화 강도에 미치는 영향)

  • Baek, Won-Jin
    • Journal of the Korean Geotechnical Society
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    • v.22 no.8
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    • pp.99-106
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    • 2006
  • In the present study, in order to clarify the effects of latent hydraulic property of granulated blast furnace slag (GBF slag) on the liquefaction, GBF slag was cured in the high temperature alkali water (adding the calcium hydroxide, pH=12, water temperature is about $30^{\circ}C$), and then the cyclic and the static tri-axial compression tests were carried out. Then the results were compared with those for Japanese standard sand of Toyoura sand and natural sand of Genkai sand. From the test results, it is clarified that the liquefaction strength of the GBF slag increases with the increase of the curing period by the hardening due to the latent hydraulic property. It is also shown that GBF slag with Dr=50% and 80% which was cured for 189 days in the fresh-water shows cohesion due to developing of latent hydraulic property. In addition, as for the liquefaction strength of GBFS during the hardening process, a linear relation between the cyclic stress ratio $R_{20}$ at the number of stress cycles Nc=20 and cohesion $C_{d}$ was observed. It is also clarified that the liquefaction strength for cured GBF slag in the high temperature alkali water is predicted by the cohesive strength or the unconfined compressive strength.

Process Development of Pyrolysis Liquefaction for Waste Plastics (폐플라스틱의 열분해 유화기술 개발)

  • Nho Nam-Sun;Shin Dae-Hyun;Park Sou-Won;Lee Kyong-Hwan;Kim Kwang-Ho;Jeon Sang-Goo;Cho Bong-Gyu
    • New & Renewable Energy
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    • v.2 no.2 s.6
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    • pp.118-125
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    • 2006
  • The target of this work was the process development of demonstration plant to produce the high quality alternative fuel oil by the pyrolysis of mixed plastic waste. In the first step of research, the bench-scale units of 70 t/y and the pilot plant of 360 t/y had been developed. Main research contents in this step were the process performance test of pilot plant of 360 ton/year and the development of demonstration plant of 3,000 t/y, which was constructed at Korea R & D Company in Kimjae City. The process performance of pilot plant of 360 t/y showed about 80% yield of liquid product, which was obtained by both light gas oil(LGO) and heavy gas oil(HGO), The boiling point range distribution of LO product that was mainly consisting of olefin components in PONA group appeared at between that of commercial gasoline and kerosene. On the other hand, HO product was mainly paraffin and olefin components and also appeared at upper temperature distribution range than commercial diesel. Gas product showed a high fraction of $C_3\;and\;C_4$ product like LPG composition, but also a high fraction of $CO_2$ and CO by probably a little leak of process.

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Process Development of Pyrolysis Liquefaction for Waste Plastics (폐플라스틱의 열분해 유화기술 개발)

  • Nho, Nam-Sun;Shin, Dae-Hyun;Park, Sou-Won;Lee, Kyong-Hwan;Kim, Kwang-Ho;Jeon, Sang-Goo;Cho, Bong-Gyu
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.523-526
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    • 2006
  • The target of this work was the process development of demonstration plant to produce the high quailty alternative fuel oil by the pyrolysis of mixed plastic waste. In the first step of research, the bench-scale units of 70t/y and the pi lot plant of 360 t/v had been developed. Main research contents in this step were the process performance test of pilot plant ot 360ton/year and the development of demonstration plant of 3 000 t/y which was constructed at Korea R & D Company in Kimjae City. The process performance of pilot plant of 360 t/v showed components in PONA group appeared at between that of commercial gasoline and kerosene. On the other hand, HO product was mainly paraffin and olefin components and also appeared at upper temperature distribution range than commercial diesel. Gas product showed a high fraction of $C_3\;and\;C_4$ product like LPG composition, but also a high fraction of $CO_2$ and CO by probably a little leak of process.

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Case Studies for SMR Natural Gas Liquefaction Plant by Capacity in Small Scale Gas Wells through Cost Analysis (소규모 가스전 규모에 따른 SMR 천연가스 액화 플랜트 용량별 비용 분석 사례연구)

  • Lee, Inkyu;Cho, Seungsik;Lee, Seungjun;Moon, Il
    • Journal of the Korean Institute of Gas
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    • v.20 no.3
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    • pp.46-51
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    • 2016
  • Natural gas liquefaction process which spends a huge amount energy is operated under cryogenic conditions. Thus, many researchers have studied on minimizing energy consumption of LNG plant. However, a few studied for cost optimization have performed. This study focused on the cost analysis for the single mixed refrigerant (SMR) process, one of the simplest natural gas liquefaction process, which has different capacity. The process capacity is increased from 1 million ton per annum (MTPA) to 2.5 MTPA by 0.5 MTPA steps. According to the increase of plant size, only flow rate of natural gas and mixed refrigerant are increased and other operating conditions are fixed. Aspen Economic Evaluator(v.8.7) is used for the cost analysis and six tenths factor rule is applied to obtain multi stream heat exchanger cost data which is not supplied by Aspen Economic Evaluator. Moreover, the optimal plant sizes for different sizes of gas wells are found as the result of applying plant cost to small scale gas wells, 20 million ton (MT), 40 MT, and 80 MT. Through this cost analysis, the foundation is built to optimize LNG plant in terms of the cost.