• 한국가스학회지
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• 제19권4호
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• pp.8-14
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• 2015

화학산업에서 다양하게 사용되고 있는 2-methyl-1-butanol의 안전한 취급을 위해서 인화점과 최소자연발화온도를 측정하였다. 2-methyl-1-butanol의 폭발하한계는 실험에서 얻어진 하부인화점을 이용하여 계산하였다. Setaflash 밀폐식은 $40^{\circ}C$, Pensky-Martens 밀폐식은 $44^{\circ}C$ 그리고 Tag 개방식은 $49^{\circ}C$, Cleveland 개방식에서는 $47^{\circ}C$로 측정되었다. ASTM E659 장치에 의한 최소자연발화온도는 $335^{\circ}C$로 측정되었다. 측정된 하부인화점 $40^{\circ}C$에 의한 폭발하한계는 1.30 Vol.%로 계산되었다. 폭발한계는 측정된 인화점이나 문헌에 제시된 인화점을 이용하여 예측 가능함을 알 수 있었다.

• 무역학회지
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• 제46권2호
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• pp.19-38
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• 2021

This study aims to analyze the foreign asset leverage effect on Korean oil & gas companies' foreign profits and to maintain the appropriate foreign asset volume for reducing exchange risk. For a long time, large Korean companies, including oil companies, overheld foreign currency liabilities. For this reason, most large companies have been burdened to hedge exchange risk and this excess limit holding deteriorated total profit and reduced foreign currency asset management efficiency. Our paper proceeds in presenting a three-stage analysis considering diversified exchange risk factors through estimation on transformation of foreign transactions a/c including annual trends of foreign asset and industry specifics. We also supplement incomplete the estimation method through a practical hedging case investigation. Our research parts are differentiated on the analyzing four periods considering period-specifics The FER value of the oil firms ranged from -0.3 to +2.3 over the entire period. The results of the FER Value are volatile and irregular; those results do not represent the industry standard comparative index. The Korean oil firms are over the credit limit without accurate prediction and finance high interest rate funds from foreign-owned banks on the basis on a biased relationship. Since the IMF crisis, liabilities of global firms have decreased. Above all, oil firms need to finance a minimum limit without opportunity losses on the demand forecast and prepare for uncertainty in the market. To reduce exchange risk from the over-the-limit position, we must consider factors that affect the corporate exchange risk on the entire business process, including the contract phase.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2009년도 제33회 추계학술대회논문집
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• pp.213-216
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• 2009

가스터빈 연소기의 화염 특성을 알기 위하여 분할 연소기 시험을 수행하였다. 점화시험은 여러 가지 연소기 유입 공기속도와 공기과잉율에 따라 토치 점화장치를 이용하여 수행되었다. 또한, 연료를 충분히 공급한 상태에서 점화를 수행한 후 점차 연료량을 감소시켜가며 희박연소한계를 측정 하였다. 실험 결과, 공기과잉율 6에서 안정한 점화를 보였고 이 값은 연소기 공기 유입속도에 따라 점점 증가함을 보였다. 최소 실화한계는 연소기 공기 유입속도 40 m/s에서 약 4였고, 이 값 또한 연소기공기유입속도에 따라 약 10 까지 증가함을 보였다.

• International Journal of Naval Architecture and Ocean Engineering
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• 제5권4호
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• pp.529-545
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• 2013

Strong restrictions on emissions from marine power plants (particularly $SO_x$, $NO_x$) will probably be adopted in the near future. In this paper, a combined solid oxide fuel cell (SOFC) and gas turbine fuelled by natural gas is proposed as an attractive option to limit the environmental impact of the marine sector. It includes a study of a heat-recovery system for 18 MW SOFC fuelled by natural gas, to provide the electric power demand onboard commercial vessels. Feasible heat-recovery systems are investigated, taking into account different operating conditions of the combined system. Two types of SOFC are considered, tubular and planar SOFCs, operated with either natural gas or hydrogen fuels. This paper includes a detailed thermodynamic analysis for the combined system. Mass and energy balances are performed, not only for the whole plant but also for each individual component, in order to evaluate the thermal efficiency of the combined cycle. In addition, the effect of using natural gas as a fuel on the fuel cell voltage and performance is investigated. It is found that a high overall efficiency approaching 70% may be achieved with an optimum configuration using SOFC system under pressure. The hybrid system would also reduce emissions, fuel consumption, and improve the total system efficiency.

• 한국수소및신에너지학회논문집
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• 제20권6호
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• pp.479-484
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• 2009

The effect of anode gas channel height on gas diffusion and cell performance in a 100 $cm^2$ class molten carbonate single cell is investigated. Single cell separators with three different channel height are used. The effect of the gas channel height on the distribution of the reactive gas concentration is evaluated by the two-dimensional concentration diffusion equation. The overpotential caused by concentration drop with different channel height is estimated by the voltage decay related to diffusion of reactants, well known as concentration polarization, using limiting current density. The estimation could have the possibility to identify the reactant mass transfer polarization in the complicate factors of the overall electrodes.

• 한국가스학회지
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• 제17권2호
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• pp.9-20
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• 2013

고갈가스전은 저류층을 개발할 당시 충분한 탄성파 탐사 및 시추 등을 수행하기 때문에 지질구조와 저류층의 물성 등의 파악이 완료된 상태이므로 가스저장전으로의 전환이 용이하다. 이러한 고갈가스전을 가스저장전으로 전환 시 저류층의 압력을 유지하기 위한 쿠션가스는 재생산을 위해 주입된 워킹가스의 재생산율에 영향을 미친다. 본 연구에서는 쿠션가스와 가스재생산율과의 관계 및 재생산 사이클에 따른 적정 쿠션가스의 양을 분석하기 위해 가스저장전의 주입 및 재생산에 대한 시뮬레이션을 수행하였다. 주입 및 재생산 사이클은 5개월 주입 5개월 생산, 7개월 주입 3개월 생산 두 가지 경우에 대한 분석을 수행하였다. 본 시스템을 대상으로 수행한 분석결과, 5개월 주입 5개월 생산 사이클의 경우 최소 10개의 생산정으로 50%의 쿠션가스를 유지해야 안정적인 생산이 가능하였고, 7개월 주입 3개월 생산 사이클의 경우 12개의 생산정으로 60%의 쿠션가스를 유지해야 안정적인 재생산이 가능한 것으로 산출되었다.

• Environmental Analysis Health and Toxicology
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• 제16권3호
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• pp.121-126
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• 2001

Analytical method of benzophenone (BP) in sediment and soil was developed by gas chromatography/mass selective detector/selected ion monitoring (GC/MSD/SIM). The ultrasonic extraction of US EPA (method 3550B) method and liquid-liquid extraction for sediment and soil samples were used for the analysis of BP from sediment and soil. BP was extracted with n-hexane. Organic layer was washed with 5% sodium chloride solution. 1∼2 l of the concentrated solution of organic layer was applied to GC/MSD. The retention time of BP peak was 11.10 min. Recovery (％) of BP by ultrasonication from sediment and soil samples was 96.0∼100.6％ and 40.0∼83.0％, respectively. Recovery of BP by liquid-liquid extraction was 51∼59％ in soil samples. The detection limit of BP in sediment and soil samples were determined to 0.1 ng/g.

• 대한기계학회논문집
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• 제19권3호
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• pp.763-770
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• 1995

Gas flow characteristics within the cylinder is important factors in impoving lean combustion stability. This paper shows the effects of various flow fields generated by a swirl control valve(SCV) on combustion process in a 4-valve spark ignition engine. An impulse swirl/tumble meter was used to elucidation the steady-state flow characteristics, and a rotating grating type LDV was developed to measure the mean velocity and tunbulence intensity in relation to the crank angle. These methodologies were applied to clarify the correlation between gas flow characteristics and combustion stability at a lean air fuel ratio. An analysis of the correlation revealed the gas flow conditions required to optimize a lean-burn system.

• 한국식품위생안전성학회지
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• 제12권3호
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• pp.210-216
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• 1997

The prevention of oxidative degradation in fats and oils is largely controlled by the use of synthetic phenolic antioxidants. Antioxidants, BHA: 2-&-3-tert-butyl-4-hydroxyanisol, BHT: 3,5-di-tert-butyl-4-hydroxytoluene, TBHQ: tert-butylhydroquinone, PG: propyl gallate, PTG: pentyl gallate, OG:octyl gallate, were extracted from fatty foods with hexane and from hexane layer to presaturated acetonitrile with hexane. The polar phenolic hydroxyl groups of antioxidants were silylated with MSTFA and injected to Gas Chromatography/Mass Spectrometry. The calibration plots were linear in the investigated range, 0.1~10.0 $\mu\textrm{g}$/g. The limit of detection for 6 phenolic antioxidants was 0.1 $\mu\textrm{g}$/g. Recoveries and reproducibilities from samples fortified at 1.0 $\mu\textrm{g}$/g were in the range of 70~90% and 0.5~13%, respectively. The simultaneous determination of phenolic antioxidants in fatty foods using GC/MS-SIM mode and macro program was described.

• 한국신뢰성학회지:신뢰성응용연구
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• 제6권1호
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• pp.37-50
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• 2006

The accelerated life tests of the catalytic gas sensor were performed at three different gas concentration conditions. From the test data, the power-Weibull model was estimated and the acceleration factor between test condition 25%LEL(Lowe Explosive Limit) and use condition 5%LEL was about 3 according to this acceleration model. Using this acceleration factor, life test specification for qualifying that B10 lifetime of the catalytic gas sensor meets the goal lifetime (5 years) was designed.