• Title/Summary/Keyword: Limestones

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Influence of Physicochemical Characteristic of Donghae-Samcheok Limestones on the Performance of Flue Gas Desulfurization (FGD) (동해-삼척지역 석회석의 물리화학적 특성이 탈황성능에 미치는 영향)

  • Seo, Jun-Hyung;Baek, Chul-Seoung;Kwon, Woo-Tech;Cho, Kye-Hong;Ahn, Ji-Whan
    • Resources Recycling
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    • v.24 no.6
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    • pp.38-44
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    • 2015
  • It studies that effect of limestone of physicochemical characteristic on the performance of flue gas desulfurization (FGD) and application examination for technology of wet type FGD process and to utilize the limestone in Donghae-Samcheok. The experiment method was measured total neutralizing capability (TNC) using the lab scale experimental apparatus based on the HCl titration test. The results of TNC of limestone samples were more dependent on the physical characteristics including particle size rather than chemical compositions such as CaO content and particle size of limestone get smaller, TNC is increased.

Exploration for the Carlin-type Gold Deposits and Its Potential to Korea (칼린형 금광상 탐사와 국내 적용성 연구)

  • Park Maeng-Eon;Sung Kyu-Youl;Baek Seung-Gyun;Kim Pil-Geun;Kang Heung-Suk;Moon Young-Hwan
    • Economic and Environmental Geology
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    • v.38 no.4 s.173
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    • pp.421-434
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    • 2005
  • Abstract Based onthe characteristics of Carlin-type gold deposit in Nevada district, a potential in Korea is evaluated to the Yemi area where is structurally controlled by folds and trust fault. The fault of high angles are combined with a more permeable rocks such as the Yemi breccia and laminated silty limestone. The pattern of enrichment factors for Tl, Sb, As, Ag, Pb, Zn, Cu, Mo and W of limestones in the southern area are geochemically similar with those reported from the Carlin-type Bold deposit. Moreover, the oxygen and carbon isotopes show a hydrothermal alteration is widely developed in this area. According to the result of geophysical interpretation, stable isotope, alteration mineralogy, geochemical study, and geological structure, this mineralized zone may be extended to the M direction, so a detailed systematic exploration is required to identify this alteration zone.

Diagenetic History of the Ordovician Chongson Limestone in the Chongson Area, Kangwon Province, Korea (강원도 정선 지역 오르도비스기 정선석회암의 속성 역사)

  • Bong, Lyon-Sik;Chung, Gong-Soo
    • Journal of the Korean earth science society
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    • v.21 no.4
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    • pp.449-468
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    • 2000
  • The Ordovician Chongson Limestone deposited in the carbonate ramp to the rimmed shelf shows diverse diagenetic features. The marine diagenetic feature appears as isopachous cements surrounding ooids and peloids. Meteoric diagenetic features are recrystallized finely and coarsely crystalline calcite, evaporite casts filled with calcite, and isopachous sparry calcite surrounding ooid grains. Shallow burial diagenetic features include wispy seam, microstylolite, and dissolution seam whereas deep burial features include stylolite, burial cements. blocky calcite with twin lamellae, and poikilotopic calcite. Dolomites consist of very finely to finely crystalline mosaic dolomite formed as supratidal dolomite, disseminated dolomite of diverse origin, patchy dolomite formed from bioturbated mottles, and saddle dolomite of burial origin. Silicified features include calcite-replacing quartz and fracture-filling megaquartz. Burial cements characterized by poikilotopic texture show ${\delta}^{18}$O value of -10.4 %$_o$ PDB, ${\delta}^{13}$C value of -1.0%$_o$ PDB and 504ppm Sr, 3643ppm Fe, and 152ppm Mn concentrations. Finely and coarsely crystalline limestones show similar ${\delta}^{18}$O and ${\delta}^{13}$C value to those of burial cements; however, they show lower Sr and higher Fe and Mn concentrations than burial cements. This suggests that very finely and coarsely crystalline limestones were recrystallized in freshwater and then they were readjusted geochemically in the burial setting whereas the burial cements were formed in relatively high temperature and low water/rock ratio conditions. Very finely and finely crystalline mosaic dolomites with ${\delta}^{18}$O value of -8.2%$_o$ PDB, ${\delta}^{13}$C value of -1.9 %$_o$ PDB, and 213ppm Sr, 3654ppm Fe, and 114ppm Mn concentrations, respectively are interpreted to have been formed penecontemporaneously in supratidal flat and then recrystallized in the low water/rock ratio burial environment. Geochemical data suggest that the low water/rock ratio burial environment was the dominant diagenetic setting in the Chongson Limestone. The Chongson Limestone has experienced marine and meteoric diagenesis during early diagenesis. With deposition of Haengmae and Hoedongri formations part of the Chongson Limestone was buried beneath these formations and it experienced shallow burial diagenesis. During the Devonian the Chongson Limestone was tectonically deformed and subaerially exposed. During the Carboniferous to the Permian about 3.3km thick Pyongan Supergroup was deposited on the Chongson Limestone and the Chongson Limestone was in deep burial depths and stylolite, burial cements, blocky calcite and saddle dolomite were formed. After this burial event the Chongson Limestone was subaerially exposed during the Mesozoic and Cenozoic by three periods of tectonic disturbance including Songnim, Daebo and Bulguksa disturbance. Since the Bulguksa disturbance during Cretaceous and early Tertiary the Chongson Limestone has been subaerially exposed.

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Analysis on the Spectral Characteristics of Dolomite and Calcite: Okgye-myeon, Gangneung-si, Gangwon-do (백운석 및 방해석의 분광특성 분석 연구: 강원도 강릉시 옥계면 지역)

  • Eom, Jinah;Ko, Bokyun;Park, Sungjae;Seon, Seung Dae;Lee, Chang-Wook
    • Korean Journal of Remote Sensing
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    • v.35 no.6_3
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    • pp.1261-1271
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    • 2019
  • In case of Korea, limestone is very useful in various industries. These limestones are mainly produced in Gangwon-do. The study area, which is located in Okgye-myeon, Gangneung-si, Gangwon-do, is Okcheon metamorphic belt where abundant limestone, dolomite stone, and high-grade limestone are produced. The purpose of this study is to distinguish between calcite and dolomite among the limestone which is one of the representative carbonate rocks using the spectral characteristics. For this study,spectral characteristics were measured in the field and laboratory using FieldSpec® 3 spectrometer equipment from Analytical Spectral Device Inc. (ASD). In the field, the reflectance was measured below 50 cm from rock surface, and in the laboratory, the reflectance was measured in the rock surface, the polished surface, and the rock powder. As a result, absorption wavelengths of calcite and dolomite were significantly different around 2,330 nm. In particular, the absorption wavelength band position of dolomite appeared before 2,330 nm wavelength compared to calcite. The study could be used as a basis data for analysis of high-grade calcite limestone.

Palaeomagnetism of the Okchon Belt, Korea: Paleozoic Rocks in Yemi Area (옥천대에 대한 고자기 연구: 예미지역 고생대 지층의 잔류자기)

  • 김인수;김성욱;최은경
    • Economic and Environmental Geology
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    • v.34 no.4
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    • pp.355-373
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    • 2001
  • Palaeomagnesim of Paleozoic Tuwibong Type Sequence in Yemi area was studied with a total of 256 core-samples collected from 23 sites. The study area (geographical coordinates: 37.l8$^{\circ}$N, l28.610E) is located between Taebaek and Yongwol belonging to the northeastern part of the Okchon Belt. Thermal cleaning was a most effective method to extract stable characteristic remanent magnetization (ChRM) direction, even though AF cleaning also worked on some specimens. Mean ChRM direction of the Cambrian Hwajol Formation was different from the present-day field direction and showed maximum clustering (max. k value) at 100% bedding-tilt correction. However, it could not pass the fold test. Ordovician Makkol and Kosong Limestones as well as Permian Sadong and Kobangsan Formations have very weak NRM, and were remagnetized into the present-day field direction. ChRM directions from the Carboniferous Hongjom Formation passed both fold and reversal tests. IRM experiments and blocking temperature spectrum indicate that both magnetite and haematite are carrier of the primary magnetization. Palaeomagnetic pole position from the Carboniferous Hongjom Formation is very similar to that of contemporary North China Block (NCB) suggesting that the study area was a part of, or located very near to, the NCB during Carboniferous.

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Characteristics of Nitrate Contamination of Groundwater - Case Study of Ogcheon Area - (지하수의 질산염 오염 특성 - 옥천지역 사례 연구 -)

  • Park, Ho-Rim;Kim, Myeong-Kyun;Hong, Sang-Pyo
    • Journal of Environmental Impact Assessment
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    • v.24 no.1
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    • pp.87-98
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    • 2015
  • Geochemical characteristics, water quality, $NO_3{^-}$ contamination and the origin of $NO_3{^-}$ were analyzed for the groundwater located at Ogcheon, Korea. The water qualities were weakly acidic to weakly alkalic and redox potentials indicated reduction condition. Compared to granitic rocks, metamorphic sedimentary rocks with intercalations of limestones and dolomites tended to be more effectively dissolved, resulting in higher pH and higher concentrations of dissolved ingredients. Contamination of heavy metals was not revealed. Geochemical reactions of carbonate rocks and influxes of artificial contamination ingredients seemed to simultaneously determine the geochemical characteristics and water qualities in the study area. From the results of ${\delta}^{15}N$ isotope analysis, the origin of $NO_3{^-}$ was estimated to be influenced dominantly by agricultural activities and human feces and urine.

Age Dating and Paleoenvironmental Changes of the Kunang Cave Paleolithic Site

  • Yum, Jong-Kwon;Lee, Yung-Jo;Kim, Jong-Chan;Kim, In-Chul;Kim, Ju-Yong
    • The Korean Journal of Quaternary Research
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    • v.17 no.2
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    • pp.145-148
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    • 2003
  • The Kunang cave paleolithic site is located at Tanyang [$N37^{\circ}2'$, $128^{\circ}21'E$], Chungbuk Province, which is in the Central part of the Korean peninsula. The cave is developed at 312 amsl in a karstic mountainous area. The South Han River flows across this region and other caves can also be found near the river. The site was discovered in 1986 and excavated 3 times by the Chungbuk National University Museum until now. The cave was wellpreserved from modem human activities until the first discovery. The full length of the cave is estimated to be ca. 140 m. However, a spacious part up to 11 m from the entrance has been excavated. Eight lithological units are divided over the vertical profile at a depth of 5 m. Each unit is deposited in ascending order as follow: mud layer (Unit 9), lower complex (Unit 8) which is composed of angular blocks and fragments with a muddy matrix, lower travertine layer (Unit 7; flowstone), middle complex (Unit 6; cultural layer) which is composed of fragments with a muddy matrix, middle travertine layer (Unit 5; flowstone), yellowish muddy layer (Unit 4), upper complex (Unit 3; cultural layer) which has a similar composition to Unit 8. the upper travertine layer (Unit 2; flowstone), and finally surface soil layer (Unit 1). The most abundant vestiges in the cultural layers are the animal bones. They are small fractured pieces and mostly less than 3 cm in length. About 3,800 bone pieces from 25 animal species have been collected so far, 90 percent of them belonging to young deers. Previous archaeological study of these bone pieces shows thatprehistoric people occupied the cavenot for permanent dwelling but for temporary shelter during their seasonal hunting activity. More extensive studies of these bones together with pollen analysis are in progress to reconstruct the paleoenvironment of this cave. Only a single date (12,500 BP) obtained from a U-Th measurement of the upper travertine layer was previously available. In spite of the importance of the cave stratigraphy, there was no detail chronological investigation to establish the depositional process of the cultural layers and to understand the periodic structure of the cave strata, alternating travertine floor and complex layers. We have measured five 14C age dating (38900+/-1000, 36400+/-900, 40600+/-1600, more than 51000 and 52000 14C BP) using Seoul National University 14C AMS facility, conducted systematic process of the collagen extraction from bone fragments samples. From the result, we estimate that sedimentation rate of the cave earth is constant, and that the travertine layers, Unit 2 and Unit 3, was formed during MIS 5a(ca. 80 kBP) and MIS 5c (ca. 100 kBP) respectively. The Kunang Cave site is located at Yochonli of the region of Danyang in the mid-eastern part of Korea. This region is compased of limestones in which many caves were found and the Nam-han river flows meanderingly. The excavations were carried out three times in 1986, 1988, and 1998.

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Study on Calcination Characteristics of Limestones for In-Furnace Desulfurization in Oxy-Fuel Combustion (순산소연소 조건에서 석회석의 소성특성 및 로내탈황에 관한 연구)

  • An, Young-Mo;Jo, Hang-Dae;Choi, Won-kil;Park, Yeong-Sung;Keel, Sang-In;Lee, Hyung-Keun
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.5
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    • pp.371-377
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    • 2009
  • In oxy-fuel combustion, $CO_2$ concentration in the flue gas may be enriched up to 95% owing to the gas recirculation. Under the high $CO_2$ concentration, the calcination characteristic of limestone is different from that of the conventional air combustion system. In this study, three types of limestone taken from different regions in Korea were used as $SO_2$ absorbent and their calcination characteristics depending on calcination temperature were investigated. The experiments were performed to examine the effects of operating variables such as absorbent species, reaction temperatures on the $SO_2$ removal efficiency and reacted limestone particles were captured to examine the sulfur contents. The degree of calcination and the specific surface area increased with calcination temperature and $SO_2$ removal efficiency increased with reaction temperature. The results showed remarkable difference in $SO_2$ removal efficiencies between the limestone types. The sulfur content of the reacted limestone with the highest $SO_2$ removal efficiency was about 10%.

Various Measurement Methods for Fold-axis from Fold-related Structural Elements: An Example from Danyang, Chungcheongbuk-do (습곡관련 구조요소들을 이용한 다양한 습곡축 측정방법의 실제적 적용성과 문제점: 충북 단양지역에서의 예)

  • Choi, Ho-Seok;Kim, Young-Seog
    • Journal of the Korean earth science society
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    • v.42 no.2
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    • pp.175-184
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    • 2021
  • Fold axis of fold, a representative ductile deformation structure, is important for collecting information on the 3D fold structure and the orientation of maximum horizontal principal stress at the time of deformation. For this reason, several fold axis measurement methods based on the fold-related structural elements have been suggested and used even in areas where it is impossible to measure it directly. Thus, these various measurement methods are briefly introduced here, and the measured data with different methods are compared to estimate these methods' reliability. For this purpose, we acquired fold axes at six sites across the Manhang formation of the Pyeongan supergroup and limestones of the Joseon supergroup in Danyang, Chungcheongbuk-do, where fold structures are well developed. The data from the different methods are generally consistent, indicating practical applicability. Most of the fold axes from the measured sites show NNNE or NE trends indicating WNW-ESE or NW-SE trending maximum horizontal principal stress, except for the one site with a WNW trend. The WNW-ESE trending fold axis might be related to a different orogeny or secondary folding. The minor difference in the trends between N-NNE and NE was interpreted as being due to different scale; however, further research is needed to confirm this.

The Development of Geosites and 3D Panoramic Geological Virtual Field Trips for Sinsu Island in Korea National Marine Park (남해 해상 국립공원 신수도의 지질명소 및 3D 파노라마 야외학습장 개발)

  • Cho, Jae-Hee;Yoon, Ma-Byong
    • Journal of the Korean Society of Earth Science Education
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    • v.15 no.1
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    • pp.91-102
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    • 2022
  • Sinsu Island in Korea National Marine Park is suitable for geological learning and geotourism as various geological structures, geological activities, and fossils can be observed. In this study, eight geosites were developed by analyzing 2015 revision science curriculum. The 3D panoramic geological virtual field trips were developed according to the three-step outdoor learning model. The 3D panoramic geological virtual field trips, which consist of 8 classes, are composed of cooperative learning by group, enabling autonomous inquiry activities. It is designed to realize convergence education that can learn not only geology but also creativity and humanity through nodular Limestones, exfoliation, salt weathering, perforated shell holes, sedimentary structures and environments, dinosaurs habitats, and volcanic activity. Five experts revised and supplemented the Delphi analysis method to verify the validity of the development purpose and direction. The satisfaction with the geological field for Sinsu Island course was 4.52, indicating that the overall satisfaction with the field course was high. By reflecting on the opinions of each student and reinforcing safety education, we completed the 3D panoramic geological virtual field trips for Sinsu Island. The 3D panoramic geological virtual field trips in Sinsu Island in Korea National Marine Park will be a good example of geology learning tourism where you can make memories and enjoy while studying geology.