• 제목/요약/키워드: Light-emitting polymer

검색결과 297건 처리시간 0.027초

Novel Electroluminescent Polymer Derived from Pyrene-Functionalized Polyaniline

  • Amarnath, Chellachamy Anbalagan;Kim, Hyoung-Kun;Yi, Dong-Kee;Lee, Sang-Hyup;Do, Young-Rag;Paik, Un-Gyu
    • Bulletin of the Korean Chemical Society
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    • 제32권5호
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    • pp.1495-1499
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    • 2011
  • A solution processable polymer was synthesized, by incorporating pyrene groups into the backbone of the polyaniline chain, and used as an emissive layer in an organic light emitting diode. The polyaniline base was reacted with acid chloride of pyrene butyric acid to form pyrene-functionalized polyaniline chains. The source of pyrene moiety was acid chloride of pyrene butyric acid. The formation of polymer from acid chloride of pyrene butyric acid and polyaniline was confirmed by the FTIR and $^1H$-NMR spectroscopy. Differential scanning calorimetry revealed high glass transition temperature of 210 $^{\circ}C$. Due to the presence of pyrene moieties in the backbone, the polyaniline synthesized in the present study is solution processable with light emitting property. The photoluminescence spectrum of the polymer revealed that emission lies in the blue region, with a peak at 475 nm. The light emitting device of this polymer exhibits the turn-on voltage of 15 V.

고분자 발광다이오드에서 공액고분자 전해질 전자수송층에 의해 변화되는 전자주입 메카니즘 (Electron Injection Mechanisms Varied by Conjugated Polyelectrolyte Electron Transporting Layers in Polymer Light-Emitting Diodes)

  • 엄성수;박주현
    • 폴리머
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    • 제36권4호
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    • pp.519-524
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    • 2012
  • 공액고분자 전해질 전자수송층을 이용하는 고분자 발광소자의 정전용량을 측정하는 것은 전류밀도-전압-발광특성을 측정하는 방법과 더불어 전자수송층으로서 공액고분자 전해질의 기능을 이해하기 위한 소자물리 연구에서 중요한 정보를 제공해준다. 본 연구에서는 고분자 전해질의 반대 이온의 종류에 따라 저주파수 영역에서 정전용량의 거동이 변화하는 것으로부터 전하 주입의 메카니즘에서 차이점이 있음을 분석하였다. 정전용량 모델을 이용한 분석은 전자주입 메카니즘이 음극/전자수송층/발광층 사이의 계면에서 발생하는 쌍극자 배열 또는 전하수송체의 축적에 의한 것임을 나타내었다.

이리듐 합성물 기반의 인광 고분자 발광 소자 (Polymer Phosphorescent Light-Emitting Devices Doped with Iridium Complex)

  • 김성진
    • 한국진공학회지
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    • 제18권4호
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    • pp.254-258
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    • 2009
  • 순방향 전압에서 안정적인 전류 흐름을 가지고 낮은 turn-on 전압으로 구동하는 이리듐 합성물 기반의 인광 고분자 발광 다이오드를 제작하였다. Poly(N-vinylcabazole)와 tris(2-phenylpyridine)iridium 재료를 포함하는 유기 발광층은 $10{\mu}m$/s 와 $20{\mu}m$m/s의 저속도 dip-coating으로 만들었다. 제안한 방법으로 형성된 유기 발광 다이오드는 100 cd/$m^2$의 기준 휘도에서 각각 5.8 V와 6.7 V로 구동이 되었지만, 발광층을 스핀코팅으로 제작된 소자는 다소 높은 전압인 9.1 V를 기록하였다. 본 연구는 대면적, 용액 공정 기반의 고효율 특성을 요구하는 유기 발광 소자에서 발광층의 새로운 박막 형성기술로 이용될 수 있다.

Design and Synthesis of New Fluorene-Based Blue Light Emitting Polymer Containing Electron Donating Alkoxy Groups and Electron Withdrawing Oxadiazole

  • Kim, Yun-Hi;Park, Sung-Jin;Park, Jong-Won;Kim, Jin-Hak;Kwon, Soon-Ki
    • Macromolecular Research
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    • 제15권3호
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    • pp.216-220
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    • 2007
  • A new polyfluorene-based copolymer having 2-ethylhexyloxy-5-methoxy-l,4-phenylene as an electron donating group and 2,5-diphenyl-oxadiazole as an electron withdrawing group was synthesized by the Suzuki coupling reaction. The obtained copolymer was characterized by $^1H-NMR,\;^{13}C-NMR$, and IR-spectroscopy. The weight average molecular weight ($M_w$) of the obtained polymer was 18,600 with a polydispersity index of 1.5. The maximum photoluminescence of the solution and film of the polymer was observed at 453 nm and 456 nm, respectively. A double-layer device with the configuration, ITO/PEDOT/copolymer/Al, emitted blue light at 460 nm.

Solution Processable P-OLED (Polymer Organic Light Emitting Diode) Display Technology.

  • Lee, Jueng-Gil;Carter, Julian
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.II
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    • pp.1050-1055
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    • 2005
  • We report the development frontiers that are dictating the speed of adoption of polymer organic light emitting diode (P-OLED) technology in market applications. Our presentation includes both the developments taking place in materials and the rapid advances in the manufacturing processes used for solution processable P OLEDs. On the manufacturing side, the latest progress in ink jet printing process is discussed. On the materials side, we look at both fluorescent and phosphorescent material performance including the CDT development roadmap.

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Solution Processable P-OLED (Polymer Organic Light Emitting Diode) Display Technology.

  • Lee, Jueng-Gil;Carter, Julian
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.II
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    • pp.1355-1360
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    • 2005
  • We report the development frontiers that are dictating the speed of adoption of polymer organic light emitting diode (P-OLED) technology in market applications. Our presentation includes both the developments taking place in materials and the rapid advances in the manufacturing processes used for solution processable P-OLEDs. On the manufacturing side, the latest progress in ink jet printing process is discussed. On the materials side, we look at both fluorescent and phosphorescent material performance including the CDT development roadmap.

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Light Emitting Polymer Displays

  • Heeks, Karl;Smith, Euan;Goodchild, Bill;Burroughes, Jeremy;Towns, Carl
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.319-324
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    • 2002
  • We will report the latest developments in light emitting polymer (LEP) systems developed at CDT. Device performance for spin coated and ink jet printed systems will be described which are state-of-the-art. We will also report on novel driving schemes for both active and passive addressed LEP displays. These drive schemes extend system lifetime as well as lowering power consumption.

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