• Bulletin of the Korean Chemical Society
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• 제35권5호
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• pp.1356-1364
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• 2014

A new conjugated copolymer, poly{4,8-bis(triisopropylsilylethynyl)benzo[1,2-b:4,5-b']dithiophene-alt-4,7- bis(5-thiophen-2-yl)-5,6-difluoro-2-(heptadecan-9-yl)-2H-benzo[d][1,2,3]triazole} (PTIPSBDT-DFDTBTz), is synthesized by Stille coupling polycondensation. The synthesized polymer has a band gap energy of 1.9 eV, and it absorbs light in the range 300-610 nm. The hole mobility of a solution-processed organic thin-film transistor fabricated using PTIPSBDT-DFDTBTz is $3.8{\times}10^{-3}cm^2V^{-1}s^{-1}$. Bulk heterojunction photovoltaic cells are fabricated, with a conventional device structure of ITO/PEDOT:PSS/polymer:$PC_{71}BM$/Ca/Al ($PC_{71}BM$ = [6,6]-phenyl-$C_{71}$-butyric acid methyl ester); the device shows a power conversion efficiency (PCE) of 2.86% with an open-circuit voltage ($V_{oc}$) of 0.85 V, a short-circuit current density ($J_{sc}$) of 7.60 mA $cm^{-2}$, and a fill factor (FF) of 0.44. Inverted photovoltaic cells with the structure ITO/ethoxylated polyethlyenimine/ polymer:$PC_{71}BM/MoO_3$/Ag are also fabricated; the device exhibits a maximum PCE of 2.92%, with a $V_{oc}$ of 0.89 V, a $J_{sc}$ of 6.81 mA $cm^{-2}$, and an FF of 0.48.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1995년도 추계학술대회 논문집
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• pp.351-356
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• 1995

A optical switch which on the LiNbO$_3$substrate is fabricated by using proton exchange method and self-alignet method. The annealing at 400[$^{\circ}C$] was carried out to control waveguide width and depth. A self-aligned method, which doesn\`t need the additional mask precesses, was applied to simplify the fabrication processes and to maximize efficiency of electric field application. The depths of the two annealed optical waveguides, which were measured by using ${\alpha}$-step, ware 1.435[K${\AA}$] and 1,380[K${\AA}$]. Using ${\alpha}$-step facility, we examined that the width of waveguides is increased from 5[$\mu\textrm{m}$] to 6.45[$\mu\textrm{m}$] and 6.3[$\mu\textrm{m}$] due to the annealing effects. The process of proton exchange was done at 400[$^{\circ}C$] for 60[min] and annealing process was done at 400[$^{\circ}C$] for 60[min]. The high speed optical modulator has very good figures of merits: the measured voltage of the input waveguide power is 3.5[V], the voltage of the coupling waveguide power is 3.9[mV], and -29.5[dB] crosstalk and 8[V] switching voltage were achieved.

• 자원환경지질
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• 제40권6호
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• pp.727-738
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• 2007

운봉지역 하상퇴적물에 대한 지구화학적 특성규명을 통해, 주성분원소 및 미량원소에 대한 자연 배경치를 제시하고, 그 기반암(압쇄상화강암, Kim et al., 1992)과의 비교를 통해 지구화학적 재해에 대해 예견하고자 한다. 73개의 하상퇴적 물시료를 물이 흐르고 있는 1차 수계를 대상으로 채취하였고, XRD, XRF ICP-AES, NAA를 이용하여 주성분원소 및 미량성분원소를 분석하였다. 운봉지역의 주성분원소 함량은 $SiO_2\;36.94{\sim}65.39 wt.%,\;Al_2O_3\;10.15{\sim}21.77wt.%,\;Fe_2O_3\;3.17{\sim}10.90wt.%,\;CaO\;0.55{\sim}5.27wt.%,\;MgO\;0.52{\sim}4.94wt.%,\;K_2O\;1.38{\sim}4.54wt.%,\;Na_2O\;0.49{\sim}3.36wt.%,\;TiO_2\;0.39{\sim}1.27wt.%,\;MnO\;0.04{\sim}0.22wt.%,\;P_2O_5\;0.08{\sim}0.54wt.%$의 범위를 보이며, 미량성분 및 희토류원소 함량은, $Cu\;4.8{\sim}134ppm,\;Pb\;24.2{\sim}82.5ppm,\;Sr\;95.9{\sim}739ppm,\;V\;19.9{\sim}124ppm,\;Zr\;52.9{\sim}145ppm,\;Li\;25.2{\sim}3.3ppm,\;Co\;3.87{\sim}50.0ppm,\;Cr\;17.4{\sim}234ppm,\;Hf\;3.93{\sim}25.2ppm,\;Sc\;4.60{\sim}20.6ppm,\;Th\;3.82{\sim}36.9ppm,\;Ce\;45.7{\sim}243ppm,\;Eu\;0.89{\sim}2.69ppm,\;Yb\;1.42{\sim}5.18ppm$의 범위를 보인다. 주성분원소의 함량비교에서 CaO, $Na_2O,\;K_2O$ 함량은 하상퇴적물에서 기반암(압쇄상화강암류, Kim et al., 1992)인 압쇄상화강암류보다 높게 나타난다. 그리고 $Al_2O_3$와 $SiO_2$는 하상퇴적물과 기반암(압쇄상화강암류, Kim et al., 1992) 모두에서 높은 상관관계를 보인다. 하상퇴적물에서는 $SiO_2$ 함량이 높아질수록 희토류원소 함량도 같이 증가하는 특징을 보이나, 압쇄상화강암류에서는 $SiO_2$ 함량이 높아질수록 희토류원소 함량은 감소하는 특징을 보인다.

• 대한금속재료학회지
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• 제49권10호
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• pp.811-817
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• 2011

In this study, we have investigated the role of a metal oxide hole injection layer (HIL) between an Indium Tin Oxide (ITO) electrode and an organic hole transporting layer (HTL) in organic light emitting diodes (OLEDs). Nickel Oxide films were deposited at different deposition times of 0 to 60 seconds, thus leading to a thickness from 0 to 15 nm on ITO/glass substrates. To study the influence of NiO film thickness on the properties of OLEDs, the relationships between NiO/ITO morphology and surface properties have been studied by UV-visible spectroscopy measurements and AFM microscopy. The dependences of the I-V-L properties on the thickness of the NiO layers were examined. Comparing these with devices without an NiO buffer layer, turn-on voltage and luminance have been obviously improved by using the NiO buffer layer with a thickness smaller than 10 nm in OLEDs. Moreover, the efficiency of the device ITO/NiO (< 5 nm)/NPB/$Alq_3$/ LiF/Al has increased two times at the same operation voltage (8V). Insertion of a thin NiO layer between the ITO and HTL enhances the hole injection, which can increase the device efficiency and decrease the turn-on voltage, while also decreasing the interface roughness.

• 대한지하수환경학회지
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• 제3권1호
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• pp.37-49
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• 1996

이 연구에서는 난지도 매립지와 화성매립지를 연구대상으로하여 주변의 지하수 오염 정도를 파악하고, 오염물질들의 지연작용을 밝히며, 최적 오염지시인자를 도출하고자 하였다. 난지도, 김포, 화성 매립지에서 채취된 침출수에 대하여 현장측정과 실내 화학분석을 실시하여 침출수의 물리화학적 수리화학적 특성들을 파악한 결과 침출수는 높은 온도(31.7-40.1$^{\circ}C$)와 높은 전기전도도(14,650-32,800 $\mu$S/cm), 약 알칼리의 pH(7.58-8.45), 낮은 Eh값(-119.4-20.4 mV)을 특징적으로 보이며, 주성분 이온들로서 $Na^{＋}$, $K^{＋}$, $Ca^{2＋}$, $Mg^{2＋}$, HC $O_3$$^{－}$, C $l^{－}$ 등이, 부성분 이온들로서 Mn, S $r^{2＋}$, $Ba^{2＋}$, L $i^{＋}$, $F_{－}$, B $r^{－}$ 등이 부화되어 있다. 일반폐기물 매립지인 난지도.김포 매립지의 침출수와 산업폐기물 매립지인 화성매립지의 침출수는 S $O_4$$^{2－}$ , Fe 중금속 원소들의 함량으로 구분된다. 지표수와 지하수의 화학분석, Cl 표준화과정, WATEQ4F 분석 등을 종합하여 앞서 연구된 유선망 분석을 바탕으로 오염물질의 거동을 해석하였다. 또한 Contamination Factor를 통하여 최적의 오염지시인자를 도출하였다. 일반페기물 매립지인 난지도 매립지의 경우 K, Na, Ca, Mg, B, Zn, HC $O_3$, Cl, F, Br, TOC 등이 , 산업 폐기 물 매립지인 화성 매립지의 경우 K, Na, Ca, Mg, B, S $O_4$, HC $O_3$, Cl, F, Br, TOC 등이 뚜렷한 대조를 보이는 좋은 오염지시인자이며, 해안 매립지는 TOC가 가장 적합한 오염지시 인자이다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1998년도 추계학술대회 논문집 학회본부 C
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• pp.822-824
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• 1998

The lithium polymer battery with polymer electrolyte is expected as a safe and long cycle life battery. This paper reports primarily the recent development results of a solid polymer electrolyte, which is a key point of the secondary battery system. The new type of polymer electrolyte was prepared under a dry Ar atmosphere by dissolving $LiCIO_4$ in a matrix of EC, PC and then dispersing polyacrylonitrile(PAN). Also adding some inorganic filler $Al_2O_3$. The dispersed solution heated at $120^{\circ}C$. The polymer electrolyte were characterized by EIS(Electrochemical Impedance Spectroscopy), TGA(Thermo Gravimetric analysis), DMA(Dynamic Mechanical Analyzer), DSC (Differential Scanning Calorimetry). The lithium ion yield is 0.29 when PAN-$Al_2O_3$ which was applied DC 5mV. The ionic conductivity of PAN, PAN-$Al_2O_3$ polymer electrolytes were showed $1.0{\times}10^{-4}S/cm$, $8.4{\times}10^{-4}S/cm$ at room temperature. When inorganic filler was added in the polymer electrolyte, ionic conductivity and lithium yield more larger than without inorganic filler.

• E2M - 전기 전자와 첨단 소재
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• 제8권4호
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• pp.443-450
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• 1995

A directional coupler which on the X-cut $LiNbO_3$ substrate is fabricated by using proton exchange method and self-aligned method. After proton exchange process, the waveguide is formed by annealing process. The relation ship between refractive index change of waveguide and maximum output was studied along with the annealing time. A self-aligned method was used to simplify the fabrication process of the waveguide and to maximize the efficiency of electric field. The on-off state of modulator has been observered with the switching of the directional coupler by the electric field effect and also the switching voltage of the directional coupler has been measured with 8.0 [V].

• 자원환경지질
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• 제39권6호
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• pp.675-687
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• 2006

이 연구에서는 청풍지역 하상퇴적물에 대한 지구화학적 특성 규명을 통해, 주성분원소 및 미량원소에 대한 청풍지역의 자연배경치를 제시하고, 지구화학적 재해에 대해 예견하고자 한다. 이를 위해 물이 흐르고 있는 1차 수계를 대상으로 하상퇴적물시료를 채취하였고, 실험실에서 자연건조 시켰으며, 화학적 분석을 위해 알루미나 몰타르를 이용하여 200메쉬 이하로 분쇄하였다. 주성분원소 및 미량성분원소는 XRD, XRF, ICP-AES, NAA를 이용하여 분석하였다. 청풍지역 하상퇴적물의 기반암에 따른 지질집단별 지구화학적 특성 비교를 위해, 화강암질편마암지역, 메타텍틱편마암지역, 다도응회암지역, 유치역암 지역, 능주용암지역으로 분류하였다. 청풍지역 하상퇴적물 전체에 대한 주성분원소 함량은 $SiO_2\;47.31{\sim}72.81\;wt.%,\;Al_2O_3 \;11.26{\sim}21.88\;wt.%,\;Fe_2O_3\;2.83{\sim}8.39\;wt.%,\;CaO\;0.34{\sim}7.54\;wt.%,\;MgO\; 0.55{\sim}3.59\;wt.%,\;K_2O\;1.71{\sim}4.31\;wt.%,\;Na_2O\;0.56{\sim}2.28\;wt.%,\;TiO_2\;0.46{\sim}1.24\;wt.%,\;MnO\;0.04{\sim}0.27\;wt.%,\;P_2O_5\;0.02{\sim}0.45\;wt.%$이다. 청풍지역 하상퇴적물 전체에 대한 미량성분원소 및 희토류원소 함량은 $Ba\;700ppm{\sim}8990ppm,\;Be\;1.0{\sim}3.50ppm,\;Cu\;6.20{\sim}60ppm,\;Nb\;12{\sim}28ppm,\;Ni\;4.4{\sim}61ppm,\;Pb\;13{\sim}34ppm,\;Sr\;65{\sim}787ppm,\;V\;4{\sim}98ppm,\;Zr\;32{\sim}164ppm,\;Li\;21{\sim}827ppm,\;Co\;3.68{\sim}65ppm,\;Cr\;16.7{\sim}409ppm,\;Cs\;72{\sim}37.1ppm,\;Hf\;4.99{\sim}49.2ppm,\;Rb\;71.9{\sim}649ppm,\;Sb\;0.16{\sim}5.03ppm,\;Sc\;4.97{\sim}5ppm,\;Zn\;26.3{\sim}375ppm,\;Ce\;60.6{\sim}373ppm,\;Eu\;0.82{\sim}6ppm,\;Yb\;0.71{\sim}10ppm$의 범위를 보였다.

• Journal of Microbiology and Biotechnology
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• 제30권6호
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• pp.856-867
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• 2020

Vibrio parahaemolyticus is a major gastroenteritis-causing pathogen in many Asian countries. Antimicrobial resistance in V. parahaemolyticus has been recognized as a critical threat to food safety. In this study, we determined the prevalence and incidence of antimicrobial resistance in V. parahaemolyticus in the southern Fujian coast, China. A total of 62 isolates were confirmed in retail aquatic products from June to October of 2018. The serotype O3:K6 strains, the virulence genes tdh and trh, antibiotic susceptibility and molecular typing were investigated. Then plasmid profiling analysis and curing experiment were performed for multidrug-resistant strains. The results showed that the total occurrence of V. parahaemolyticus was 31% out of 200 samples. Five strains (8.1%) out of 62 isolates were identified as the V. parahaemolyticus O3:K6 pandemic clone. A large majority of isolates exhibited higher resistance to penicillin (77.4%), oxacillin (71%), ampicillin (66.1%) and vancomycin (59.7%). Seventy-one percent (44/62) of the isolates exhibited multiple antimicrobial resistance. All 62 isolates were grouped into 7 clusters by randomly amplified polymorphic DNA, and most of the isolates (80.6%) were distributed within cluster A. Plasmids were detected in approximately 75% of the isolates, and seven different profiles were observed. Seventy-six percent (25/33) of the isolates carrying the plasmids were eliminated by 0.006% SDS incubated at 42℃, a sublethal condition. The occurrence of multidrug-resistant strains could be an indication of the excessive use of antibiotics in aquaculture farming. The rational use of antimicrobial agents and the surveillance of antibiotic administration may reduce the acquisition of resistance by microorganisms in aquatic ecosystems.

• 대한전자공학회논문지TE
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• 제37권3호
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• pp.1-5
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• 2000

A waveguide of coupled optical modulator was fabricated on LiNbO$_3$ based on proton exchange with self-aligned thin film electrode method. The electrode pattern was designed using a self-aligned method. After proton exchange process, the waveguide was prepared by annealing process. The initial crossover state of the fabricated 2$\times$2 coupled optical modulator was observed with controlling the annealing process variables and the structure of self-aligned thin film electrodes. It was shown form the present work that the measured crosstalk is -29.5[dB] and 8.0[V] of detected modulating voltage.