• Title/Summary/Keyword: LiPO

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Fabrication of porous glass ceramics in Li$_2$O-TiO$_2$-P$_2$O$_{5}$ system (R$_2$O-TiO$_2$-P$_2$O$_{5}$계 다공질 글라스 세라믹스의 제조)

  • 권면주;윤영진;강원호
    • Proceedings of the KAIS Fall Conference
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    • 2000.10a
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    • pp.173-177
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    • 2000
  • 인산염계 5Li₂O, 36CaO, 20TiO₂, 27P₂O/sub 5/의 조성을 선정하여 10K/min 승온속도로 1300℃에서 2시간동안 유지시켜 모유리를 제조하였고, 최적의 핵형성을 위해 610℃에서 20시간, 최고 결정성장을 위해 840℃에서 20시간 동안 열처리함으로써 LiTi₂(PO₄)₃상과 β-Ca₃(PO₄)₂결정상이 존재하는 Glass Ceramics를 제조하였고, 이를 1N-HCI용액에서 3일간 담지하여 β-Ca₃(PO₄)₂결정상을 용출시켜 LiTi₂(PO₄)₃상만이 존재하는 다공성 Glass Ceramics를 제조하였다.

Comparison of SOC estimation using EKF of the LiFePO4 cell according to minor loop in individual SOC range (EKF를 이용한 SOC 구간별 개별 Minor loop에 따른 LiFePO4 셀의 SOC 추정성능 비교분석)

  • Lee, Hyun-jun;Park, Joung-hu;Kim, Jonghoon
    • Proceedings of the KIPE Conference
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    • 2015.07a
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    • pp.397-398
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    • 2015
  • 본 논문은 $LiFePO_4$ 셀의 SOC(State of Charge) 추정에서 가장 중요한 역할을 하는 모델 파라미터인 OCV(Open Circuit Voltage)의 설계에 관한 것이다. $LiFePO_4$ 셀은 히스테리시스 특성 때문에 Charging/Discharging OCV값을 이은 curve인 Major loop만으로는 신뢰도 높은 SOC 추정이 어렵다. 따라서, 기존의 Major loop에 추가적으로 SOC 10% 구간별로 Minor loop을 설계해 줌으로써 배터리 모델링의 정확도를 높이고, 이를 최종적으로 EKF(Extended Kalman Filter)알고리즘을 이용하여 SOC 추정으로 해봄으로써 정확도 향상을 비교해 보고 분석해 보고자 한다.

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Synthesis of LiFePO4 nano-fibers for cathode materials by electrospinning process

  • Kang, Chung-Soo;Kim, Cheong;Son, Jong-Tae
    • Journal of Ceramic Processing Research
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    • v.13 no.spc2
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    • pp.304-307
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    • 2012
  • Nano-fibers of LiFePO4 were synthesized from a metal oxide precursor by adopting electrospinning method. After calcination of the above precursor nano-fibers at 800 ℃, LiFePO4 nano-fibers with a diameter of 300 ~ 800 nm, were successfully obtained. Measurement were performed using X-ray diffraction (XRD), fourier transform infrared spectrometer (FT-IR), videoscope, scanning electron microscope (SEM) and atomic force microscope (AFM), respectively, were performed to characterize the properties of the as-prepared materials. The results showed that the crystalline phase and morphology of the fibers were largely influenced the starting materials and electrospinning conditions.

Synthesis and Electrochemical Properties of LiFePO4 Cathode Material obtained by Electrospinning Method (전기방사법을 이용한 LiFePO4 양극 활물질의 합성 및 전기화학적 특성)

  • Lee, Seung-Byung;Cho, Seung-Hyun;Park, Sun-Il;Lee, Wan-Jin;Lee, Yun-Sung
    • Journal of the Korean Electrochemical Society
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    • v.11 no.4
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    • pp.268-272
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    • 2008
  • $LiFePO_4$ material was synthesized by electrospinning method to obtain optimal particle size($50{\sim}100\;nm$) without carbon coating or ball milling. This material showed an orthorthombic structure with Pnma space group without any impurities, such as FeP or $Fe_2P$, in the XRD pattern. The particle morphology and particle shape were observed by SEM analysis. Li/$LiFePO_4$ cell showed a high initial discharge capacity of 135 mAh/g, at current density of $0.1\;mA/cm^2$ with a cut-off voltage of 2.8 to 4.0V. This cell exhibited a perfect cycle performance over 99.9% cycle retention rate up to 50 cycles.

The Anti-Bacterial Properties of LTP Crystallized Glass by Ag Ion Exchange (LTP계 결정화유리의 Ag이온교환에 따른 항균특성)

  • 권면주;윤영진;강원호
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.3 no.3
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    • pp.183-188
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    • 2002
  • Antibacterial glass ceramics composed of $5Li_2O{\cdot}36CaO{\cdot}20TiO_2{\cdot}27P_2O_5$ were Prepared. After ion exchange in the $AgNO_3$solution, crystallization phases were $AgTi_2(PO_4)_3$, $LiTi_2(PO_4)_3$ and $Ca_3(PO_4)_2$. In case of ion exchange, the crystallization phases started to be transformed from $LiTi_2(PO_4)_3$ to $AgTi_2(PO_4)_3$in 0.5 mole $AgNO_3$ solution and the transformation was almost completed in 1.0 mole. ion exchange rate of glass-ceramics powder, considering ion exchange time, was more fast than that of bulk. The bacteriostatic effect of the glass-ceramics on Staphyloroccus aureus and Salmonella typhi bacteria was more excellent than that of glass when the crystallization phase was transformed from LTP to AgTP.

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Urgency of LiFePO4 as cathode material for Li-ion batteries

  • Guo, Kelvii Wei
    • Advances in materials Research
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    • v.4 no.2
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    • pp.63-76
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    • 2015
  • The energy crisis involving depletion of fossil fuel resource is not the sole driving force for developing renewable energy technologies. Another driving force is the ever increasing concerns on the air quality of our planet, associated with the continuous and dramatic increase of the concentration of greenhouse gas (mainly carbon dioxide) emissions. The internal combustion engine is a major source of distributed $CO_2$ emissions caused by combustion of gasoline derived largely from fossil fuel. Another major source of $CO_2$ is the combustion of fossil fuels to produce electricity. New technologies for generating electricity from sources that do not emit $CO_2$, such as water, solar, wind, and nuclear, together with the advent of plug-in hybrid electric vehicles (PHEV) and even all-electric vehicles (EVs), offer the potential of alleviating our present problem. Therefore, the relevant technologies in $LiFePO_4$ as cathode material for Li-ion batteries suitable to the friendly environment are reviewed aim to provide the vital information about the growing field for energies to minimize the potential environmental risks.