• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2005년도 동계학술발표대회 논문집
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• pp.347-352
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• 2005

The objectives of this paper are to study the characteristics of heat transfer and pressure drop in plate heat exchangers for absorption applications, and to quantify the effect of mass flow rate, solution concentration, and geometric conditions such as chevron angle on the heat transfer coefficient and pressure drop in the plate heat exchangers. The working fluid is $H_2O$/LiBr solution with the LiBr concentration range of 53.2 - 62.5 % in mass. The results show that the overall heat transfer coefficient increases linearly with increasing Re. The heat transfer rate increases with increasing the chevron angle while it does not significantly depend on the LiBr concentration. The pressure drop also increases with increasing the chevron angle. The effect of the chevron angle on the pressure drop is more significant than that of the concentration.

• 설비공학논문집
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• 제5권1호
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• pp.1-9
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• 1993

Mass transfer coefficients were measured for water vapor absorption into a LiBr-Water solution of 60wt% flowing down an absorber of vertical tube type. The absorber is copper tube of 25mm inner diameter and 1000mm length. The film Reynolds number were varied in the range of 35~130. The solution is fed from the top of the pipe, and the conditions of solution are supercooled liquid and superheated liquid. As results, the flowrates of LiBr solution which takes peak value of average absorption mass flux exist. Mass transfer coefficients decrease with increasing the flowrate of LiBr solution, and the decrease rate in the case of supercooled liquid is large as compared with that in the case of superheated liquid. But the absorption rate of supercooled liquid is decidedly superior to that of superheated liquid.

• International Journal of Industrial Entomology and Biomaterials
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• 제20권2호
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• pp.99-105
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• 2010

In this paper, the regenerated silk fibroins were dissolved in LiBr aqueous solution with different dissolution temperature and time, and the effects of the dissolution condition on the regeneration yield, molecular weight, wet spinnability, and electrospinnability of regenerated silk fibroin were investigated. The regeneration yield, molecular weight distribution, and wet spinnability of regenerated silk fibroin were nearly affected by the dissolution temperature and time. However, the electrospinning performance of silk fibroin was influenced by the dissolution condition implying the electrospinning of silk fibroin is more sensitive process than the wet spinning in the range tested in this study. While $25^{\circ}C$ of dissolution temperature resulted in a good electrospinnability of regenerated silk fibroin, the electrospinnability was slightly deteriorated when silk fibroin was dissolved at $60^{\circ}C$ for 6 hours. Also, though the fiber diameters of electrospun silk fibroin produced by the dissolution at $25^{\circ}C$ for 6 hours and 24 hours were 443 and 451 nm, respectively, that at $60^{\circ}C$ for 5 min was reduced to 411 nm. The fiber diameter was more decreased to 393 nm when the dissolution time increased up to 6 hours at $60^{\circ}C$.

• 한국표면공학회지
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• 제57권2호
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• pp.92-97
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• 2024

The LiBr aqueous solution, which is the absorption liquid of absorption refrigerator, must be replaced periodically because the concentration of impurities such as Cu²⁺, Fe²⁺, Ca²⁺, etc., increases due to corrosion of the tubes as the period of use increases, and the refrigeration efficiency decreases significantly. In order to reuse the waste absorption liquid, flocculation-precipitation method is mainly applied to precipitate the impurities, which requires hundreds of times the concentration of impurities and generates additional waste. In this study, a process for removing Cu ion impurities from cyclone electrolyzer by electrolytic reduction is presented in a small-scale facility without additional waste. It was confirmed that Cu ion impurities can be removed down to 1 ppm by electrolytic reduction process, and to further improve the removal rate, the mass transfer rate was increased by using a cyclone electrolyzer. The removal rate of Cu ions increased with the increase of flow rate and current density, and it was confirmed that Cu was removed at a rate of 1.48 ppm/h under the condition of 330 mL/sec and 2.5 mA/cm².

• Bulletin of the Korean Chemical Society
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• 제33권2호
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• pp.589-596
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• 2012

In this paper, the reactive dynamics properties of the reactions Ba + $C_6H_5Br$ and Ba + m-$C_6H_4CH_3Br$ were studied by means of the quasi-classical trajectory method based on the London-Eyring-Polanyi-Sato potential energy surfaces. The vibrational distributions, reaction cross sections, rotational alignments of the products BaBr all were obtained. The peak values of the vibrational distributions are located at $\nu$ = 0 for the reactions Ba + $C_6H_5Br$ and Ba + m-$C_6H_4CH_3Br$ when the collision energies are 1.09 and 1.10 eV, respectively. The reaction cross sections increase with the increasing collision energy, which changes from 0.6 to 1.5 eV. The product rotational alignments deviate from -0.5 and firstly increase and then decrease while the collision energy is increasing, just like that of Heavy+Light-Light system.

• 한국안전학회지
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• 제7권2호
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• pp.63-70
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• 1992

흡수식 열펌프에서 폭 넓게 사용되고 있는 대표적인 냉매/흡수용액은 $H_2O$ / LiBr 계이다 그러나, LiBr 수용액의 점성계수는 LiBr의 농도가 커짐에 따라 증가하기 때문에, LiBr수용액의 농용액 영역에서 물질확산계수가 감소한다. 이 결점을 보완하기 위해 흡수용액에 계면활성제를 첨가시키므로서 흡수를 촉진시키는 방식을 이용하고 있다. 계면활성제의 첨가에 의한 흡수용액의 열 및 물질이동 촉진에 관한 연구는 계면활성제 첨가농도에 의해 흡수용액의 표면상에서 게면활성제가 액적으로 존재하는 계면활성제 포화용해도 이상의 조건에서 발생하는 마랑고니대류가 효과적이다. 이 흡수촉진효과는 냉매증기의 흡수시 흡수용액표면상의 분포한 계면활성제와 흡수용액사이의 표면장력차에 기인하는 계면교한 현상에 기인한다. 그러나, 이흡수촉지효과는 냉매증기의 흡수가 일어나는 흡수기 내부의 不안정상태, 즉, 불응축성가스(공기)가 존재하지 않는 조건하에서 이루어지며, 불응축성가스가 흡수촉진저하(열 및 물질이동의 저하)에 기인하는 연구는 보고된 바 없다. 이러한 불응축성가스가 흡수기 내부에 존재할 때 계면교한의 거동 및 열 및 물질이동저하현상을 파악하기 위하여 계면활성제 농도변화(포화용해도 이상 및 이하의 두 조건)에 따른 증기흡수 실험 및 계면교한가시화 실험을 행하였다. 결과적으로 본실험을 통하여 불응축성가스가 수증기흡수에 끼치는 영향을 파악(계면교란의 악화) 첨가시의 흡수량과 不安定상태(불응축성가스가 존재시)의 증기흡수량의 비교에 의해 급격한 증기흡수저하가 不安定상태하에서 발생함으로서 불응축성가스가 흡수촉진효과(계면교한현상)을 저해시키는 결론을 얻었다.es and facts obtained by the expenence in this area, respectively. Both depth-first search and backward chaining schemes are used in reasoning process. This expert system is written in an artificial intelligence language "PROLOG", and its availability is demonstrated through the case study.e함량은 감소되었으며 sulfhydryl기가 증가됨에 따라서 disulfide groups은 감소되는 경향을 보였고 ascorbic acid는 열처리 온도뿐만 아니라 시간과도 관련이 있음을 알 수 있었다. 저온 살균유와 초고온 살균유 사이에서는 지표물질들의 함량이 다소 차이가 있음을 볼 수 있었다.담시간이 구체적으로 기술되지 않았으며, 고유한 언어를 통역하는 과정에서 의미론적 문제에 대한 고려가 부족하였다. 면접과 기록과정에서 보면 자료의 기록과정과 분류 및 분석과정이 명시되어 있지 않았다. 참여관찰과 면접방법을 사용시 이에 대한 자세한 기술이 되어 있지 않았다. 5. 연구결과의 적용 및 이에 대한 논의는 상당히 제한되어 있었는데, 수편의 연구만이 방법론 문제점과 앞으로의 연구분야에 대한 전망을 제시하였으며, 특이한 것은 어 떤 연구자도 이른 개발을 위한 적용 및 임상실무적 차원에서 간호에 대한 제언을 하지 않았다.유모델변수들은 유입-유출 자료들로부터 평가할 수 있으며, 이를 위해서 본 논문에서는 Gauss-Newton 방법을 이용한 Bard

• 광학세계
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• 통권172호
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• pp.37-41
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• 2017

• 대한기계학회논문집
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• 제19권4호
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• pp.1071-1082
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• 1995

Numerical analyses have been performed to obtain the absorption heat and mass transfer coefficients and the absorption mass flux from a falling film of the LiBr aqueous solution which is cooled by cooling air. Heat flux at the wall is specified in terms of the heat transfer coefficient of cooling air and the cooling air temperature. Effects of operating conditions, such as the heat transfer coefficient, the cooling air temperature, the system pressure and the solution inlet concentration have been investigated in view of the local absorption mass flux and the total mass transfer rate. Effects of film thickness and film Reynolds number on the heat and mass transfer coefficients have been also estimated. Analyses for the constant wall temperature condition have been also carried out to examine the reliability of present numerical method by comparing with previous investigations.

• 태양에너지
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• 제12권1호
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• pp.15-24
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• 1992

태양열이용 LiBr-water 흡수식 냉난방시스템의 시간단위의 simulation model을 SuperCalc spreadsheet를 사용해서 제시하였고 전체시스템의 열성능을 분석함으로써 spreadsheet simulation 방식의 가치를 입증하였다. Arizona, Tucson에 위치한 사무실형 건물의 시간단위의 냉난방 부하를 ASHRAE 방식에 의하여 계산하였으며 전체 시스템의 구성요소 및 제어 방식에 대한 알고리즘을 제시하였다. 두 종류의 흡수식 시스템의 열성능을 시스템 매개변수를 이용해서 비교하였다.

• Journal of Advanced Marine Engineering and Technology
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• 제24권3호
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• pp.113-120
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• 2000

On the absorber of absorption chiller/heater, LiBr solution at high concentration is sprinkled on a bundle of horizontal tube cooled by cooling water. In this case, the conditions of LiBr solution and cooling water have an influence on heat/mass transfer coefficient in this system. Therefor it is important to find optimal operation conditions of absorption chiller/heater to save energy. Heat and mass transfer coefficient increased with the increase of solution flow rate, and also heat and mass transfer rate increased but overall heat and mass transfer coefficient decreased by increasing the solution concentration within the experimental range. The superheating of the solution resulted in superior heat transfer character to a state of equilibrium from the point of heat flux and overall heat transfer coefficient.