• 제목/요약/키워드: LiBr

검색결과 232건 처리시간 0.021초

고온 작동형 전지의 전해질 및 전극내 첨가염 변화에 따른 전기화학적 특성 연구 (Electrochemical Properties on High Temperature Operating Battery by Electrolyte and Salts in Electrodes)

  • 최유송;하상현;조성백
    • 한국군사과학기술학회지
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    • 제14권4호
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    • pp.740-746
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    • 2011
  • Thermally activated batteries have good stability, reliability and long shelf life. Due to these characteristics and operational mechanism, thermal batteries are usually applied to military power sources. Especially, Li/$FeS_2$ thermal batteries, which are used mostly in these days, use LiCl-KCl and LiBr-LiCl-LiF as electrolytes. The electrochemistry of thermal batteries have been researched for long time, however, electrochemical study using impedance spectroscopy was not published so much. Through this research, microscopic electrochemical research was investigated with electrochemical impedance spectroscopy(E.I.S). Electrolyte effects on Li/$FeS_2$ thermal battery was researched changing electrolytes, LiCl-KCl and LiBr-LiCl-LiF. Additionally, the salts, which are added to electrolytes, effects on thermal battery were researched. It is expected that the impedance spectroscopy analysis is applicable to not only thermal battery electrochemical study effectively, but also, thermal battery developments.

UF/MF막의 국내 적용사례

  • 김정학
    • 한국막학회:학술대회논문집
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    • 한국막학회 1998년도 제6회 하계 Workshop (98 한국막학회, 국립환경연구원 국제 Workshop, 수자원 보전과 막분리 공정)
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    • pp.171-221
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    • 1998
  • 막분리기술은 이제 분리, 정제만의 단순한 개념이 아니며 고도분리정제와 자원재활용등이 복합적으로 해결되는 효율적 공정으로서 "Zero discharge" 및 "Closed-loop System" 으로서의 개념을 가지고 있다. 이것은 Clean Technology의 개념으로서 Membrane기술의 향후 Vision이라고 할 수 있다. 국내에 적용되고 있는 UF/MF막의 용도는 다음과 같다. -수처리분야, 가정용정수기, 폐수처리분야, 식품/생물공정 분야, 전착도장, 흡수식 냉동기의 LiBr 용액정제, 흡수식 냉동기의 LiBr 용액정제

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Evaluation of Chinese Brown Rice as an Alternative Energy Source in Pig Diets

  • Piao, X.S.;Li, Defa;Han, In K.;Chen, Y.;Lee, J.H.;Wang, D.Y.;Li, J.B.;Zhang, D.F.
    • Asian-Australasian Journal of Animal Sciences
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    • 제15권1호
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    • pp.89-93
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    • 2002
  • A total of six crossbred barrows ($Duroc{\times}Landrace{\times}Large$ White, $44.17{\pm}1.94kg$ BW) were housed conducted to evaluate apparent fecal digestibilities of Brown Rice (BR) as an alternative energy source in growing pigs. Pigs were housed individually on metabolism crate on the basis of body weight. Four treatments contained: 1) 100% of corn-soybean meal (C100; Control diet), 2) 75% of corn-soybean meal diet plus 25% of corn meal (C25), 3) 100% of brown rice-soybean meal diet (BR100), 4) 75% of brown rice-soybean meal diet plus 25% of brown rice meal (BR25). Brown rice has an excellent gross energy and crude protein composition compared to corn. The BR used had 3,801 kcal of gross energy/kg, 8.0% crude protein, 2.6% of ether extract, 0.035% calcium and 0.35% total phosphorus. The best digestibilities of energy (87.75%), DM (81.71%) and CP (78.57%) were observed in BR 100 group and the worst were found in Corn 25 group. The nutrient digestibility was not significantly different in most nutrients. Through this experiment, BR appeared a good alternative energy source that can replace corn yellow to 100% in growing pigs. Therefore, the price relationship between corn and BR may provide an excellent opportunity for pork producers to use BR in order to reduce feed costs provided that diet has been balanced for digestible amino acids.

LiCl-$CaCl_2-Zn(NO_3)_2$ 수용액을 사용하는 흡수 2중효용 시스템에서 태양열을 증발기 열원으로 사용하는 난방기의 열역학적 해석 (Thermodynamic Analysis of a Double-Effect Absorption Heating System Using Water-LiCl-$CaCl_2-Zn(NO_3)_2$ Solution at Solar Evaporator Heating)

  • 원승호
    • 한국태양에너지학회 논문집
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    • 제27권3호
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    • pp.87-94
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    • 2007
  • In this paper, with water-LiCl-$CaCl_2-Zn(NO_3)_2$ mixture which utilizes solar energy at the evaporator heat source, a thermodynamic analysis was performed to provide design data for a double-effect absorption heating system. A comparative study of the water-LiCl-$CaCl_2-Zn(NO_3)_2$ mixture against the water-LiBr pair was conducted by a computer simulation. The computer simulation is based on mass, material and heat balance equations for each part of the system. Coefficients of performance and flow ratios for effects of different operating temperatures are investigated. It is found that the heating COP is higher for the water-LiCl-$CaCl_2-Zn(NO_3)_2$ mixture than for the water-LiBr pair, and FR is lower for the former.

1, 2종 흡수식 히트펌프의 작동 매체에 따른 성능 해석[I] (Thermodynamic Analysis of an Absorption Heat Pump System with New Working Pairs[I])

  • 원승호;이원용;정헌생
    • 설비공학논문집
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    • 제1권3호
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    • pp.219-227
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    • 1989
  • Performance analysis of an absorption heat pump system for solar energy recovery has been done by computer simulation to find improved working pairs. Based on the thermodynamic analysis, the coefficient of performance and mass flow ratio have been calculated to compare two aqueous solutions [LiCl-water, $LiCi-CaCl_2-Zn(NO_3)_2$-water] which were developed for cooling by others, with the conventional LiBr-water solution. As a result of this analysis, the performances of the new aqueous solutions were found to be better than that of LiBr-water solution not only in cooling systems, but also in heating and in heat transformer systems. Their theoretical thermodynamic performance data were given here with.

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셀룰로스의 분석을 위한 새로운 시료처리 및 크기배제크로마토그래피 (A New Sampling and SEC Method for Analysis of Underivatized Cellulose)

  • 이승호;박희영
    • 대한화학회지
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    • 제42권2호
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    • pp.190-196
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    • 1998
  • 셀룰로스시료를 치환체로 만들지 않고 분자량 및 분자량분포를 결정하기 위한 새로운 시료처리 및 크기배제크로마토그래피방법을 확립하였다. 먼저 셀룰로스시료를 N-methylmorpholine N-oxide (NMMO)에 녹인 후 dimethyl sulfoxide (DMSO)에 희석함으로써 50/50(w) NMMO/DMSO에 녹은 약 0.1%의 시료용액을 만들었다. 컬럼으로는 글루코오스를 입힌 polydivinylbenzene 겔을 채운 크기배제크로마토그래피용 컬럼을 이용하였으며 용리액으로는 0.05M의 LiBr와 2.5%의 바탕용액을 포함하는 DMSO를 이용하였다.유속은 1 mL/min로 일정하게 유지하였고, DMSO의 점도를 낮추기 위해 컬럼을 포함하는 전체 시스템을 80$^{\circ}C$ 로 유지하였다. 0.05M의 LiBr를 가함으로써 SEC바탕선의 표류를 방지할 수 있었고 2.5%의 바탕용액을 가함으로써 시료와 컬럼충진물질 사이의 상호작용을 감소시키는 효과를 얻었다. 좁은 분포를 가지는 pullulan표준물질로부터 얻은 컬럼보정곡선을 이용하여 두 개의 I 펄프시료와 두 개의 셀룰로스 스펀지 시료의 평균분자량을 결정함으로써 펄프로부터 스펀지를 만드는 서로 다른 두 가지 공정에서의 셀룰로스 분자들의 분해정도를 결정, 비교할 수 있었다.

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이성분 나노유체($H_2O$/LiBr+나노입자)를 적용한 유하박막 흡수기의 열 및 물질전달 촉진 실험 (An Experimental Study on Falling Film Heat and Mass Transfer for Binary Nanofluids ($H_2O$/LiBr+Nanoparticles))

  • 김현대;김성수;남상철;정진희;강용태
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2008년도 하계학술발표대회 논문집
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    • pp.130-135
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    • 2008
  • The objectives of this study are to investigate the combined heat and mass transfer enhancement using binary nanofluids as the working fluids in a $H_2O$/LiBr absorber. The result of heat and mass transfer experiment with the additives(Arabicgum, 2E1H) showed that the heat and mass transfer performance of binary nanofluid with 2E1H enhanced significantly in comparison with that without additive. In the case of 0.01wt% $Al_2O_3$ binary nanofluids with 2E1H, the vapor absorption rate increased up to 77% in comparison with that without additive. The heat transfer rate of 0.01wt% $Al_2O_3$ binary nanofluids with 2E1H increased up to 19%. Based on the experimental results, it is recommended that the $Al_2O_3$ binary nanofluid be good with 2E1H to improve the heat and mass transfer performance.

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이중 효용과 일중 효용을 복합한 다단 재생 고효율 흡수식 냉동 사이클 개발 (Development of High Efficiency Cycle by Combining Double-Effect with Single-Effect Absorption Chiller Systems)

  • 윤상국
    • 설비공학논문집
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    • 제29권7호
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    • pp.360-365
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    • 2017
  • Recently, development efforts of triple-effect absorption chiller have been increased in order to improve the efficiency of double-effect absorption chiller. However, triple-effect absorption chiller has some disadvantages, including high corrosion characteristic of LiBr solution at high temperature of $200^{\circ}C$. Moreover, it is necessary to develop new components for operation under high pressure of 2 bars even though COP is increased to 1.6 or 1.7. The objective of this study was to introduce a new system by combining double effect absorption chiller with single effect absorption chiller with multi-generators using bypass flow of LiBr dilute solution to $3^{rd}$ generator to overcome the disadvantages of triple-effect chiller and improve energy efficiency. Results indicate that the new absorption cycle had a much higher efficiency than double-effect chiller system, showing significant improvement when bypass solution flow rate of 25% was applied to the $3^{rd}$ generator using the main dilute solution of the absorber. The COP of the new chiller system was found to be 1.438, which was 21.7% higher than that (1.18) of the present double-effect system. The COP was decreased when solution by-pass rate to the $3^{rd}$ generator was increased. In addition, lower cooling water temperature caused higher COP. Therefore, the multi-generator system with by-pass solution might be an excellent chiller alternative to triple-effect absorption chiller with higher efficiency.