• 신재생에너지
• /
• 제16권4호
• /
• pp.1-8
• /
• 2020

The possibility of conversion to the RC-MAT propulsion system (gasoline engine → electric motor) was studied. However, as commercial battery capacities are low. it is not possible to change the propulsion system. Nevertheless, development of nex-generation batteries is necessary for high capacity and high energy density. Although Li/S batteries are theoretically suitable as new generation batteries, these batteries are not composed of only Li and S. Hence, ensuring high energy density can be difficult. Moreover, electrolytes are important components in the study of energy density; hence, the battery by Li2S8 Molarity was sorted. There are no studied on its various electrode components. In this study, a Li/S battery was fabricated using an assorted 3D sulfur electrode of high energy density and its electrochemical properties were studied. The Li/S battery has a high energy density of 468 Wh/kg at 1.28 M Li2S8 (A805-1.28). Its capacity rapidly decreased after 1 cycle with more than 1 M Li2S8.

• 한국군사과학기술학회지
• /
• 제14권4호
• /
• pp.740-746
• /
• 2011

Thermally activated batteries have good stability, reliability and long shelf life. Due to these characteristics and operational mechanism, thermal batteries are usually applied to military power sources. Especially, Li/$FeS_2$ thermal batteries, which are used mostly in these days, use LiCl-KCl and LiBr-LiCl-LiF as electrolytes. The electrochemistry of thermal batteries have been researched for long time, however, electrochemical study using impedance spectroscopy was not published so much. Through this research, microscopic electrochemical research was investigated with electrochemical impedance spectroscopy(E.I.S). Electrolyte effects on Li/$FeS_2$ thermal battery was researched changing electrolytes, LiCl-KCl and LiBr-LiCl-LiF. Additionally, the salts, which are added to electrolytes, effects on thermal battery were researched. It is expected that the impedance spectroscopy analysis is applicable to not only thermal battery electrochemical study effectively, but also, thermal battery developments.

• 전기화학회지
• /
• 제2권2호
• /
• pp.88-92
• /
• 1999

리튬이온전지용 $LiCoO_2$ 전극의 도전재료인 흑연과 블랙에 대하여 도전재료 함량에 따른 복합체 전극의 겉보기 밀도, 전해액 중에서 집전체로부터 전극복합체의 자기박리 및 전자전도 저항 특성을 조사하였다. $LiCoO_2$복합전극의 겉보기 밀도는 도전재료의 함량 증가에 따라 감소하였으며, 복합체 중 $LiCoO_2$ 단독의 겉보기 밀도는 보다 큰 감소를 나타내었다. $4.7\%w/w$ 이상의 super s black 도전재료를 사용한 전극은 propylene carbonate와 diethyl carbonate의 1: 1 체적비 혼합용매 중의 1 mol/I $LiPF_6$ 전해액 함침으로 자기박리하였으며, 흑연 도전재료에서는 자기박리가 없었다 복합전극의 전자전도에 대한 비저항은 도전재료의 함량 증가에 따라 감소하였으며, super s black도전재료 $2\~3\%w/w$ 함량의 비저항은 Lonza KS6흑연 도전재료 $12\%w/w$ 함량의 비저항과 유사하였다. 본 연구에서 나타낸 범위 내에서 super s black도전재료를 사용할 때 전극 복합체 중의 $LiCoO_2$밀도가 높아 고용량을 나타내었다.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1996년도 하계학술대회 논문집 C
• /
• pp.1412-1413
• /
• 1996

Li ion battery have many advantages such as high energy density, high voltage and low self discharge, so it will replace conventional Ni/Cd battery. But, charge-discharge characterization of Li battery is controlled by weight ratio of electrodes (Cathode/Anode). So, we performed a study on relation between charge/discharge characterization and weight ratio (cathode/anode).

• 한국수소및신에너지학회논문집
• /
• 제13권4호
• /
• pp.259-269
• /
• 2002

A battery based on the lithium/elemental sulfur redox couple has the advantage of high theoretical specific capacity of 1,675 mAh/g-sulfur. However, Li/S battery has bad cyclic durability at room temperature due to sulfur active material loss resulting from lithium polysulfide dissolution. To improve the cycle life of Li/S battery, PEGDME (Poly(ethylene glycol) dimethyl ether) 500 containing 1M LiTFSI salt which has high viscosity was used as electrolyte to retard the polysulfide dissolution and nano-sized $Mg_{0.6}Ni_{0.4}O$ was added to sulfur cathode as additive to adsorb soluble polysulfide within sulfur cathode. From experimental results, the improvement of the capacity and cycle life of Li/S battery was observed( maximum discharge capacity : 1,185 mAh/g-sulfur, C50/C1 = 85 % ). Through the charge-discharge test, we knew that PEGDME 500 played a role of preventing incomplete charge-discharge $behavior^{1,2)$. And then, in sulfur dissolution analysis and rate capability test, we first confirmed that nano-sized $Mg_{0.6}Ni_{0.4}O$ had polysulfide adsorbing effect and catalytic effect of promoting the Li/S redox reaction. In addition, from BET surface area analysis, we also verified that it played the part of increasing the porosity of sulfur cathode.

• 한국전기전자재료학회논문지
• /
• 제22권7호
• /
• pp.576-579
• /
• 2009

This paper suggests a autonomous linear Li-ion battery charger which can safely distribute power between an external power source(AC adapter, auto adapter, or USB source), battery, and the system load. Depending on an external power source's capability, the charger selects proper charging-mode automatically. The charger IC designed and fabricated on Dongbu HITEC's $0.35{\mu}m$ BCD process with layers of one poly and three metals.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2009년도 춘계학술대회 논문집
• /
• pp.27-28
• /
• 2009

This paper suggests a autonomous linear Li-ion battery charger which can safely distribute power between an external power source(AC adapter, auto adapter, or USB source), battery, and the system load. Depending on an external power source's capability, the charger selects proper charging-mode automatically. The charger IC designed and fabricated on Dongbu HITEC's $0.35{\mu}m$ BCD process with layers of one poly and three metals.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1994년도 추계학술대회 논문집 학회본부
• /
• pp.205-208
• /
• 1994

The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li secondary battery. PEO-$LiClO_4$ electrolyte with plasticizer is very unstable. Passivation phenomena in polymer electrolyte cell was described by the SPL model. The time dependance of the impedance indicates that a passivation layer grows rapidly on the Li surface. However, the growing of passivation layer on the Li surface can be restrained by addition of zeolite to the PEO electrolyte. It suggested that addition of zeoliteto to the PEO-$LiClO_4$ electrolyte effectively controls the formation of a passivation layer on Li electrode.

• Transactions on Electrical and Electronic Materials
• /
• 제18권5호
• /
• pp.237-245
• /
• 2017

A novel battery model based on the manufacturer datasheet is proposed. According to this model, not only the steady state but also the dynamic charging performance of the Li-ion battery can be analyzed and evaluated. The major advantage of our model is that all the parameters can be directly obtained from the datasheet and no additional experiments are required. Moreover, the transition between charge and discharge stages was analyzed based on our model, and a novel Simulink module was built to predict the energy consumption of a battery-powered system. Experiments were carried out to verify the model accuracy. Although the new model was developed for the Li-ion battery, it is expected to be applicable to other batteries.

• 한국산학기술학회논문지
• /
• 제15권7호
• /
• pp.4692-4697
• /
• 2014

태양광 전원은 태양광 패널이 설치된 지역의 위치와 날씨 그리고 기후 등에 매우 큰 영향을 받으며, 전원으로서의 사용시간의 제한과 출력의 불확실성이라는 특성을 갖는다. 이러한 태양광 전원의 불확실성을 가능한 줄이기 위해, 태양광 전원의 출력에 대한 오랜 기간 동안의 데이터를 분석하여 출력의 평균값을 산출해 내었다. 태양광 전원의 출력의 평균값은 태양광 전원에 직접 연결되어 그리드에 안정적인 전력을 공급하기 위한 Li 에너지 저장장치의 적정 용량산정과 운용방식에 꼭 필요한 데이터이며, 이로부터 Li 배터리의 충방전모드에 의해 그리드에 일정한 출력의 전력을 공급하는 것이 가능하도록 하였다. 태양광 전원과 Li 배터리를 포함하는 시스템이 악조건의 그리드 운전상태에서의 동작특성을 관찰하기 위해 Li 배터리의 충전율이 100%에서 10%로 단시간에 감소될 정도의 과부하 상태에 대해 태양광 전원과 Li 배터리의 운용특성을 분석하고 Li 배터리 셀 단위의 출력 및 온도특성을 해석하였다.