• Title/Summary/Keyword: Li reduction

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Fabrication of LiDAR-detectable Plate-type Black Materials and Application in Hydrophilic Paints (라이다 센서에 인지되는 판상형 검은색 소재의 제조 및 친수성 도료로의 응용)

  • Jiwon Kim;Minki Sa;Chan-Gyo Kim;Ha-Yeong Kim;Yeon-Ryong Chu;Suk Jekal;Chang-Min Yoon
    • Journal of Adhesion and Interface
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    • v.24 no.3
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    • pp.95-99
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    • 2023
  • In this study, LiDAR-detectable black materials are synthesized by coating and reduction of titanium dioxide onto plate-type natural mica, which evaluated practical LiDAR verification. In detail, black TiO2@Mica materials are fabricated by utilizing a sol-gel reaction to coat titanium dioxide onto natural mica, followed by reduction using sodium tetrahydridoborate. Subsequently, Black TiO2@Mica materials are dispersed in hydrophilic transparent varnish and sprayed onto the glass substrate to assess applicability as paints. As a result, Black TiO2@Mica-based paints exhibit true blackness (L*=12.1) and a higher NIR reflectance (30.2 R%). In addition, it was confirmed that as-synthesized Black TiO2@Mica materials are successfully recognized by a LiDAR sensor. This phenomenon is attributed to Fresnel's reflection law, in which light reflection occurs at the interface between natural mica and titanium dioxide with different refractive indices. In this regard, the findings of the study are expected to contribute to the potential utilization of LiDAR-detectable materials in various fields such as autonomous vehicles, robotics, and drones.

Effects of Korean Medicine Treatments on Pain Reduction of Thoracolumbar Compression Fracture Patients : A Restrospective Observational Study (흉추 및 요추 압박골절 환자의 통증 감소에 대한 한의학적 치료 효과 : 후향적 관찰연구)

  • Oh, Seung Joon;Jo, Dong Chan;Li, Yu Chen;Lee, Eun Jung
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.32 no.4
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    • pp.283-290
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    • 2018
  • The aim of the study was to investigate the effect of Korean medicine treatments on pain reduction of thoracolumbar compression fracture patients. We analysed 48 patients who have been diagnosed as thoracolumbar compression fracture on Computed Tomography(CT) or Magnetic Resonance Imaging(MRI) scan and had admitted to Dunsan Korean Medical hospital from January 1,2014 to April 4, 2017. The analysis was conducted as retrospective study which analyzes patient's medical records. Statistical analysis was performed using the IBM SPSS statistics 24 program. We used Visual Analog Scale(VAS) and pain reduction scale to evaluate pain reduction of patients. The result showed that there were statistically significant pain reduction on thoracolumbar compression fracture patients treated with korean medicine treatments. In conclusion, we found that the korean medicine treatments showed positive effect on pain reduction of thoracolumbar compression fracture patients.

Electrochemical Reduction Process for Pyroprocessing (파이로프로세싱을 위한 전해환원 공정기술 개발)

  • Choi, Eun-Young;Hong, Sun-Seok;Park, Wooshin;Im, Hun Suk;Oh, Seung-Chul;Won, Chan Yeon;Cha, Ju-Sun;Hur, Jin-Mok
    • Korean Chemical Engineering Research
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    • v.52 no.3
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    • pp.279-288
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    • 2014
  • Nuclear energy is expected to meet the growing energy demand while avoiding CO2 emission. However, the problem of accumulating spent fuel from current nuclear power plants which is mainly composed of uranium oxides should be addressed. One of the most practical solutions is to reduce the spent oxide fuel and recycle it. Next-generation fuel cycles demand innovative features such as a reduction of the environmental load, improved safety, efficient recycling of resources, and feasible economics. Pyroprocessing based on molten salt electrolysis is one of the key technologies for reducing the amount of spent nuclear fuel and destroying toxic waste products, such as the long-life fission products. The oxide reduction process based on the electrochemical reduction in a LiCl-$Li_2O$ electrolyte has been developed for the volume reduction of PWR (Pressurized Water Reactor) spent fuels and for providing metal feeds for the electrorefining process. To speed up the electrochemical reduction process, the influences of the feed form for the cathode and the type of anode shroud on the reduction rate were investigated.

Asymptotic Test for Dimensionality in Sliced Inverse Regression (분할 역회귀모형에서 차원결정을 위한 점근검정법)

  • Park, Chang-Sun;Kwak, Jae-Guen
    • The Korean Journal of Applied Statistics
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    • v.18 no.2
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    • pp.381-393
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    • 2005
  • As a promising technique for dimension reduction in regression analysis, Sliced Inverse Regression (SIR) and an associated chi-square test for dimensionality were introduced by Li (1991). However, Li's test needs assumption of Normality for predictors and found to be heavily dependent on the number of slices. We will provide a unified asymptotic test for determining the dimensionality of the SIR model which is based on the probabilistic principal component analysis and free of normality assumption on predictors. Illustrative results with simulated and real examples will also be provided.

EFFECTS OF PROCESS PARAMETERS ON GRAIN SIZE DURING ISOTHERMAL FORGING OF A TC6 ALLOY

  • Miaoquan LI;Aiming XIONG;Shankun XUE;Yuanchun LI;Hai LIN;Hairong WANG;Shaobo SU;Lichuang SHEN
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2003.10b
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    • pp.47-50
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    • 2003
  • Grain size of the $\alpha$ phase is computed during isothermal forging of the TC6 aerofoil blade, by combining FE with the Yada's model of grain size. The present results illustrate the grain size and distribution of the $\alpha$ phase during isothermal forging of the TC6 aerofoil blade' in detail. The computed results show that height reduction, deformation temperature, hammer velocity and friction have significant effect on distribution of the equivalent strain, and that height reduction, deformation temperature and hammer velocity have more significant effect on grain size of the $\alpha$ phase than friction between billet and die.

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Analysis of Cell Performance with Varied Electrolyte Species and Amounts in a Molten Carbonate Fuel Cell

  • Lee, Ki-Jeong;Kim, Yu-Jeong;Koomson, Samuel;Lee, Choong-Gon
    • Journal of Electrochemical Science and Technology
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    • v.9 no.2
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    • pp.141-148
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    • 2018
  • This study evaluated the performance characteristics of varied electrolyte species and amounts in a molten carbonate fuel cell (MCFC). Coin-type MCFCs were used at the condition of $650^{\circ}C$ and 1 atm. In order to measure the effects of varied electrolyte species and amounts, electrolytes of $(Li+K)_2CO_3$ and $(Li+Na)_2CO_3$ were selected and the amounts of 1.5 g, 2.0 g, 3.0 g, and 4.0 g were used. Insignificant performance differences were observed in the cell using different electrolytes, but the cell performance was sensitive to the amount of the electrolyte used. The pore-filling ratio (PFR), a ratio of pore filling in the components by the liquid carbonate electrolytes, was used to determine the optimum performance range. Consequently, 77% PFR demonstrated the optimum performance for both electrolytes. Thus, the MCFC had a permissible but narrow optimum performance range. The remaining amounts of electrolyte in the cells were determined using the weight reduction ratio (WRR) method after several hours of cell operation. The WRR used the relationship between the initial loaded amount of electrolyte and weight reduction of components in 10 wt% acetic acid. The relationships were linear and identical between the two electrolyte species.

Deposition of Functional Organic and Inorganic Layer on the Cathode for the Improved Electrochemical Performance of Li-S Battery

  • Sohn, Hiesang
    • Korean Chemical Engineering Research
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    • v.55 no.4
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    • pp.483-489
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    • 2017
  • The loss of the sulfur cathode material through dissolution of the polysulfide into electrolyte causes a significant capacity reduction of the lithium-sulfur cell during the charge-discharge reaction, thereby debilitating the electrochemical performance of the cell. We addressed this problem by using a chemical and physical approach called reduction of polysulfide dissolution through direct coating functional inorganic (graphene oxide) or organic layer (polyethylene oxide) on electrode, since the deposition of external functional layer can chemically interact with polysulfide and physically prevent the leakage of lithium polysulfide out of the electrode. Through this approach, we obtained a composite electrode for a lithium-sulfur battery (sulfur: 60%) coated with uniform and thin external functional layers where the thin external layer was coated on the electrode by solution coating and drying by a subsequent heat treatment at low temperature (${\sim}80^{\circ}C$). The external functional layer, such as inorganic or organic layer, not only alleviates the dissolution of the polysulfide electrolyte during the charging/discharging through physical layer formation, but also makes a chemical interaction between the polysulfide and the functional layer. As-formed lithium-sulfur battery exhibits stable cycling electrochemical performance during charging and discharging at a reversible capacity of 700~1187 mAh/g at 0.1 C (1 C = 1675 mA/g) for 30 cycles or more.

Integral Analysis of the Effects of Non-absorbable gases on the Heat Mass Transfer of Laminar Falling Film

  • Kim, Byong-Joo
    • International Journal of Air-Conditioning and Refrigeration
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    • v.6
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    • pp.56-66
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    • 1998
  • The absorption process of water vapor in a liquid film is an important process in LiBr-Water absorption system. The composition of the gas phase, in which a non-absorbable gas is combined with the absorbate, influences the transport characteristics. In the present work, the absorption processes of water vapor into aqueous solutions of lithium bromide in the presence of non-absorbable gas are investigated. The continuity, momentum, energy and diffusion equations for the solution film and gas are formulated in integral forms and solved numerically. It is found that the mass transfer resistance in gas phase increases with the concentration of non-absorbable gas. However the primary resistance to mass transfer is in the liquid phase. As the concentration of non-absorbable gas in the absorbate increases, the interfacial temperature and concentration of absorbate in solution decrease, which results in the reduction of absorption rate. The reduction of mass transfer rate is found to be significant for the addition of a small amount of non-absorbable gas to the pure vapor, especially at the outlet of tube where the non-absorbable gas accumulates. At higher non-absorbable gas concentration, the decrease of absorption rate seems to be linear to the concentration of non-absorbable gas.

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Numerical studies on the effects of the lateral boundary on soil-structure interaction in homogeneous soil foundations

  • Li, Z.N.;Li, Q.S.;Lou, M.L.
    • Structural Engineering and Mechanics
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    • v.20 no.4
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    • pp.421-434
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    • 2005
  • In this paper, the finite element method is applied to investigate the effect of the lateral boundary in homogenous soil on the seismic response of a superstructure. Some influencing factors are presented and discussed, and several parameters are identified to be important for conducting soil-structure interaction experiments on shaking tables. Numerical results show that the cross-section width L, thickness H, wave propagation velocity and lateral boundaries of soil layer have certain influences on the computational accuracy. The dimensionless parameter L/H is the most significant one among the influencing factors. In other words, a greater depth of soil layer near the foundation should be considered in shaking table tests as the thickness of the soil layer increases, which can be regarded as a linear relationship approximately. It is also found that the wave propagation velocity in soil layer affects the numerical accuracy and it is suggested to consider a greater depth of the soil layer as the wave propagation velocity increases. A numerical study on a soil-structure experimental model with a rubber ring surrounding the soil on a shaking table is also conducted. It is found the rubber ring has great effect on the soil-structure interaction experiments on shaking table. The experimental precision can be improved by reasonably choosing the elastic parameter and width of the rubber ring.

Electrochemical Characteristics of Ru Added Li4Ti5O12 as an Anode Material (Ru를 첨가한 음극활물질 Li4Ti5O12의 전기화학적 특성)

  • Cho, Woo-Ram;Na, Byung-Ki
    • Clean Technology
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    • v.20 no.4
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    • pp.433-438
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    • 2014
  • There is an increasing interest in the development of rechargeable batteries suitable for use in both hybrid electric vehicles and energy storage systems that require higher charge & discharge rates, bigger battery sizes and increased safety of the batteries. Spinel-type lithium titanium oxide ($Li_4Ti_5O_{12}$) as a potential anode for lithium ion batteries has many advantages. It is a zero-strain materials and it experiences no structural change during the charge/discharge precess. Thus, it has long cycle life due to its structural integrity. It also offers a stable operation voltage of approximately 1.55 V versus $Li^+/Li$, above the reduction potential of most organic electrolyte. In this study, Ru added $Li_4Ti_5O_{12}$ composites were synthesized by solid state process. The characteristics of active material were investigated with TGA-DTA, XRD, SEM and charge/discharge test. The capacity was reduced when Ru was added, however, the polarization decreased. The capacity rate of $Li_4Ti_5O_{12}$ with Ru (3%, 4%) addition was reduced during the charge/discharge precess with 10 C-rate as a high current density.