• Title/Summary/Keyword: Li excess

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Jet-grouting in ground improvement and rotary grouting pile installation: Theoretical analysis

  • Wang, You;Li, Lin;Li, Jingpei;Sun, De'an
    • Geomechanics and Engineering
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    • v.21 no.3
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    • pp.279-288
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    • 2020
  • The permeation grouting is a commonly used technique to improve the engineering geology condition of the soft ground. It is of great significance to predict the permeation range of the grout so as to ensure the effects of grouting. This paper conducts a theoretical analysis of jet-grouting effects in ground improvement and rotary grouting pile installation by utilizing deformation-permeation coupled poroelastic solutions based on Biot's theory and Laplace-Fourier integral transform technique. The exponential function and the intermittent trigonometric function are chosen to represent time-dependent grouting pressure usually encountered in ground improvement and rotary grouting pile installation process, respectively. The results, including the radial displacement, the hoop stress, the excess pore fluid pressure, the radial discharge, and the permeation radius of grout, are presented for different grouting time, radial positions and grouting lengths. Parametric study is conducted to explore the effects of variation of the exponent in the exponential grouting pressure-time relationship on grouting-induced responses. It is expected that the proposed solutions can be used to estimate the permeation range of grouting in ground improvement and rotary grouting pile installation.

Target Preparation for KLN sputtering and optical properties of thin films deposited on Corning 1737 glass (KLN 스퍼터링용 타겟의 제조 및 코닝 1737 유리 기판위에 성장시킨 박막의 광학적 성질)

  • Park, Seong-Geun;Seo, Jeong-Hun;Kim, Seong-Yeon;Jeon, Byeong-Eok;Kim, Jin-Su;Kim, Ji-Hyeon;Choe, Si-Yeong;Kim, Gi-Wan
    • Korean Journal of Materials Research
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    • v.11 no.3
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    • pp.178-184
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    • 2001
  • Transparent and highly oriented KLN thin films have been grown by an rf- magnetron sputtering deposition method. A homogeneous and stable KLN target was prepared by calcine and sintering process. For KLN target, stoichiometry and composition excess with K of 30% and 60%, and Li of 15% and 30% respectively, was prepared. The targets were sintered at low temperature to prevent vaporization of K and Li. KLN thin films were fabricated by rf-magnetron sputtering method using those targets. In this experiment, using the target of composition excessed with K of 60% and Li of 30%, single phase KLN thin film was produced. KLN thin film has excellent crystallinity and highly c-axis oriented on Corning 1737 substrate. Transmittance of thin film in visible range was 90%, absorption edge is 333 nm and refractive index at 632.8 nm was 1.93.

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Effects of In on the Precipitation Phenomena of Al-2.1Li-2.9Cu Alloy by Differential Scanning Calorimetry (열분석법에 의한 Al-2.1Li-2.9Cu합금이 석출현상에 미치는 In 첨가의 영향)

  • Park, Tae-Won;Song, Young-Beum;Lee, Yong-Yun
    • Journal of the Korean Society for Heat Treatment
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    • v.10 no.4
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    • pp.237-245
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    • 1997
  • A study was conducted to examine the effects of In addition on the precipitation behaviors of Al-2.1Li-2.9Cu alloy by differential scanning calorimetry, transmission electron microscopy and micro-hardness tester. DSC analysis was measured over the temperature range of $25{\sim}550^{\circ}C$ at a heating rate of $2{\sim}20^{\circ}C$/min. The heat evolution peaks due to the formation of GP zone and ${\delta}$'phase shift to higher temperature and the peaks to $T_1$ and ${\theta}$'phases shift to lower temperature by In addition. From this result, it was proved that the formation of GP zone and ${\delta}$'phase is suppresed whereas that of $T_1$ and ${\theta}$'phases are accelerated by the In addition of 0.15wt%. The age hardening curve aged at $190^{\circ}C$ showed that the In bearing alloy(alloy B) has more faster age hardening response and a higher peak hardness than In-free alloy(alloy A), attributed to the fine and homogeneous distribution of $T_1$ and ${\theta}$'phases. The activation energies for the formation of ${\delta}$'phase in In-free and In-bearing alloys are 22.3kcal/mol and 18.6kcal/mol, respectively. Those for $T_1(+{\theta}^{\prime})$ phase of In-free and In-bearing alloys are 24.3 and 37.5kcal/mol, respectively. Quenched-in excess vacancies play an important role to the formation of precipitates.

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Piezoelectric and Dielectric Characteristics of PMN-PNN-PZT Ceramics According to the amount of PbO (PbO량에 따른 PMN-PNN-PZT 세라믹스의 유전 및 압전특성)

  • Kim, Do-Hyung;Kim, Kook-Jin;Yoo, Ju-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.219-220
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    • 2006
  • In this study, m order to develop multilayer ceramics vibrator for ultrasonic nozzle, PMN-PNN-PZT ceramics were fabricated using $Li_2CO_3-Na_2CO_3$ as sintering aids and their piezoelectric and dielectric characteristics were investigated according to the aomunt of PbO. With increasing PbO contents. secondary phases were increased and phase structure were changed from tetragonal structure to rhombohedral structure and also electromechanical coupling factor were linearly decreased. At the composition ceramics with the sintering temperature of $870^{\circ}C$ and 1 mol% excess PbO, density, electromechanical coupling factor, dielectric constant, piezoelectric d constant and mechanical quality factor showed the optimum value of $7.879g/cm^2$, 0.55, 1149, 328pC/N, 1224, respectively for multilayer ceramics vibrator application for ultrasonic nozzle.

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Submerged Culture of Phanerochaete chrysosporium and Lignin Peroxidase Production (Phanerochaete chrysosporium의 액체 배양 및 Lignin Peroxidase 생산)

  • Park, Se-Keun;Jeong, Myoung-Sun;Kim, Yeong-Kwan
    • Journal of Industrial Technology
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    • v.21 no.A
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    • pp.343-349
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    • 2001
  • This study characterizes the growth of white rot fungi Phanerochaete chrysosporium IFO 31249) and lignin peroxidase(LiP) activity in different submerged culture media. P. chrysosporium was grown in the form of pellet of various sizes from a spore inoculum under shaking liquid culture condition. While the growth of mycelia was higher under the nitrogen-sufficient culture than under the nitrogen-limited culture, ligninase activity was relatively lower. The lignin peroxidase appeared in nitrogen-limited culture and was suppressed by excess nitrogen. High level(40U/l) of lignin peroxidase activity was obtained in the growth medium containing 1.5mM veratryl alcohol, a secondary metabolite of P. chrysosporium. Lignin peroxidase production was not observed under conditions of nitrogen sufficiency or in balanced media, suggesting that control parameters could increase the activity by manipulating the secondary metabolism.

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APPLICATION OF STABLE EMULSIONS TO LIPASE IMMOBILISED MEMBRANE REACTORS FOR KINETIC RESOLUTION OF RACEMIC ESTERS

  • Giorno, Lidietta;Na, Li;Drioli, Enrico
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.07a
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    • pp.65-68
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    • 2003
  • The paper discusses the use of stable emulsion, prepared by membrane emulsification technology, to improve the enantiocatalytic performance of immobilised lipase in multiphasic membrane reactors. The production of optical pure (S)-naproxen from racemic naproxen methyl ester has been used as model reaction system. The enzyme was immobilised in the sponge layer (shell side) of capillary polyamide membrane with 50 kDa cut-off, The O/W emulsion, containing the substrate in the organic dispersed phase, was fed to the enzyme membrane reactor from shell-to-lumen. The results evidenced that lipase maintained stable activity during all the operation time (more than 250 hours), showing an enantiomeric excess (96 $\pm$2%) comparable to the free enzyme (98 $\pm$ 1%) and much higher compared to similar lipase-loaded membrane reactors used in two-separate phase systems (90%). The study showed that immobilised enzymes can achieve high stability as well as high catalytic activity and enantioselectivity.

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Modeling and characterization of beryllium reflector elements under irradiation conditions

  • Ahmed H. Elhefnawy;Mohamed A. Gaheen;Hanaa H. Abou Gabal;Mohamed E. Nagy
    • Nuclear Engineering and Technology
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    • v.55 no.12
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    • pp.4583-4590
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    • 2023
  • This study aims at modeling the beryllium reflector poisoning under neutron irradiation conditions and calculating the impact of beryllium poisoning on the core parameters of ETRR-2 research reactor. The CITVAP code was used to calculate the neutron flux and parameters of ETRR-2 core with beryllium reflector elements. The neutron flux in each reflector element was calculated to solve the modeling equations for the atomic densities of lithium-6 (6Li), tritium-3 (3H), and helium-3 (3He) using the BERYL program. The results are discussed based on CITVAP calculations of the core excess reactivity and cycle length Full Power Days (FPD). Possible solutions to minimize the degradation due to beryllium poisoning are also discussed and compared based on calculations.

A Literature Study on the Application of Sa-am Acupuncture for the Treatment of Stroke (중풍(中風)에 대한 사암침법(舍岩鍼法)의 운용(運用)에 관한 문헌(文獻) 연구 - ${\ll}$사암침구정전(舍岩鍼灸正傳)${\gg}$${\ll}$동의보감(東醫寶鑑)${\gg}$${\ll}$침구대성(鍼灸大成)${\gg}$과의 비교연구 -)

  • Lee, Jung-Tae;Yim, Yun-Kyoung
    • Journal of Acupuncture Research
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    • v.23 no.5
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    • pp.115-125
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    • 2006
  • Objectives & methods : This study aimed to investigate and compare the traditional acupuncture treatment and Sa-am acupuncture treatment of stroke. We investigated ${\ll}$Sa-am chimgujeongjeon(舍岩鍼灸正傳)${\gg}$ for Sa-am acupuncture treatment, and ${\ll}$Dongeuibogam(東醫寶鑑)${\gg}$ and ${\ll}$Chimgudaesung (鍼灸大成)${\gg}$ for traditional acupuncture treatment. Results & Conclusion : 1. In the traditional acupuncture treatment, acupoints on CV, GV, GB, LI, ST meridians to remove pathogens such as fire, damp, phlegm, blood stagnation and Ashi points (nearby points) are often used rather than acupoints according to the diagnosis of excess & deficiency in organs and meridians. 2. In ${\ll}$Sa-am chimgujungjeon(舍岩鍼灸正傳)${\gg}$, symptoms of stroke are classified into 21 and each symptoms are analyzed according to the diagnosis of excess & deficiency of organs and meridians, consequently treated using tonification & sedation of corresponding meridians. 3. For the treatment of stroke in ${\ll}$Sa-am chimgujungjeon(舍岩鍼灸正傳)${\gg}$, tonification & sedation of the acupoints on related meridian is often omitted, using only the acupoints on targeted meridian. 4. In ${\ll}$Sa-am chimgujungjeon(舍岩鍼灸正傳)${\gg}$, empirical points are preferably used for the treatment of stroke.

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A Study on the life of Yoon Cho Chang(尹草窓) and Cho-Chang-Kyeul(草窓訣) (윤초창(尹草窓)의 생애(生涯)와 초창결(草窓訣)에 관(關) 연구(硏究))

  • Kim, Joon Tae;Yoon, Chang Yeul
    • Journal of Korean Medical classics
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    • v.6
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    • pp.189-227
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    • 1993
  • I have studied life of Yoon-Dong-Li(尹東里), who applied Un-Ki(運氣) theory to medicine during Suk-Jong(肅宗) to Joong-Jo(正祖) in Yi-Dynasty and also studied his existing writings named ${\ll}$Cho-Chang-kyeol${\gg}$ (草窓訣). The referenced original work prints were based on 1980's print of Chung-Ku oriental medical society and National Central Library and The academy a korean studies possessed print. Studied with these books, I have concluded as follows. 1. Yoon-Dong-Li(尹東里) courtesy name is Ja-Mi(子美), pen name is Cho-Chang(草窓). He was born in 1705, Suk-Jong(肅宗) 31yrs, and died in 1784, Jeong-Jo(正祖) 8yrs in Yi-Dynasty. He had lineage of third-generationed-doctor and learned medicine from his uncle, Yoon-Woo-Kyo(尹雨敎). His father Yoon-Yi-Kyo(尹이敎) gaved him second influence. 2. Confucianal physician in Ming Dynasty You-Bu(劉溥) respected Ju-Ryeom-Kye(周溓溪), confucianist in Song-Dynasty and You-Bu(劉溥) does not removed grass in front of window (because in chinese, Cho-Charig(草窓) means grass in front of window), and named himself Cho-Chang(草窓). Yoon-Dong-Li(尹東里) followed this suit so called himself Cho-Chang (草窓). 3. The main contents of ${\ll}$Cho-Chang-Kyeol${\gg}$ (草窓訣), (運氣衍論) was written in 1725, when Yoon-Dong-Li(尹東里) was 21yrs old and printed in 1736. The other part of ${\ll}$Cho-Chang-Kyeol${\gg}$ (草窓訣), (用藥篇) was written in 1746. These two parts were not written in the satre time. The (運氣衍論) was written llyears earlier than (用藥). Two parts were combined another day and named (草窓訣). 4. Existing ${\ll}$Cho-Chang-Kyeol${\gg}$ (草窓訣) is transcribed printing with the con tent of "Five elements motion and the six kind of natural factors theory" (五運六氣設). Each edition is generally similar in content, but also has different points each other so naw we hardly finds a complete set of works. 5. ${\ll}$Cho-Chang-Kyeol${\gg}$ (草窓訣) is a first technical book which treats of Un-Ki(運氣) theory in korea. 6. The contents of (運氣衍論) of ${\ll}$Cho-Chang-Kyeol${\gg}$ (草窓訣) is mechanism of diease according to excess and insuffciency of five elements motion and six kinds of nalural faclors.and symploms and priscriptions, includes variated priscriptions. 7. Two parts in (運氣衍論) of ${\ll}$Cho-Chang-Kyeol${\gg}$ (草窓訣), 'Sang-tong' (相通) and 'Kak-Tong' (各通), threats of mochanisim of the disease according to five elements. with the principle of inter-promoting and inter-acting, in the change of ten heavenly stems and five elements motion. 8. In the (用藥篇) of ${\ll}$Cho-Chang-Kyeol${\gg}$ (草窓訣) describes priscription for clinical application according to Un-Ki(運氣) and also records about misuse of medicine. 9. In the ${\ll}$Cho-Chang-Kyeol${\gg}$ (草窓訣), most of priscription are common using one, which also found in ${\ll}$Dong-$\breve{U}$i-Bo-Garm${\gg}$ (東醫寶鑑) and there are few of priscriptions hy Yoon-Dong-Li(尹東里).

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Synthesis of SnSb alloys using high energy ball-miiling and its lithium electrochemical behavior (고에너지 볼밀을 이용한 SnSb 합금 분말 제조와 리튬 전기화학적 특성)

  • Kim, Dae Kyung;Lee, Hyukjae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.5
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    • pp.191-198
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    • 2018
  • SnSb alloy powders with excess Sn or Sb are fabricated by the high energy ball-milling of pure Sn and Sb powders with different Sn/Sb molar ratios, and then their material properties and lithium electrochemical performances are investigated. It is revealed by X-ray diffraction that SnSb alloys are successfully synthesized, and the powder size is decreased via ball-milling. Charge-discharge test using a coin-cell shows that the best result, in terms of the cyclability and the capacity after 50 cycles, comes from the electrode composed of Sn : Sb = 4 : 6, i.e. the capacity of $580mAh\;g^{-1}$ after 50 cycles. When the electrode is composed of Sn : Sb = 3 : 7, however, the capacity is noticeably decreased by the restrained Sn reaction with Li-ion. The pure SnSb alloy powders (Sn : Sb = 5 : 5) results in the second best performance. In the case of Sn-rich SnSb alloys, the initial capacity is relatively high, but the capacity is quickly fading after 20 cycles.