• Proceedings of the KIEE Conference
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• 1994.07b
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• pp.1229-1232
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• 1994

The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li secondary battery. This paper describes the effects of lithium salts, plasticizer addition and temperature dependence of conductivity of PEO electrolytes. Polyethylene oxide(PEO) based polymer electrolyte films were prepared by solution casting an acetonitrile solution of preweighed PEO and Li salt. After solvent evaporation, the electrolyte films were vacuum-dried at $60^{\circ}C$ for 48h, the thickness of the films were $90{\sim}110{\mu}m$. The conductivity properties of prepared PEO electrolytes are summarized as follows. PEO electrolyte complexed with $LiClO_4$ shows the better conductivity of the others. $PEO-LiClO_4$ electrolyte when $EO/Li^+$ ratio is 8, showed the best conductivity. Optimum operating temperature of PEO electrolyte is $60^{\circ}C$. By adding propylene carbonate and ethylene carbonate to $PEO-LiClO_4$ electrolyte, its conductivity was higher than $PEO-LiClO_4$ without those. Also $PEO_8LiClO_4$ electrolyte remains static up to 4.5V vs. $Li/Li^+$.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.07a
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• pp.474-477
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• 2001

The properties of LiMnO$_2$ was studied as a cathode active material for lithium polymer batteries. LiMnO$_2$ cathode active materials were synthesized by the reaction of LiOH . $H_2O$ and Mn$_2$O$_3$at various temperature under argon atmosphere. For lithium polymer battery applications, the LiMnO$_2$cell was characterized electrochemically by charge-discharge experiments and a.c. impedance spectroscopy. And the relationship between the characteristics of powders and electrochemical properties was studied in this research. A maximum discharge capacity of 160-170 mAh/g for ο-LiMnO$_2$ cell was achieved. Used that SP270 as electric active material in LiMnO$_2$, it is excellent than property of electric active material used Acetylene black or KS6 at charge/discharge capacity.

• Journal of Electrical Engineering and Technology
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• v.7 no.6
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• pp.932-939
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• 2012

This paper presents an equivalent circuit model of a LIPB (Li-Ion Polymer battery) for Hybrid Electric Vehicles (HEVs). The proposed equivalent circuit can be used to predict the charging/discharging characteristics in time domain as well as the impedance characteristic analysis in frequency domain. Based on these features, a one-cell model is established as a function of Depth of Discharge (DoD), and a 48-cell model for a battery pack was also established. It was confirmed by experiment that the proposed model predict the discharging and impedance (AC) characteristics quite accurately at different constant current levels. To check the usefulness of the proposed circuit, the model was used to simulate a motor driving circuit with an Insulated Gate Bipolar Transistor (IGBT) inverter and Brushless DC (BLDC) motor, and it is confirmed that the model can calculate the battery voltage fluctuation in time domain at different DoDs.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.42 no.4
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• pp.855-863
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• 2017

Because Li-ion battery and Li-Polymer battery have high-energy storage density, they are used for various electronic devices such as electronic cigarette, electronic bicycle, drone, second battery, even golf cart and electronic car. Recently, however, battery explosion is sometimes occurring on electronic devices using Li-ion battery and is becoming serious as bodily harm is breaking out due to explosion. For this, this paper described the Li-ion Battery's operating principles and verified the cause of explosion by overload tests caused by the high-energy storage density. According to the these experiments, we conducted a study to develope scanning techniques of fire and safety measures.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.13 no.4
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• pp.306-311
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• 2000

The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li polymer battery. The temperature dependence of conductivity impedance spectroscopy and electrochemical properties of PDF/PAN electrolytes as a function of a mixed ratio were reported for PVDF/PAN based polymer electrolyte films which were prepared by thermal gellification method of preweighed PVDF/PAN plasticizer and Li salt. The conductivity of PVDF/PAN electrolytes was 10$\^$-3/S/cm. 20PVDF5PEN LiCiO$\_$4//PC$\_$10//EC$\_$10/ electrolyte has the better conductivity compared to others. 20PVDF5PANLICIO$\_$4//PC$\_$10//EC$\_$10/ electroylte remains stable up to 5V vs. Li/Li$\^$+/. Steady state current method and ac impedance were used for the determination of transference numbers in PVDF/PAN electrolyte film. The transference number of 20PVDF5PANLiCO$\^$4//PC$\_$10//EC$\_$10/ electrolyte is 0.48.

• Journal of the Korean Electrochemical Society
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• v.2 no.1
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• pp.1-4
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• 1999

A lithium ion battery with polymer electrolyte is expected as a safe and long cycle life battery. This paper reports primarily the recent development results of a solid polymer electrolyte, which is a key factor of the secondary battery system, that has been obtained during the process of the development of a polymer type lithium battery. As a successful result of the solid polymer electrolyte. The ionic conductivity of the solid polymer electrolyte, which is composed of polyacrylonitrile and $LiClO_4\;with\; Al_2O_3$ dissolved as the supporting electrolyte, has been confirmed to be $2.3\times10^{-4} S/cm$ at room temperature.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.15 no.2
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• pp.162-168
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• 2002

The purpose of this study is to research and develop LiMnO$_2$-organic and Li$_{0.3}$MnO$_{2}$-organic composite with high energy density for Lithium ion polymer battery. This paper describes cyclic voltammetry, impedance sepctroscopy, electrochemical properties of LiMnO$_2$-organic and Li$_{0.3}$MnO$_{2}$-organic composite with polymer electrolyte as a function of a mixed ratio. The first discharge capacity of LiMnO$_2$-PAn with 3 wt.% PAn was 83mHA/g, while that of Li$_{0.3}$MnO$_{2}$-PPy composite was 136 mAh/g. The Ah efficiency was above 98% after the 2nd cycle. The LiMnO$_2$-PAn with DMcT 2 wt.% and Li$_{0.3}$MnO$_{2}$-PPy composites cathode with 5wt. PPy in PVDF-PC-EC-LiClO$_4$ electrolyte showed good capaity with cycling. The discharge capacity of LiMnO$_2$-PAn with wt.% DMcT was 80 and 130 mAh/g at 1st and 12th cycle, respectively. The capacity of LiMnO$_2$-PAn composite with 2 wt.% DMcT was higher than that of LiMnO$_2$-PAn composite.mposite.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11b
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• pp.541-544
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• 2001

Orthorhombic $LiMnO_2$ was synthesized by solid-state reaction using $LiOH{\cdot}H_{2}O$ and $Mn_{2}O_{3}$ as starting material. Its electrochemical properties as cathode in lithium batteries were examined. X-ray diiffraction revealed that the $LiMnO_2$ compound showed a well-defined orthorhombic phase of a space group with Pmnm. The capacity of $LiMnO_2$ agreed well with its specific surface area and grinding treatment was effective in improving cycling performance. For lithium polymer battery applications. the $LiMnO_2$ cell was characterized electrochemically by charge-discharge experiments. And the relationship between the characteristics of powder and electrochemical properties was studied in this research. A maximum discharge capacity of $160-170mAhg^{-1}$ for $LiMnO_2/Li$ cell was achieved.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11a
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• pp.541-544
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• 2001

Orthorhombic LiMnO$_2$ was synthesized by solid-state reaction using LiOH$.$H$_2$O and Mn$_2$O$_3$ as starting material. Its electrochemical properties as cathode in lithium batteries were examined. X-ray diffraction revealed that the LiMnO$_2$ compound showed a well-defined orthorhombic phase of a space group with Pmnm. The capacity of LiMnO$_2$ agreed well with its specific surface area and grinding treatment was effective in improving cycling performance. For lithium polymer battery applications, the LiMnO$_2$ cell was characterized electrochemically by charge-discharge experiments. And the relationship between the characteristics of powder and electrochemical properties was studied in this research. A maximum discharge capacity of 160-170mAhg$^{-1}$ for LiMnO$_2$/Li cell was achieved

• Bulletin of the Korean Chemical Society
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• v.23 no.8
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• pp.1144-1148
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• 2002

We prepared the polyaniline (Pani) film and powder by chemical polymerization and doping with different dopants and also investigated the capability of Li//polyaniline cells after assembling. The oxidation/reduction potentials and electrochemical reaction of Li//polyaniline cells were tested by cyclic voltammetry technique. The Li//Pani-HCl cells with 10% and 20% conductors show a little larger specific discharge capacities than that without conductor. The highest discharge capacity of almost 50 mAh/g at 100th cycle is also achieved. However, Li//Pani-LiPF6 with 20% conductor shows a remarkable performance of ~90 mAh/g at 100th cycle. This is feasible value for using as the positive electrode material of lithium ion secondary batteries. It is also proved that the powder type electrode of Pani is better to use than the film type one to improve the specific discharge capacity and its stability with cycle.