• 대한금속재료학회지
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• 제50권9호
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• pp.645-651
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• 2012

This study investigated changes in phase fraction caused by the addition of Mo, as well as the subsequent behaviour of N and its effect on the mechanical properties of welded 24Cr-N duplex stainless steel weld metals. Filler metal was produced by fixing the contents of Cr, Ni, N, and Mn while adjusting the Mo content to 1.4, 2.5, 3.5 wt%. The delta ferrite fraction increased as the Mo content increased. In contrast, the ${\gamma}$ fraction decreased and changed from a round to an acicular shape. Secondary austenite (${\gamma}^{\prime}$) was observed in all specimens in a refined form, but it decreased as the Mo content increased to the extent that it was nearly impossible to find any secondary austenite at 3.5 wt% Mo. Both tensile and yield strengths increased with the addition of Mo. In contrast, the highest value of ductility was observed at 1.41 wt% Mo. At all temperatures, impact energy absorption showed the lowest value at 3.5 wt% Mo, at which the amount of ${\delta}$-ferrite was greatest. There was no significant temperature dependence of the impact energy absorption values for any of the specimens. As the fraction of ${\gamma}$ phase decreased, the amount of N stacked in the ${\gamma}$ phase increased. Consequently, the stacking fault energy decreased, while the hardness of ${\gamma}$ increased.

• 한국철도학회논문집
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• 제13권3호
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• pp.264-270
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• 2010

본 연구에서는 역사 내 철도 안전 감시 시스템의 최적 디스플레이 설계를 위하여 생태학적 인터페이스 디자인(EID, Ecological Interface Design) 프레임웍을 적용하였다. 특히, EID 개발을 위한 가장 선행적 연구인 작업 영역 분석(WDA, Work Domain Analysis)을 실시하였다. 먼저 WDA를 위한 시스템 경계를 도시철도의 역사 내 안전 감시 시스템으로 설정하고, Abstraction Hierarchy (AH)를 이용하여 역무원의 작업 환경을 분석하였다. AH 결과 역무원이 작업 환경에서 얻게 되는 정보의 흐름을 다섯 단계의 수준(Functional Purpose, Values and Priority Measures, Purpose-related Functions, Object-related Process, Physical Object)으로 전개할 수 있었고, 각각의 수준의 정보로 이루어진 작업 영역 모델(WDM, Work Domain Model)을 얻었다. 이 WDM이 도시철도 안전 감시 시스템의 작업 환경을 얼마나 반영하는지 평가하기 위하여 10년 이상의 역무실 직무 경험이 있는 전문가를 대상으로 Scenario Mapping법을 실시하였다. 평가된 WDM을 바탕으로 현재 역사 내 안전 감시 시스템이 제공하고 있는 정보는 물론이고, 현재 안전 감시 시스템이 제공해주고 있지 못하는 13개의 요구 정보를 추가로 추출하였다. 이렇게 추출된 요구 정보는 도시철도 안전 감시 시스템의 EID에 반드시 반영되어야 할 필수적인 정보로 활용될 수 있다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 춘계학술대회 논문집 전자세라믹스 센서 및 박막재료 반도체재료 일렉트렛트 및 응용기술
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• pp.117-120
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• 2000

The relation of crystal phase and charge/discharge capacity of $Li[Li_yMn_{2-y}]O_4$ were studied for different degrees of Li substitution (y). All cathode material showed spinel phase based on cubic phase in X-ray diffraction. Other peaks didn't show in spite of the increase of y value in $Li[Li_yMn_{2-y}]O_4$. Ununiform of $Li[Li_yMn_{2-y}]O_4$ which calcinated by (111) face and (222) face was more stable than that of pure $LiMn_2O_4$. In addition, At TG analysis, calcined $Li[Li_{0.1}Mn_{1.9}]O_4$ exhibited much mass loss at $800{\mu}m$. The cycle performance of the $Li(Li_yMn_{2-y}]O_4$ was improved by the substitution of $Li^{1+}$ for $Mn^{3+}$ in the octahedral sites. Specially, $Li[Li_{0.08}Mn_{1.92}]O_4$ and $Li[Li_{0.1}Mn_{1.9}]O_4$ cathode materials showed the charge and discharge capacity of about 125mAh/g at first cycle, and about 95mAh/g after 70th cycle. It is excellent than that of pure $LiMn_2O_4$, which 125mAh/g at first cycle, 65mAh/g at 70th.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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• pp.288-288
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• 2013

Lithium-ion battery (LIB) is one of the most important rechargeable battery and portable energy storage for the electric digital devices. In particular, study about the higher energy capacity and longer cycle life is intensively studied because of applications in mobile electronics and electric vehicles. Generally, the LIB's capacity can be improved by replacing anode materials with high capacitance. The graphite, common anode materials, has a good cyclability but shows limitations of capacity (~374 mAh/g). On the contrary, silicon (Si) and germanium(Ge), which is same group elements, are promising candidate for high-performance LIB electrodes because it has a higher theoretical specific capacity. (Si:4200 mAh/g, Ge:1600 mAh/g) However, it is well known that Si volume change by 400% upon full lithiation (lithium insertion into Si), which result in a mechanical pulverization and poor capacity retention during cycling. Therefore, variety of nanostructure group IV elements, including nanoparticles, nanowires, and hollow nanospheres, can be promising solution about the critical issues associated with the large volume change. However, the fundamental research about correlation between the composition and structure for LIB anode is not studied yet. Herein, we successfully synthesized various structure of nanowire such as Si-Ge, Ge-Carbon and Si-graphene core-shell types and analyzed the properties of LIB. Nanowires (NWs) were grown on stainless steel substrates using Au catalyst via VLS (Vapor Liquid Solid) mechanism. And, core-shell NWs were grown by VS (Vapor-Solid) process on the surface of NWs. In order to characterize it, we used FE-SEM, HR-TEM, and Raman spectroscopy. We measured battery property of various nanostructures for checking the capacity and cyclability by cell-tester.

• Bulletin of the Korean Chemical Society
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• 제29권8호
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• pp.1565-1568
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• 2008

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 2011년도 정기 학술대회
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• pp.187-190
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• 2011

방파제 설계시 고려되는 파랑하중에 대한 설계 방법으로 기존 설계는 정수압만을 고려한 정적해석을 실시하였으며 최근 설계에서는 정정해석과 동적해석을 동시에 실시하고 있다. 하지만 이때의 동적해석 방법은 파랑하중에 의한 파압을 구조물내의 임의의 지점에서만 산정하여 등가파압으로 적용하여 해석을 하고 있다. 본 연구에서는 방파제의 경사면뿐만 아니라 해저지반에서의 파압을 추가적으로 고려함과 동시에 등 가파압이 아닌 모든 절점에서의 파압을 산정하여 파압을 적용하였다. 그 결과 현재의 설계법과 본연구의 설계법으로 구한 침하량의 값이 상당한 차이를 나타내고 있다.

• 한국재료학회지
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• 제11권4호
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• pp.294-299
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• 2001

기계적 합금화 방법을 이용하여 제작한 Ni-MH 전지용 $Mg_2$Ni전극의 표면 불화처리에 대한 전기화학적 충.방전 특성이 조사되었다. 20시간 밀링을 통해 제조된 $Mg_2$Ni합금은 나노결정을 가졌으며 그 $Mg_2$Ni전극의 KOH전해질내에서 충.방전 실험 결과, 초기 방전 용량이 280mAh/g이상으로 증가하였으나 10cyc1e이내에 급격히 퇴화되었다. 전극표면에서 지속적이고 안정한 불화층 형성을 목적으로 KOH용액에 잉여의 불소이온이 첨가된 $Mg_2$Ni전극의 내구성은 크게 향상되었으며 특히 2N KF를 첨가했을 경우 전극의 내구성이 가장 크게 향상되었다. 고율 방전실험의 경우도 그 성능이 90-100mAh/g으로 유지되었다 이러한 내구성 향상의 이유는 표면에 얕고 다공성인 $Mg_2$Ni층의 형성으로 인해 퇴화의 주요인인 Mg(OH)$_2$의 생성이 억제되었기 때문이었다. Effects of the surface fluorination on the electrochemical charge-discharge properties of $Mg_2$Ni electrode in Ni-MH batteries fabricated by mechanical alloying were investigated. After 20h ball milling, Mg and Ni powder formed nanocrystalline $Mg_2$Ni. Discharge capacity of this alloy increased greatly at first one cycle, but due to the formation of Mg(OH)$_2$ passive layer, it showed a rapid degradation in alkaline solution within 10cyc1es. In case of 6N KOH +xN KF electrolyte (x = 0.5, 1, 2), a continuous and stable fluorinated layer formed by adding excess F$^{-}$ ion, increased durability of $Mg_2$Ni electrode greatly and high rate discharge capability(90-100mAh/g). 2N KF addition led to the highest durability of all tested here. The reason of the improvement is due to thin MgF$_2$, which can prevent the $Mg_2$Ni electrode from forming Mg(OH)$_2$layer that is the main cause of degradation.

• Bulletin of the Korean Chemical Society
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• 제32권5호
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• pp.1491-1494
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• 2011

Lithium vanadium phosphate, $Li_3V_2(PO_4)_3$ was prepared by a simple solid state route. It was found that making a fine powder of $Li_3V_2(PO_4)_3$ by the mechanical milling is very effective for increasing the insertion/extraction of lithium from $Li_3V_2(PO_4)_3$ structure. In charge/discharge test, the ball-milled $Li_3V_2(PO_4)_3$ sample exhibited a higher initial discharge capacity of 174 mAh/g in the voltage range of 3.0-4.8 V, compared with pure $Li_3V_2(PO_4)_3$ sample (152 mAh/g). Furthermore, the ball-milled $Li_3V_2(PO_4)_3$ presented not only higher cycle retention rate after 50 cycles, but also better rate capability compared with pure sample in the whole region (0.1-7 C).

• 대한예방의학회:학술대회논문집
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• 대한예방의학회 1995년도 제47차 추계 학술대회 연제집
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• pp.267-268
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• 1995

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 2000년도 제15차 학술회의논문집
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• pp.458-458
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• 2000

Quick evaluations of two in-plane orbit maneuvers using small see of real-time CPS navigation solutions were peformed lot the KOMPSAT-1 spacecraft operation. Real-time GPS navigation solutions of the KOMPSAT-1 were collected during the Korean Ground Station(KGS) pass. Only a few sets of position and velocity data after completion of the thruster firing were used for the quick maneuver evaluations. The results were used for antenna pointing data predictions for the next station contact. Normal orbit maneuver evaluations using large see of playback GPS navigation solutions were also performed and the result were compared with the quick evaluation results.