• Journal of the Korean Society of Combustion
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• v.17 no.4
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• pp.5-10
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• 2012

The reformer system is a chemical device that drives the conversion of hydrocarbon to hydrogen rich gas under high temperature environment($600-1,000^{\circ}C$). Generally, NG(Natural Gas) or AOG(Anode Off Gas) is used as fuel of fuel cell reformer combustion system. The experimental study to analyze the combustion characteristics of a premixed ceramic burner used for 0.5-1.0 kW fuel cell reformer was performed. Ceramic burner experiments using NG and AOG were carried out to investigate the flame stability characteristics by heating capacity, equivalence ratio and different fuels respectively. The results show that surface flames can be classified into green, red, blue and lift-off flames as the equivalence ratio of methane-air mixture decreases. And the stable flames can be established using NG and AOG as reformer fuel in the perforated ceramic burner. In particular, the blue flame is found to be stable at a lean equivalence ratio under different mixture conditions of NG and AOG for the 0.5 to 1.0 kW fuel cell system power range. NOx emission is under 60 ppm between 0.70 to 0.78 of equivalence ratio and CO emission is under 50 ppm between 0.70 to 0.84 of equivalence ratio.

• Journal of Mechanical Science and Technology
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• v.19 no.6
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• pp.1366-1377
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• 2005

Experimental study was carried out in an atmospheric pressure, laboratory-scale dump combustor showing features of combustion instabilities. Flame structure and heat release rates were obtained from OH emission spectroscopy. Qualitative comparisons were made between line-integrated OH chemiluminescence image and Abel-transformed one. Local Rayleigh index distributions were also examined. Mean temperature, normalized standard deviation and temperature fluctuations were measured by coherent anti-Stokes Raman spectroscopy (CARS). To see the periodic behavior of oscillating flames, phase-resolved measurements were performed with respect to the pressure wave in the combustor. Results on system damping and driving characteristics were provided as a function of equivalence ratio. It also could be observed that phase resolved temperatures have been changed in a well-defined manner, while its difference between maximum and minimum reached up to 280K. These results would be expected to play an important role in better understanding of driving mechanisms and thermo-acoustic interactions.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.1
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• pp.47-58
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• 2023

Experimental data conducted by Colson et al. and numerical data conducted in this study were compared through counterflow flames to understand of the characteristic of basic flame about mixture of ammonia/methane. In order to use the suitable numerical mechanism, the validation was performed using total four mechanisms and the Okafor's mechanism showed satisfactory experimental results. The extinction boundary of the stability map could be explained through the effective Lewis number and the trend of LeD. The extinction behavior of the flame was different under the lean and rich symmetric conditions and it was investigated by the major variables, global strain rate (a_g) and mole fraction of ammonia (Ω_NH3).

• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.2
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• pp.179-188
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• 2011

Experiments were conducted in a constant-pressure combustion chamber to investigate the effects of hydrocarbon addition on cellular instabilities of syngas-air flames. The measured laminar burning velocities were compared with the predicted results computed using reliable kinetic mechanisms with detailed transport and chemistry. The cellular instabilities that included hydrodynamic and diffusional-thermal instabilities of the hydrocarbon-added syngas-air flames were identified and evaluated. Further, experimentally measured critical Peclet numbers for fuel-lean flames were compared with the predicted results. Experimental results showed that the laminar burning velocities decreased significantly with an increase in the amount of hydrocarbon added in the reactant mixtures. With addition of propane and butane, the propensity for cell formation was significantly diminished whereas the cellular instabilities for methane-added syngas-air flames were not suppressed.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.10
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• pp.1193-1201
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• 2004

The effect of equivalence ratio and fuel/air mixing quality on the phase-resolved gas temperatures at different phases of the oscillating pressure cycle was experimentally investigated. An atmospheric pressure, optically accessible and laboratory-scale dump combustor operating on methane with heat release rate of 1.59kW was used. Temperature measurements were made using coherent anti-Stokes Raman spectroscopy (CARS) at several spatial locations fur typical unstable combustion conditions. Analysis was conducted using parameters such as phase-resolved averaged temperature, normalized standard deviation and temperature probability distribution functions (PDFs). Also the probability on the occurrence of high temperature (over 1900K) was investigated to get the information on the perturbation of equivalence ratio and NOx emission characteristics. It was shown that most of temperature histograms exhibit Gaussian profile which has short breadth of temperature fluctuation at equivalence ratio of 0.6, while beta profile was predominant for the cases of other equivalence ratios (${\Phi}$=0.55, 0.50). It was also shown that phase-resolved averaged temperature oscillated in phase with pressure cycle, while normalized standard deviations which represent temporal turbulent intensity of temperature showed nearly constant value around 0.1. The characteristics on the occurrence of high temperature also displayed periodic wave form which was very similar to the pressure signal. And the amplitude of this profile went larger as the fuel/air mixing quality became poorer. These also provided additional information on the perturbation of equivalence ratio at flame as well as NOx emission characteristics.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• v.y2005m4
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• pp.274-280
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• 2005

Experimental investigations were carried out in an atmospheric pressure, optically accessible and laboratory-scale dump combustor. The objective of this study is to obtain the phase-resolved gas temperatures at different phases of the oscillating pressure cycle during unstable combustion. To see the effect of incomplete fuel-air mixing on phase-resolved temperature characteristics, CARS temperature measurements were performed. Results including phase-resolved averaged temperature, normalized standard deviation and temperature probability distribution functions (PDFs) were provided in this paper. It could be found that the profile of mean temperature showed the in-phase relationship with pressure cycle. Temperature PDFs give an insight on the flame behavior as well as NOx emission characteristics. These results would be expected to play an important role in better understanding of driving mechanisms and thermo-acoustic interactions.

• Journal of Energy Engineering
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• v.13 no.2
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• pp.144-151
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• 2004

Stabilization and reduction of combustion noise and NOx emission from dry low NOx combustor of GE MS7001F gas turbine were achieved. Dry low NOx gas turbines that adopt the lean premixed combustion technology frequently generate the flame instability and high NOx emissions if not adequately tuned. Dynamic pressure oscillation during the combustion mode transfer increased as ambient temperature decreased with frequency of 80㎐ and magnitude of 4-9 psi. Effects of both combustor tuning for uniform fuel flow with burner nozzles and fuel pre-filling into transfer fuel valves on stabilisation of the dry low NOx combustor were very significant. Dynamic pressure oscillation during the combustion mode change was decreased up to 2.5 psi. Also, NOx emission from GE7F DLN-1 combustor can be maintained as low as 35-43ppm (15% O$_2$) in base load operation of 150 MW.

• Journal of the Korean Society of Propulsion Engineers
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• v.19 no.4
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• pp.15-23
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• 2015

This study predicts the basic characteristics of combustion instabilities in a gas turbine lean premixed combustor using ASCI3D code which is a FEM(Finite Element Method)-based Helmholtz solver. The prediction results show the good agreement with the measured data in modeling the overall combustion instability features, however, the code is found to overpredict the unstable conditions. As one of the efforts to improve the model accuracy, the effects of acoustic boundary conditions on the instability growth rate are analyzed. As a result, it is shown that the acoustic reflection coefficient has a great impact on the instability and the prediction accuracy can be enhanced by defining the precise acoustic conditions.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.26 no.4
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• pp.555-560
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• 2002

Numerical simulations of freely propagating flames burning stoichiometric CH$_4$/O$_2$/$N_2$mixtures are performed at atmospheric pressure in order to understand the effect of the $O_2$enrichment level on CH$_4$/Air flame. A chemical kinetic mechanism is employed, the adopted scheme involving 54 gas-phase species and 632 forward reactions. The calculated flame speeds are compared with the experiments for the flames established at several $O_2$enrichment level, the results of which is in excellent agreement. As a result of the increased $O_2$enrichment level from 0.21 to 1, the mole fraction of CO in the burred gas is increased. The flame speed and the temperature in the burned gas are also increased, but the thickness of the flame is severely shrunken in the preheat region. The maximum of the calculated EINO is obtained around 0.6 and 0.7 of the $O_2$enrichment level in cases of flames for fuel-lean mixtures.

• 한국연소학회:학술대회논문집
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• 2003.12a
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• pp.103-108
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• 2003

The effect of equivalence ratio and fuel/air mixing quality on the phase-resolved gas temperatures at different phases of the oscillating pressure cycle was experimentally investigated. An atmospheric pressure, optically accessible and laboratory-scale dump combustor operating on methane with heat release rate of 1.59kW was used. Temperature measurements were made using coherent anti-Stokes Raman spectroscopy (CARS) at several spatial locations for typical unstable combustion conditions. Analysis was conducted using parameters such as phase-resolved averaged temperature, normalized standard deviation and temperature probability distribution functions (PDFs). Also the probability on the occurrence of high temperature (over 1900K) was investigated to get the information on the perturbation of equivalence ratio and NOx emission characteristics. It was shown that most of temperature histograms exhibit Gaussian profile which has short breadth of temperature fluctuation at equivalence ratio of 0.6, while beta profile was predominant for the cases of other equivalence ratios (${\Phi}$=0.55, 0.50). The characteristics on the occurrence of high temperature also displayed periodic wave form which is very similar to the pressure signal. And the amplitude of this profile goes larger as the fuel/air mixing quality become poorer. These also provided additional information on the perturbation of equivalence ratio at flame as well as NOx emission characteristics.