• Title/Summary/Keyword: Lead ion

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Analysis and quantification of DNA photoadducts by HPLC/ion trap mass spectrometry

  • Zhang, Guangyu;Linscheid, Michael
    • Proceedings of the SCSK Conference
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    • 2003.09b
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    • pp.405-406
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    • 2003
  • DNA is known as the genetic material in cells. Various environmental factors can cause DNA damages. One of them is sunlight. The life on earth depends on the sunlight, but on the other hand, the UV light in sunlight can cause skin DNA damages. When these damages are not fully repaired before replication, they can lead to mutations of oncogenes and tumour suppressor gene and result in photo carcinogenesis, in the end, skin cancer.(omitted)

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Adsorption of $\textrm{Pb}_{2+}$ in the components of bacterial cell membrane

  • Kim, Mal-Nam
    • Journal of Microbiology
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    • v.33 no.4
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    • pp.278-282
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    • 1995
  • S. epidermidis cell was fractionated into cell wall, cell membrane and cytoplasm. The cell membrane adsorbed the most abundant $\textrm{Pb}_{2+}$ per unit dry weight of the three fractions tested. Adsorption behavior of $\textrm{Pb}_{2+}$ in lipid and protein, which are the main components of the cell membrane, indicated that phosphatidylethanolamine and phosphatidylinositol having phosphoryl group and gangliosides containing carboxyl groups adsorbed much more $\textrm{Pb}_{2+}$ than triglycerides lacking any chargeable functional groups. Protein purified from cell membrane adsorbed larger amount of $\textrm{Pb}_{2+}$ than total native cell membrane or cell membrane lipid.

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Removal of Lead Ions from Aqueous Solution Using Juniperus chinenensis Waste (폐향나무를 이용한 수용액에서 납 이온 제거)

  • Choi, Suk Soon
    • Applied Chemistry for Engineering
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    • v.24 no.4
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    • pp.428-432
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    • 2013
  • From the forest areas in Chungbuk, large amounts of wood wastes by pruning are generated, however most of them considered as by-products are not treated properly with no disposal options. In this work, among diverse wood wastes such as Quercus variabillis, Juniperus chinensis, Larix kaemoferi, and Pinus densiflora, Juniperus chinensis was found to be more effective biosorbent for the removal of lead ions than other wood wastes. Also, the enhancement of lead removal efficiency from the aqueous phase was investigated using Juniperus chinensis waste. It was observed that the optimal initial pH to increase the removal efficiency of 20 mg/L lead ions was 4.0 and the optimal dosage concentration with regard to the biosorbent for the enhanced removal of 50 mg/L lead ions was 0.6 g/100 mL. In addition, chemical treatment of Juniperus chinensis waste with sulfuric acid was required to improve the adsorption capacity for high lead concentrations (over 100 mg/L). When Juniperus chinensis waste was chemically treated with 6 M sulfuric acid, the adsorption quantities of lead ions were 180, 340, and 425 mg/g with regard to 200, 400, and 500 mg/L lead ions concentrations, respectively. These results indicate that the practical biosorbent technology developed in this study is a highly efficient method to treat the lead ion from an aqueous solution.

Feasibility Study of Vertical Multileaf Collimator for Determination of Irradiation Size (수직형 다엽 콜리메이터의 방사선 조사면 크기 결정을 통한 유용성 연구)

  • Lee, Chang-Yeol;Son, Ki-Hong;Shin, Sang-Hun;Park, Seung-Woo;Lee, Dong-Han;Jung, Hai-Jo;Choi, Mun-Sik;Oh, Won-Young;Kim, Kum-Bae;Yang, Gwang-Mo;Ji, Young-Hoon
    • Progress in Medical Physics
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    • v.22 no.1
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    • pp.3-11
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    • 2011
  • The purpose of this study was to evaluate feasibility of Vertical Multileaf Collimator for determination of irradiation size using Vertical Multileaf Collimator and lead block to determine 4 different irradiation shape in case of Co-60 gamma-ray and 6 MV X-ray. We chose ion chamber, glass dosimeter and EBT chromic film to compare with Vertical Multileaf Collimator results and lead block results. In case of Co-60 gamma-ray and 6 MV X-ray, the central axis point dose normalized at reference field of lead block with ion chamber results for Vertical Multileaf Collimator were estimated higher than lead block about 5.1%, 4.2%. In case of Co-60 gamma-ray, the central axis point dose normalized at reference field of lead block with glass dosimeter results for Vertical Multileaf Collimator were estimated higher than lead block about 2.2%, 7.8%, 7.2%, 4.0% for reference, circle, triangle, cross field, respectively. In case of 6 MV X-ray, the central axis point dose normalized at reference field of lead block with glass dosimeter results for Vertical Multileaf Collimator were estimated higher than lead block about 6.7%, 6.2%, 3.8%, 6.2% for reference, circle, triangle, cross field, respectively. The results of EBT chromic film, Vertical Multileaf Collimator of penumbra size for all irradiation shape was smaller than lead block of those size that 2.0~3.5 mm for Co-60 gamma-ray, 0.5~1.0 mm for 6 MV X-ray. The results from this study, radiation treatment volume that results in shielding block can be minimized. In addition, during radiation treatment for 2, 3-dimensional radiation therapy using a Vertical Multileaf Collimator of this survey can be used to determine variety of irradiation fields.

Resistance In Chloride ion Penetration and Pore Structure of Concrete Containing Pozzolanic Admixtures (포졸란재 함유 콘크리트의 세공구조와 염화물이온 침투 저항성)

  • 소양섭;소형석
    • Journal of the Korea Concrete Institute
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    • v.14 no.1
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    • pp.100-109
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    • 2002
  • Significant damage to concrete results from the intrusion of corrosive solutions, for example, dissolved chlorides corrode reinforcing steel and cause spatting. Effectively blocks the penetration of these solutions will eliminate or greatly reduce this damage and lead to increased durability. This study is to investigate the effects of pozzolanic admixtures, fly ash and silica fume, and a blast furnace slag on the chloride ion penetration of concretes. The main experimental variables wore the water-cementitious material ratios, the types and amount of admixtures, and the curing time. And it is tested for the porosity and pore size distributions of cement paste, chloride ion permeability based on electrical conductance, and 180-day ponding test for chloride intrusion. The results show that the resistance of concrete to the penetration of chloride ions increases as the w/c was decreased, and the increasing of curing time. Also, concrete with pozzolans exhibited higher resistance to chloride ion penetration than the plain concrete. The significant reduction in chloride ion permeability(charge passed) of concrete with pozzolans due to formation of a discontinuous macro-pore system which inhibits flow. It is shown that there is a relationship between chloride ion permeability and depth of chloride ion penetration of concrete, based on the pore structure (porosity and pore size distributions) of cement paste.

The Effect of pH on Citric Acid Leaching of Soil Contaminated with Heavy Metals (중금속(重金屬) 오염토양(汚染土壤)의 구산(枸酸) 침출(浸出)에 대한 pH의 영향(影響))

  • Jung, Kyungbae;Park, Hongki;Yoo, Kyoungkeun;Park, Jay Hyun;Choi, Ui Kyu
    • Resources Recycling
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    • v.22 no.5
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    • pp.13-19
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    • 2013
  • The effect of pH on the citrate leaching behavior of heavy metal ion was investigated to develop an eco-friendly process for removing heavy metals from soil contaminated with copper, zinc, and lead. The leaching tests were performed using citrate solution with pH adjusted by mixing citric acid and sodium citrate under the following leaching conditions: particle size, under $75{\mu}m$; temperature, $50^{\circ}C$; citrate concentration, $1kmol/m^3$; pulp density, 5%; shaking speed, 100 rpm; leaching time, 1 hour. The difference of pH before and after the leaching test was not observed, and this result indicates the direct effect of hydrogen ion concentration on the leaching of metals was insignificant. The removal ratios of copper, zinc, and lead from the contaminated soil decreased with increasing pH. The thermodynamic calculation suggests that the leaching behaviors of metal ions were determined by two reactions; one is the reaction to form complex ions between heavy metal ions and citrate ion species, and the other is the reaction to form metal hydroxide between heavy metal ions and hydroxide ion.

Damage Characteristics of Metal Specimens by Formaldehyde (포름알데히드에 의한 금속시편의 손상 특성)

  • Kim, Myoung Nam;Lim, Bo A;Lee, Sun Myung
    • Journal of Conservation Science
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    • v.31 no.3
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    • pp.287-298
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    • 2015
  • The formaldehyde is damage to the metal are known universally. However, the quantification of the damage level and degree of damage is not clear. This study was conducted to test the following steps using a gas corrosion tester, and then evaluated by the optical, chemical and physical measurement. First, it was confirmed the damage level of the metal specimen(silver, copper, iron, lead, brass) by the formaldehyde(0.5, 1, 10, 100, 500ppm). Second, weighted damage to the metal specimens were tested according to the temperature and humidity conditions under damage levels. Third, the damage of accelerated degradation metal specimens were examined under damage levles. As a result, at 500ppm / day, the optical, chemical and physical damage of lead have been identified, the optical damage of all metals are was observed. The optical damage of some specimens were weighted in $25^{\circ}C-50%$, $30^{\circ}C-50%$. Chemical damage to the lead specimen is 2.8 times, 1.3 times were weighted in $30^{\circ}C-80%$, $25^{\circ}C-80%$. Referring to formate ion concentration of the accelerated degradation metal, corrosion products of iron and brass were actived the reaction of the formaldehyde gas, oxide film of lead was blocked the reaction of formaldehyde gas.

Surface Complexation of Cationic Metal Adsorption Onto Amorphous Aluminum Oxide (무정형 알루미늄 산화물에 의한 양이온 중금속의 표면착화)

  • Park, Youn-Jong;Yang, Jae-Kyu;Choi, Sang-Il
    • Journal of Soil and Groundwater Environment
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    • v.13 no.1
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    • pp.101-109
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    • 2008
  • The adsorption characteristics of cationic metals such as copper, cadmium, and lead onto the amorphous aluminum oxide, AMA-L, which was mineralized from raw sanding powder at $550^{\circ}C$ were investigated. Additionally, surface complexation reaction of cationic heavy metals onto AMA-L was simulated with MINEQL + software employing a diffuse layer model. From the batch adsorption tests in a single element system, the adsorption affinity of each metal ion onto AMA-L was following order: lead > copper > cadmium. In a binary system composed with copper and cadmium, quite a similar adsorption affinity was observed in each metal ion compared to the single element system. When the surface complexation constants obtained in the single system were used in the prediction of experimental adsorption results, model predictions were well fitted with experimental results of both single and binary systems.

Ion Migration Failure Mechanism for Organic PCB under Biased HAST (고온고습 전압인가(Biased HAST) 시험에서 인쇄회로기판의 이온 마이그레이션 불량 메커니즘)

  • Huh, Seok-Hwan;Shin, An-Seob;Ham, Suk-Jin
    • Journal of the Microelectronics and Packaging Society
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    • v.22 no.1
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    • pp.43-49
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    • 2015
  • By the trends of electronic package to be smaller, thinner and more integrative, organic printed circuit board is required to be finer Cu trace pitch. This paper reports on a study of failure mechanism for PCB with fine Cu trace pitch using biased HAST. In weibull analysis of the biased HAST lifetime, it is found that the acceleration factor (AF) of between $135^{\circ}C/90%RH/3.3V$ and $130^{\circ}C/85%RH/3.3V$ is 2.079. A focused ion beam (FIB) was used to polish the cross sections to reveal details of the microstructure of the failure mode. It is found that $Cu_xO/Cu(OH)_2$ colloids and Cu dendrites were formed at anode (+) and at cathode (-), respectively. Thus, this gives the evidence that Cu dendrites formed at cathode by $Cu^{2+}$ ion migration lead to a short failure between a pair of Cu nets.

Adsorption of Uranium (VI) Ion on Synthetic Resin Adsorbent with Styrene Hazardous Materials (Styrene 위험물을 포함한 합성수지 흡착제에 의한 우라늄(VI) 이온의 흡착)

  • Kim, Joon-Tae
    • Applied Chemistry for Engineering
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    • v.20 no.2
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    • pp.165-171
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    • 2009
  • Resins were synthesized by mixing 1-aza-15-crown-5 macrocyclic ligand attached to styrene (2th petroleum in 4th class hazardous materials) and divinylbenzene (DVB) copolymer with crosslinkage of 1%, 2%, 8%, and 16% by substitution reaction. The characteristic of these resins was confirmed by content of chlorine, element analysis, thermogravimetric analysis (TGA), surface area (BET), and IR-spectroscopy. The effects of pH, time, dielectric constant of solvent and crosslinkage on adsorption of metal ion by the synthetic resin adsorbent were investigated. The metal ion showed a fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in an increasing order of uranium $(UO_2^{2+})$ > lead $(Pb^{2+})$ > chromium $(Cr^{3+})$ ion. The adsorption was in the order of 1%, 2%, 8%, and 16% crosslinkage resin and adsorption of resin decreased in proportion to the order of dielectric constant of solvents.