• Title/Summary/Keyword: Lead adsorptivity

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Lead Adsorption by Carboxylated Alginic Acid and Its Application in Cleansing Cosmetics (Carboxylated Alginic Acid 및 이를 함유한 세정용 화장품의 납 흡착 효과)

  • Park, Hee-Yeon;Jang, Mi-Soon;Kadnikova, Irina;Kim, Yeon-Kye;Lim, Chi-Won;Yoon, Ho-Dong
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.43 no.5
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    • pp.400-405
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    • 2010
  • This study investigated lead adsorption by carboxylated alginic acid and its application in cleansing cosmetics. Carboxylated alginic acid showed the highest lead adsorptivity after oxidation in a 4-6 mM hydrogen peroxide solution at $20-30^{\circ}C$ for 30-40 min. Carboxylated alginic acid adsorbed $648.1{\pm}2.8-653.0{\pm}2.9$ mg/g of lead dry mass at pH 4-6. Carboxylated alginic acid modified by hydrogen peroxide and potassium permanganate adsorbed $651.3{\pm}3.8$ and $639.9{\pm}4.0$ mg/g of lead dry mass, respectively. Carboxylated alginic acid showed higher lead adsorptivity after modification by hydrogen peroxide than by potassium permanganate, with an increase of ~30% compared with raw alginic acid. To access the potential application of carboxylated alginic acid in cleansing cosmetics, we investigated the lead adsorptivity, conditions of the cosmetics procedure, and cytotoxicity of various concentrations of cleansing cosmetics added to 5% carboxylated alginic acid. The ideal cosmetic concentrations combined with 5% carboxylated alginic acid were 70% for peeling gel, 20% for massage cream, 20% for foam cleansing and 40% for cleansing cream. There was no cytotoxicity in cleansing cosmetics combined with 5% carboxylated alginic acid.

Characteristics of VOCs Adsorption of Brick Prepared by MSWI Fly Ash (소각재로 제조한 건축외장재의 VOCs 흡착 특성 평가)

  • Ban, Hyo-Jin;Jeong, Jae-A;Lee, Woo-Keun
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.9
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    • pp.857-861
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    • 2010
  • Recently photochemical smog has become a serious urban air pollution. And VOC is the major pollutant for it. With the advance of industrialization and urbanization, MSWI fly ash and sewage sludge and melting slag were generated. It is necessary to de-toxificate ashes, because they contain many toxic constituents and probably lead to contaminate the environment. The objective of this research was to prepare multi-functional brick which is able to remove VOCs in ambient air. The bricks were made of MSWI fly ash, sewage sludge and slag. The benzene adsorption experiment by brick was acted to evaluate its adsorptivity. And also photocatalyst material was coated to enhance its adsorptivity and the endurance on the brick. According to the result, the benzene showed 74~96%. The removal efficiency was increased and the breakpoint time was lengthened by coating a brick.

Adsorption Characteristics Evaluation of Natural Zeolite for Heavy-metal Contaminated Material Remediation (중금속 오염물질 정화를 위한 천연제올라이트의 흡착특성)

  • Shin, Eun-Chul;Park, Jeong-Jun;Jeong, Cheol-Gyu;Kim, Sung-Hwan
    • Journal of the Korean Geosynthetics Society
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    • v.13 no.2
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    • pp.59-67
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    • 2014
  • The amount of the contaminants that can be adsorbed on the drain was evaluated for the effective remediation of the contaminated soil, and the contaminants adsorptivity of the drain was evaluated by comparing the isothermal adsorption model after carrying out the contaminants adsorption test of the reactants coated on the surface of the drain. The reactant used in the experiment is a natural zeolite, and the contaminants are copper, lead and cadmium. The results that Freundlich and Langmuir adsorption isotherm model are compared to the adsorption amount according to the change of the initial concentration by the contaminants. As a result of the component analysis, because Si, Al and O are contained approximately 28%, 11% and 48%, respectively, it is identified that the material coated on the surface of the drain is the component of the zeolite which is the reactant for the adsorption of the heavy-metal (Cu, Pb, Cd) contaminants. The heavy-metal adsorption kinetic of the zeolite which is the reactant was decreased in order of lead, copper and cadmium. The important factor of the performance evaluation of the adsorbent is the reaction rate, and if zeolite is used as the reactant in the relationship between the maximum amount of adsorption and reaction rate, it can be utilized as the design factor that determine the removal order of the complex heavy-metal. In other words, because the maximum adsorption quantity of lead is smaller compared to copper but the reaction rate is relatively fast, it can be primarily removed, and copper can be removed after removing the lead. It was analyzed that Cadmium can be finally removed after that other heavy-metal is removed.