• Title/Summary/Keyword: Lead

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A Cross-check of Domestic Lead Material Flow in Public Database Sets for the Recycling Status Analysis (재활용 현황파악을 위한 공공 자료별 국내 납 물질 흐름 상호 확인)

  • Lee, Sang-hun;Kim, Jungeun
    • Resources Recycling
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    • v.30 no.3
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    • pp.63-69
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    • 2021
  • Supply deficit of lead commodities and environmental pollution can be simultaneously resolved through the recovery and recycling of waste lead. The recent recovery of lead through recycling of the lead battery waste is a positive development. To maximize the effect of lead recovery and recycling in the future, the updated status of the lead material flow should be recognized. However, such an analysis at the preliminary stages may be cumbersome owing to the complexity and diversity of emission sources and material streams. At this stage, a preliminary screening by domestic lead flow using public information should be feasible. Therefore, in this study, using the data from the UN Comtrade and domestic PRTR (Pollutant Release and Transfer Register) databases, the amounts of lead import, emission, and transfer were identified and cross-checked with the domestic lead flow described in the National Material Flow Analysis database. The lead flow for major categories such as waste lead-acid batteries showed a rough consistency between the databases.

Hemoglobin Concentration in Female Workers of Occupational Exposure to Lead (연 취급 근로자들의 혈색소치의 변동)

  • Park, Nan-Kyu;Kang, Pock-Soo;Chung, Jong-Hak
    • Journal of Yeungnam Medical Science
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    • v.3 no.1
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    • pp.73-79
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    • 1986
  • This study was conducted to evaluate the effects of lead on the incidence of anemia and to find cases with lead poisoning early among female workers who have been exposed to lead occupationally, for one year from August, 1985. The level of blood lead and hemoglobin concentration were observed for 284 female lead workers and 123 female non-lead workers of industries in the Gumi industrial complex in Kyungpook Province. The average age was $20.3{\pm}2.9$years and $21.1{\pm}3.5$ years in lead workers and non-lead workers, respectively. The average working duration was $26.46{\pm}19.26$ months in lead workers. The mean value of blood lead was $30.11{\pm}6.61{\mu}g/100ml$ and $21.86{\pm}3.75{\mu}g/100ml$ in lead workers and non-lead workers, respectively. There were significant differences between two groups. The mean value of hemoglobin concentration was $14.00{\pm}0.57g/100ml$ and $14.03{\pm}0.64g/100ml$ in lead workers and non-lead workers, respectively. Anemia cases were not observed at Hb concentration below 12g/100ml. The percentages of lead workers at Hb concentration ranged 12.0~13.0g/100ml were 4.5%. There was no dose-response relationship between blood lead level and the incidence of anemia. There were no remarkable differences between age and blood lead level as well as Hb concentration, and between working duration and the level of blood lead and hemoglobin.

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Accumulated Concentration of Lead in Plant Organ of Arabidopsis thaliana Exposed to Lead (납에 노출된 애기장대의 식물기관에 축적된 납 농도)

  • Park, Jong-Bum
    • Journal of Life Science
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    • v.17 no.10
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    • pp.1414-1418
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    • 2007
  • This study was to examine the accumulated concentration of lead in the organ of Arabidopsis thaliana grown in the soil added three different concentrations of lead. The accumulated concentrations of lead in the stem of plant grown in the soil added official standard concentration of lead of pollutant exhaust notified by the Ministry of Environment (1 mg/l), concentration ten times higher than the official standard concentration (10 mg/l) and concentration fifty times higher (50 mg/l) were similar to the rate of increase between three different concentrations, and increased average 24% compared with normal plant stem. The accumulated concentrations of lead in the leaf of plant grown in the soil added three different concentrations of lead were increased average 57% compared with normal plant leaf. And accumulated concentrations of lead in the leaf was no significant difference according to increase of lead concentration added in the soil as stem, the rate of increase was similar to between three different concentrations. The accumulated concentrations of lead in the root of plant grown in the soil added official standard concentration of lead of pollutant exhaust and concentration ten times higher were increased average 114% compared with normal plant root, but increased about 861% in the concentration fifty times higher than the official standard concentration. This result contrast with the data of stem and leaf. The accumulated concentration of lead in the plant body of Arabidopsis thaliana was increased according to increase of lead concentration added in the soil. Especially, the accumulated concentration of lead in the plant body grown in the concentration fifty times higher than the official standard concentration was increased about 2.6 times than normal plant. These results show that lead contaminated within the soil was more accumulated in the root than the stem or leaf, and accumulated concentrations of lead in the stem and leaf were not increased in proportion to the concentration of lead in the soil, but very increased in proportion to the concentration in the root.

The change of validity of blood zinc protoporphyrin test by different cut-off level in lead workers (연취급 근로자들의 혈중 ZPP 농도 선별기준에 따른 정확도의 변화)

  • Kim, Yong-Bae;Ahn, Hyun-Cheol;HwangBo, Young;Lee, Gap-Soo;Lee, Sung-Soo;Ahn, Kyu-Dong;Lee, Byung-Kook
    • Journal of Preventive Medicine and Public Health
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    • v.30 no.4 s.59
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    • pp.741-751
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    • 1997
  • Measurement of blood lead (PbB) and blood zinc protoporphyrin (ZPP) are most common biological indices to identify the individual at risk for excess or the health sequences by lead exposure. Because PbB is known most important and reliable index of lead exposure, PbB is often regarded as a gold standard to detect lead exposure. But in Korea PbB is a secondary test item of detailed health check-up with positive finding of screening test in most occasion. Our lead standard requires all lead workers to take annual heath-check twice a year for investigation of their health effect due to lead exposure. Blood ZPP is one of most important index to detect high lead absorption in lead workers as a screening test. Measurement of blood ZPP is known ,well to correlate with PbB in steady state of exposure in most lead workers and is often used as a primary screening test to detect high lead absorption of lead workers with the advantage of simplicity, easiness, portability and low cost. The current cut-off criteria of blood ZPP for further detailed health check-up is $100{\mu}g/d\ell$ which is supposed to match the level of $40{\mu}g/d\ell$ of PbB according to our standard. Authors tried to investigate the validity of current criteria of cut-off level $(100{\mu}g/d\ell)$ of blood ZPP and possible another better cut-off level of it to detect the lead workers whose PbB level over $40{\mu}g/d\ell$. The subjects in our study were 212 male workers in three small scale storage battery industries. Blood ZPP, PbB and hemoglobin (Hb) were selected as the indices of lead exposure. The results were as follows. 1. The mean of blood ZPP, PbB and Hb in lead workers were $79.5{\pm}46.7{\mu}g/d\ell,\;38.7{\pm}15.1{\mu}g/d\ell,\;and\;14.8{\pm}1.2g/d\ell$, respectively. There were significant differences in blood ZPP, PbB and Hb by industry (P<0.01). 2. The percents of lead workers whose blood ZPP were above $100{\mu}g/d\ell$ in the group of work duration below 1, 1-4, 5-9 and above 10 years were 8.6%, 17.2%, 47.6%, and 50.0%, respectively. The percents of lead workers whose PbB were above $40{\mu}g/d\ell$ in those were 31.4%, 40.4%, 71.4%, and 86.4%, respectively. 3. The percents of lead workers whose PbB were below $40{\mu}g/d\ell$, $40-59{\mu}g/d\ell$ and above $60{\mu}g/d\ell$ were 54.7%, 34.9% and 10.4%, respectively. Those of lead workers whose blood ZPP were below $100{\mu}g/d\ell$, $100-149{\mu}g/d\ell$ and above $150{\mu}g/d\ell$ were 79.2%, 13.7% and 7.1%, respectively. 4. Simple linear regression of PbB on blood ZPP was statistically significant (P<0.01) and as PbB was $40{\mu}g/d\ell$, blood ZPP was $82.1{\mu}g/d\ell$. 5. While the highest sensitivity and specificity of blood ZPP test to detect lead workers with PbB eve. $40{\mu}g/d\ell$ were observed in the cut-off level of $50{\mu}g/d\ell$ and $100{\mu}g/d\ell$ of blood ZPP, respectively, the highest validity (sensitivity+specificity) of blood ZPP to detect lead workers with PbB over $40{\mu}g/d\ell$ was observed in the cut-off level of around $70{\mu}g/d\ell$ of blood ZPP. But even with optimal cut-off level of around $70{\mu}g/d\ell$ of blood ZPP, still 25.0% of false negative and 20.7% false positive lead workers were found. As the result of this study, it was suggested that reconsideration of current blood ZPP cut-off of our lead standard from $100{\mu}g/d\ell$ to somewhat lower level such as around $70{\mu}g/d\ell$ and the inclusion of PbB measurement as a primary screening test for lead workers was highly recommended for the effective prevention of lead workers.

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Pin Pull Characteristics of Pin Lead with Variation of Mechanical Properties of Pin Lead in PGA (Pin Grid Array) Package (PGA (Pin Grid Array) 패키지의 Lead Pin의 기계적 특성에 따른 Pin Pull 거동 특성 해석)

  • Cho, Seung-Hyun;Choi, Jin-Won;Park, Gyun-Myoung
    • Journal of the Microelectronics and Packaging Society
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    • v.17 no.1
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    • pp.9-17
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    • 2010
  • In this study, von Mises stress and total strain energy density characteristics of lead pin in PGA (Pin Grid Array) packages have been calculated by using the FEM (Finite Element Method). FEM computation is carried out with various heat treatment conditions of lead pin material under $20^{\circ}$ bending and 50 mm tension condition. Results show that von Mises stress locally concentrated on lead pin corners and interface between lead pin head and solder. von Mises stress and total strain energy density decrease as heat treatment temperature of lead pin increases. Also, round shaped corner of lead pin decreases both von Mises stress and total strain energy density on interface between lead pin head and solder. This means that PGA package reliability can be improved by changing the mechanical property of lead pin through heat treatment. This has been known that solder fatigue life decreases as total strain energy density of solder increases. Therefore, it is recommended that both optimized lead pin shape and optimized material property with high lead pin heat treatment temperature determine better PGA package reliability.

Assessment of Nutritional Status by Estimation of Nutrients and Food Intakes of the Lead Workers in Republic of Korea

  • Kim, Hee-Seon;Song, Ok-Young;Lee, Sung-Soo;Young Hwangbo;Ahn, Kyu-Dong;Lee, Byung-Kook
    • Nutritional Sciences
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    • v.4 no.2
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    • pp.91-97
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    • 2001
  • The purpose of this study was to assess the nutritional status of Korean workers with occupational exposure to lead by estimating nutrients and flood intakes so that we can eventually establish the dietary guidelines to be recommended for the lead workers. Food consumption survey was conducted by a 24-hr recall method with 135 lead workers and 50 non-exposed controls. Food intake data were convened into nutrients intake using computer aided nutritional analysis program. Mean daily energy intake and percentage of recommended daily allowance (RDA) of male lead workers were 2138 local and 87% of RDA while those of control were estimated as 2234 kcal and 91% of RDA. Mean daily intakes of nutrients of male lead workers were 78 g (111% RDA) for protein 502 mg (71% RDA) for calcium, 11.7 mg (97% RDA) for iron, 665 $\mu$g R.E (95% RDA) for vitamin A, 1.39 mg (108% RDA) for thiamin, 1.14 mg (77% RDA) for riboflavin, 15 mg N.E (92% RDA) for niacin and 66 mg (94% RDA) for vitamin C. On average, male lead workers showed significantly lower protein, calcium, iron, sodium, potassium, niacin and vitamin C intakes than control group while cholesterol intake of the male lead workers was significantly higher than that of control group. Intakes of calcium of male lead workers were Less than 75% RDA meaning that nutritional intake of calcium of male lead workers was insufficient and could possibly result in nutritional deficient. Some food groups such as milk, meat and fish must be strongly suggested to improve nutritional status of lead workers. Continuing nutrition monitoring and appropriate nutrition intervention for lead workers most be conducted further.

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The Effects of Lead Exposure on Hematocrit ana Hemoglobin (연폭로시 혈구용적치 및 혈색소치의 변화)

  • Lee, Se-Hoon
    • Journal of Preventive Medicine and Public Health
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    • v.13 no.1
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    • pp.41-46
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    • 1980
  • In order to study the effect of lead exposure on the hematocrit and hemoglobin values in accordance with the level of lead exposure, twenty-four Sprague-Dawley rats were equally divided into four groups of six rats each. Lead acetate disolved in glucose was injected intraperitoneally six times a week, for four weeks with dose of 0.05 mg/kg/day for group I, 0.5 mg/kg/day for group II, and 5 mg/kg/day for group III. Control group was injected glucose only. Blood samples for the checking of the hematocrit and hemoglobin values, were taking from tail vein of rats before lead injection and on the third, seventh, fourteenth, twenty-first, and twenty-eighth days after lead injection. And also, the concentration of lead and ALA in urine were checked for evaluating the lead absorption. The results were as follows: 1. The alteration of the hematocrit and hemoglobin values of the group I was not significant as that of the control group. 2. In group II, the hematocrit values were significantly decreased from the fourteenth day after lead injection, and the hemoglobin values were decreased from the twenty-first day after lead injection when the concentration of lead in urine was elevated more than $260{\mu}g/liter$. 3. In group III, the hematocrit values were decreased from the seventh day after lead injection, and the hemoglobin values were decreased even from the third day after lead injection. And the hemoglobin values were more rapidly decreased than the hematocrit values. 4. In all groups, the correlation coefficient between hematocrit and hemoglobin was highly significant. And the difference between the correlation coefficient of the group III and that of the others was highly significant.

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Interaction of lead and selenium on several aspects of thyroid, liver, and kidney function in guinea pigs (기니픽에서 갑상선, 간 및 신기능에 미치는 납과 selenium의 상호관계)

  • Kim, Jin-sang;Kang, Hyung-sub;Kang, Chang-won
    • Korean Journal of Veterinary Research
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    • v.36 no.3
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    • pp.699-707
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    • 1996
  • This study was designed to examine the involvement of lead in function of target organ, and the protective effect of selenium in lead-treated guinea pigs for 8 weeks. The effects of exposure to 0.5% lead acetate(lead) and/or 4ppm sodium selenite(selenium) in feed on serveral aspects were evaluated by measuring thyroid stimulating hormone(TSH), triiodothyronine($T_3$), thyroxine($T_4$), serum biochemical activities, organ weights, and serum and organ lead concentrations in growing animals. The many indicators of endocrine function(TSH, $T_3$, and $T_4$ in serum), enzyme and biochemical activities(${\alpha}$-glutamyltranspeptidase, alkaline phosphatase, lactate dehydrogenase, triglyceride, creatinine, $Ca^{2+}$ in serum), and organ weights(kidney, spleen and testis) were correlated with lead exposure or showed significantly different mean values between the exposed and controls. These changes on some aspects were reversed by combination-fed of selenium, but did not statistically significant. The organ(kidney, liver, spleen, testis and brain) and serum lead concentrations of lead-fed group were clearly higher than that of controls. Selenium supplementation resulted in a significant protection against lead accumulation in liver and testis. These results suggest that lead can cause a toxic effect on several organ and that selenium seems to has a protective effect on specific reaction by lead-induced organic function toxicity.

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Curative and Protective Effects of Garlic on Lead Poisoning (납중독에 대한 마늘의 치료와 방어효과)

  • Lee, Yong-Hwan;Park, Myung-Ho;Choi, Myung-Won;Chun, Bong-Kwon;Hur, Bang;Tak, Hyo-Jung;Hwang, In-Chul
    • Journal of Life Science
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    • v.11 no.6
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    • pp.543-553
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    • 2001
  • Lead poisoning is currently one of the major public health problems in industrialized countries. Several chelating agents have been developed and used to treat the lead poisoning. It was recently proposed that garlic, having a large quantity of S-S compounds, may react readily with lead, producing various sulfur componds, and thus provide curative and protective effects on the lead toxicity. The present study was undertaken to evaluate this possibility in experimental animals. The garlic treatment on rats pre-exposed to lead significantly enhanced urinary excretion of lead at a garlic dose of 500 mg/kg and decreased the bloon level of lead at both 250 and 500 mg/kg doses. The administration of grilic 500mg/kg along with lead significantly alleviated the renal histological alterations induced by lead. These results suggest that garilic has a curative as well as a protective effect against lead poisoning , thus it may act as a chelator of lead.

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Current Status of Lead Smelting and Recycling (납의 제련 및 리사이클링 현황)

  • Sohn, Ho-Sang
    • Resources Recycling
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    • v.28 no.4
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    • pp.3-14
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    • 2019
  • Lead is one of the common non-ferrous metals used in modern industry. The usage of lead continues to increase and has risen from 5 million tonnes per year worldwide in the 1970s to 11 million tonnes in the 2010s. In principle lead is virtually 100 % recyclable as an element without loss of quality. The recycling of lead scrap reduces the energy consumption and environmental burden, comparing to the primary metal production. Therefore production of secondary lead from scrap has been steadily growing and at present it meets approximately 60 % of usage worldwide. Lead scrap (mainly lead-acid battery) is smelted in primary and secondary smelter. Most secondary lead smelting were performed in a shaft-type furnace (blast furnace), rotary furnace and reverberatory furnace. The lead bullion is either cast into ingots and re-melted in refining kettles or refining is performed on the hot lead bullion immediately after production. This work provides an overview of the primary lead production and recycling process.