• Title/Summary/Keyword: Lead(Pb)

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Subclinical Neuropathy at 'Safe' Levels of Lead Exposure

  • Seppalanen Anna Maria;Tola Sakari;Hernberg Sven;Kock Boria
    • 대한예방의학회:학술대회논문집
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    • 1994.02a
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    • pp.545-548
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    • 1994
  • Eletrophysiological methods revealed subclinical neuropathy in 26 workers, exposed from 1 to 17 years to lead and whose blood lead (PbB) values had never exceeded $70{\mu}g/100\;ml$, as ascertained by checking the monitor reports of the factory and by careful exposure history. The PbB determinations had been tested repostedly and had been found valid. The main findings were slowing of the maximal motor conduction velocities of the median and ulnar nerves and particularly the conduction velocity of the slower fibers of the ulnar nerve. Eletrophysiological abnormalities comprised fibriliations, diminution of the number of motor units on maximal contraction, and an abnormal. Thus, a dose-response relationship exlets on a group basis. Since the regular monitoring of PbBs in most workers during their entire period of exposure excludes the possibility of a body burden out of proportion to the PbBs silght neuro-logical damage is produced at exposures hitherto regarded as quite sale.

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Enhanced field emission properties of double-walled carbon nanotubes coated with lead selenide nanoparticles (셀렌화납 코팅을 통한 이중벽 탄소나노튜브의 전계방출특성 향상)

  • Shin, Dong-Hoon;Lee, Cheol-Jin;Choi, Young-Min;Kim, Jong-Ung
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.3
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    • pp.594-598
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    • 2010
  • We studied on the field emission properties of double-walled carbon nanotubes (DWCNTs) coated with lead selenide (PbSe) nanoparticles. PbSe nanoparticles were uniformly attached on the surface of the DWCNTs by a simple chemical process. The PbSe-coated DWCNTs showed highly increased emission current density and enhanced emission stability over 20 h, compared with raw DWCNTs. We consider that the enhanced field emission properties of PbSe-coated DWCNTs were attributed to the increased field enhancement factor and lowered work function of the emitters.

Effects of Repeated Exposure to Pb Acetate on Hematopoietic Function, Testis and Kidney in Male Rats (Pb acetate의 13주 반복투여가 랫드의 조혈기능, 정소 및 신장에 미치는 영향)

  • 홍충만
    • Toxicological Research
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    • v.17 no.4
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    • pp.309-316
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    • 2001
  • Male Sprague Dawley rats were exposed to 0, 0.04, 0.2, and 0.8% Pb acetate in drinking water for 13 weeks and fed a commercial diet. Dose-related adverse effects observed at the end of the Pb acetate exposure in the drinking water were as follows: decrease in body weight gain, decrease in hemoglobin, hematocrit(HCT), mean corpuscular volume (MCV) and mean corpuscular hemoglobin (MCH), increase in serum glucose, decrease in serum testosterone, increase in lead accumulation and $\delta$-ALA release in urine, and decrease in $\delta$-ALAD activities DNA content and histopathlogy (intranuclear inclusion body in kidney proximal tubule cell). Taken together, repeated exposure of lead acetate induced toxicities in hematopoietic system, especially testis and kidney.

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Preparation of Lead Titanate Powders from Oxalates (수산에타놀법에 의한 $PbTiO_3$ 말의 합성)

  • Choi, Hee-Lark;Lee, Bong;Moon, Chang-Kwan
    • Journal of Ocean Engineering and Technology
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    • v.14 no.1
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    • pp.37-43
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    • 2000
  • $PbTiO_3$ was prepared by addition of lead-tltanium mixed aqueous solution to an ethanol solution of oxalic acid. The influence of various ripening factors was invesigated. On the basis of the results in the mono-component system we studied the foramtion of $PbTiO_3$ phase with various ripening conditions. The $PbTiO_3$ phase formation was accelerated with the ripening time temperature and ultrasonic irradiation.

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Effect of Roadside Soil and Vegetation with Lead and Zine by Motor Vehicles (자동차 매연중의 미량금속이 토양 및 식물체에 미치는 영향)

  • 강상준
    • Journal of Plant Biology
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    • v.15 no.3
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    • pp.9-13
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    • 1972
  • This report deals with lead and zinc contamination of roadside soil and plants caused by motor vehicles as a function of distance from the road edge. The concentrations of Pb and Zn in roadside soil and plant samples from several locations decrease regularly with increasing distance from traffic. Soil samples up to 24m distance from the road edge are contaminated with more than 12.99ppm lead, and 13.40ppm zinc. The decrease in Pb and Zn contamination with increasing distance from the road is characteristically curvilinear; the relative coefficiency of Pb and Zn with distance is -0.69, -0.48, respectively. The average contents of Pb and Zn in plants are 21.5ppm and 30.00ppm. It is suggested that the contamination is related to the composition of gasoline, motor oil and to roadside of the residues of this metals.

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A Compositional Design of Low Melting Lead-free Glass (저융점 Lead-free glass의 조성설계)

  • Lee, Young-Hun;Choi, Byung-Hyun;Kim, Sei-Ki;Lee, Mi-Jai;Lee, Hong-Lim
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.453-454
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    • 2005
  • PDP에 사용되는 유전체, 격벽재, 봉착재 등의 glass들은 모두 PbO를 다량 함유하는 저융점 유리조성계로 되어있다. 최근 환경규제에 따라 Pb 대체 재료의 개발이 필요하게 되었으며, 그에 대한 많은 연구들이 진행되고 있다. 본 연구에서는 투명 유전체를 겨냥한 저융점 이면서 무해한 3성분계 Pb-free 유리를 제조하였다. 또한 SnO 계 유리와의 혼합 용융에 의한 영향을 고찰하였으며, 유리로서의 고유물성과 응용용도별 특성을 함께 고찰하였다.

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A Study on the Additive of Positive Paste in Lead Acid Battery (납축전지 양극 Paste 첨가제에 관한 연구)

  • Jeong, Soon-Wook;Ku, Bon-Keun
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.2
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    • pp.196-201
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    • 2010
  • The influence of red lead($Pb_3O_4$) to curing and formation reaction properties when it was added in positive material of lead acid battery for vehicle use has been investigated. At the results, it was confirmed that the addition of red lead led 4BS crystal size to be smaller and increased the rates of 4BS formation and Pb consumption. Consequently the curing time was shortened to half compared with that of red lead-free one. In addition to this, the lead acid battery prepared by adding red lead showed 14% higher efficiency at the life cycle test than that without red lead.

Effect of Various Biodegradable Chelating Agents on Growth of Plants under Lead stress (생분해되는 다양한 킬레이트들이 납에 노출된 식물의 성장에 미치는 영향)

  • Lee, Sang-Man
    • Korean Journal of Environmental Agriculture
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    • v.29 no.1
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    • pp.61-65
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    • 2010
  • Phytoextraction is a method of phytoremediation using plants to remediate metal-contaminated soils. Recently, various chelating agents were used in this method to increase the bioavailability of metals in soils. Even though phytoextraction is an economic and environment-friendly method, this cannot be applied in highly metal-contaminated areas because plants will not normally grow in such conditions. This research focuses on identifying chelating agents which are biodegradable and applicable to highly metal-contaminated areas. Lead (Pb) as a target metal and cysteine (Cys), histidine (His), citrate, malate, oxalate, succinate, and ethylenediamine (EDA) as biodegradable chelating agents were selected. Ethylenediamine tetraacetic acid (EDTA) was used as a comparative standard. Plants were grown on agar media containing various chelating agents with Pb to analyze the effect on root growth. Cys strongly increased the inhibitory effect of Pb on root growth of plants, while, His did not affect on it significantly. The inhibitory effect of oxalate is weak, and malate, citrate, and succinate did not show significant effects. Both EDTA and EDA diminished the inhibitory effect of Pb on root growth. The effect of EDA is correlated with decreased Pb uptake into the plants. In conclusion, as biodegradable chelating agents, EDA is a good candidate for highly Pb-contaminated area.

Effect of $TiO_2$ in the Lead-Zinc-Borosilicate Solder Glass ($TiO_2$ 의 첨가가 Lead-Zinc-Borosilicate 봉착 유리에 미치는 영향)

  • 채수철;김철영
    • Journal of the Korean Ceramic Society
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    • v.21 no.4
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    • pp.349-354
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    • 1984
  • The purpose of present study is to find the structure crystallization mechanism and physical properties in $TiO_2$ containing lead zinc borosilicate glass system. The experiments such as differential thermal analysis infrared spectral analysis. X-ray diffraction analysis and thermal expansion measurements have been done. Differential thermal analysis of coarse and fine glass powder showed bulk nucleating mechanism for high $TiO_2$ containing glasses and surface nucleation mechanism for low $TiO_2$ containing glasses. The prepared glasses crystallized to crystalline mixture of PbO.2ZnO. $B_2O_3$ .4PbO.2ZnO.$5B_2O_3$and 2PbO.ZnO.$B_2O_3$ when heat-treated in the range of 480 and 51$0^{\circ}C$ and crystallized to PbTiO3 when heat-treated at $600^{\circ}C$. Obtained crystalline phase of $PbTiO_3$ in glass matrix strongly affects to thermal expansion coefficient and the value of crystallized glass varied 68.0 to $107.1{\times}10-7$/$^{\circ}C$ depending on the amount of $TiO_2$added. Infrared spectral analysis showed that [$BO_3$] triangle and [$BO_3$] tetrahedral units were coexisted in the glass with high content of PbO.

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Adsorption characteristics of lead ion in aqueous solution by volcanic ash (화산재에 의한 수용액의 납 이온 흡착특성)

  • Kim, Mi-Yeon;So, Myeong-Gi;Kim, Yeong-Gwan
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.3
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    • pp.359-366
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    • 2011
  • The feasibility of using volcanic ash for lead ion removal from wastewater was evaluated. The adsorption experiments were carried out in batch tests using volcanic ash that was treated with either NaOH or HCl prior to the use. Volcanic ash dose, temperature and initial Pb(II) concentration were chosen as 3 operational variables for a $2^3$ factorial design. Ash dose and concentration were found to be significant factors affecting Pb(II) adsorption. The removal of Pb(II) was enhanced with increasing volcanic ash dose and with decreasing the initial Pb(II) concentration. Pb(II) adsorption on the volcanic ash surface was spontaneous reaction and favored at high temperatures. Calculation of Gibb's free energy indicated that the adsorption was endothermic reaction. The equilibrium parameters were determined by fitting the Langmuir and Freundlich isotherms, and Langmuir model better fitted to the data than Freundlich model. BTV(base-treated volcanic ash) showed the maximum adsorption capacity($Q_{max}$) of 47.39mg/g. A pseudo second-order kinetic model was fitted to the data and the calculated $q_e$ values from the kinetic model were found close to the values obtained from the equilibrium experiments. The results of this study provided useful information about the adsorption characteristics of volcanic ash for Pb(II) removal from aqueous solution.