• 공업화학
• /
• 제2권4호
• /
• pp.372-384
• /
• 1991

국내 부존의 함티탄자철광으로 부터 천연 rutile 광의 대체를 위한 합성 rutile의 제조 및 고순도 철산화물을 제조할 수 있는 새로운 공정개발과 아울러 황산암모늄을 황산화제로 사용할 수 있는 새로운 용도개발의 가능성을 조사키 위해 함티탄자철광과 황산암모늄의 반응을 시도하였다. 그 결과 적절한 황산화 반응조건은 반응온도 $425^{\circ}C$, 반응시간 2.5h, 시료 함티탄자철광에 대한 황산암모늄의 무게비 11.0 그리고 시료ilmenite의 입도 -250 mesh였다. 이 조건에서 얻어진 황산화된 함티탄자철광을 물로 침출시켜 90.4%의 $TiO_2$와 85.3%의 Fe를 함티탄자철광으로 부터 추출하였다. 이 추출 용액으로 부터 제조된 합성 rutile의 $TiO_2$ 품위는 93.8%로서 rutile과 anatase의 혼합결정구조 였으며 철산화물은 순도 97.6% 의 ${\alpha}-Fe_2O_3$였다.

• 한국토양비료학회지
• /
• 제47권5호
• /
• pp.332-339
• /
• 2014

This research was performed to test the hypothesis that the optimal fertilization rate for red pepper is changed by soil moisture condition. The experiment was conducted in rainfall-intercepted fields in Suwon, South Korea from 2002 to 2003. Soil was irrigated at 30, 50, or 80 kPa of soil moisture tension at 20 cm soil depth in 2002 and 30, 50, 100, or 150 kPa in 2003. For both years, fertilization was performed with four levels: none, 0.5, 1, and 1.5 times of the recommended N, P, and K fertilization rate. The irrigation amount was the greatest at 30 kPa irrigation while the water use efficiency increased with decrease of irrigation amount. The Irrigation amount was 508 mm at 30 kPa irrigation and ranged from 355 mm to 435 mm at 50 kPa irrigation. The maximum yield was found at 30 kPa irrigation and 1.5 times of the recommend fertilization rate in 2002 and 2003. The yield index of red pepper increased linearly with the fertilization rate at 30 kPa which implied that excess irrigation induced nutrient leaching and reduced nutrient availability. The maximum yield in 50 kPa and 80 kPa was found at the recommend fertilization rate while the yield decreased by fertilization at 100 kPa and 150 kPa irrigation. It implies that reduction of fertilization is the feasible practice to mitigate drought stress in fields without stable irrigation resources.

• 한국수산과학회지
• /
• 제14권3호
• /
• pp.158-164
• /
• 1981

식품 저장용 옹기유의 납 용출양의 변화에 대하여 여러 가지 조건에서 검토한 결과를 요약하면 다음과 같다. 1) 옹기유의 납 용출양은 pH가 낮을수록 용출양이 많았으며, pH4이하에서는 저장기간이 경과함에 따라 기간당용출양도 증가하였으나, pH6 이상에서는 검출되지 않았다. 2) 외관상의 색채로 볼 때 붉고 광택이 있는 것이 검은 것 보다 납이 많이 용출되었으며 이것은 산화납을 사용하여 저온소성한 것으로 추정되었다. 3) 용출온도에 따라 용출양을 비교해 보면 $100^{\circ}C$에서 6시간 정도의 가열로써는 납은 검출되지 않았다. 4) 김치를 포함한 각종 산성 식품을 저장하는 경우 모두 3주 이상 경과하면 납의 용출양이 증가하였다. 5) 시판되고 있는 식기류를 $4\%$(v/v)아세트산용액으로 24시간 실온에서 용출시키면 납은$ND\sim171.1ppb$, 구리 $ND\sim4.71ppb$ 및 카드뮴 $ND\sim5.92ppb$의 범위로 검출되었다.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
• /
• pp.549-552
• /
• 2008

시멘트는 CaO, SiO2, Al2O3, Fe2O3, 등을 주요 성분으로 이루어져 있으며, 시멘트는 천연의 원료인 석회석, 규석, 점토, 철질 원료를 분쇄 및 혼합하여 고온의 킬른에서 소성 공정을 거쳐 제조된다.산화분위기의 소성과정을 거치면서 원료에 포함되어진 크롬 중 일부는 6가 크롬으로 용출된다. 또한 클링커의 원료 중 일부는 슬래그, 슬러지 등으로 대체되어 사용되고 있어 소성 공정중 원료에 포함되어져 있는 크롬은 6가 크롬으로 전환되어져 최종의 제품인 시멘트에도 6가 크롬은 포함되어진다. 원료에 함유된 중금속중 수용성 6가 크롬은 접촉시 알레르기를 발생시키는 원인으로 보고되고있다. 따라서 시멘트 중 6가 크롬의 저감 방법으로는 시멘트 공장에서 사용되어지는 대체원료의 사용량을 줄이고, 크롬 함량이 낮은 원료를 사용해야 하며, 클링커가 제조되는 분위기를 제어하여 크롬의 전환율을 낮추는 방법이 있을 수 있다. 따라서 클링커 원료의 종류 및 함량을 변화시켜 제조된 클링커의 6가 크롬의 용출특성을 검토하였으며, 대체원료의 사용이 증가함에 따라 6가 크롬의 용출량은 증가하였으며, 클링커의 소성온도가 낮아짐에 따라 6가 크롬의 용출도 증가함을 확인할 수 있었다.

• 한국지반공학회논문집
• /
• 제15권5호
• /
• pp.291-300
• /
• 1999

BTEX로 오염된 혼합토(사질토/점토)의 정화를 위한 계면활성제 기법의 적용성 및 제거효율에 대한 연구를 진행하였다. 초기농도 275mg/kg으로부터 1975mg/kg의 BTEX로 오염시킨 8개의 컬럼에 물, methyl alcohol과 계면활성제 용액을 주입하였고 이때 계면활성제와 첨가물의 혼합과 비혼합시에 대해 제거거동을 비교 분석하였다. 물을 이용한 흙 세척법의 적용 결과 850 간극부피의 물을 주입하여 98%의 제거 효율을 보였으나 8mg/kg 이하의 저농도에서는 더 이상 제거가 이루어지지 않고 일정한 양상을 가지는 tailing effect를 보였다. 본 실험 결과 가장 우수한 조건은3% ethyl alcohol과 3% SXS를 첨가한 4% SOFTANOL(equation omitted)-90을 간헐적으로 주입한 경우였으며 이 때 95 간극부피에서 99.5%의 제거효율을 보였다. 실험결과 물을 주입하였을 경우 850 간극부피를 주입한 반면, 계면활성제 적용시 95-165 간극부피에서 84.5%-99.5%의 제거효율을 보였는데 이는 계면활성제 기법을 오염된 지반 정화에 효율적으로 적용할 수 있음을 나타내는 것이다.

• 상하수도학회지
• /
• 제32권5호
• /
• pp.399-409
• /
• 2018

Prussian blue is known as a superior material for selective adsorption of radioactive cesium ions; however, the separation of Prussian blue from aqueous suspension, due to particle size of around several tens of nanometers, is a hurdle that must be overcome. Therefore, this study aims to develop granule type adsorbent material containing Prussian blue in order to selectively adsorb and remove radioactive cesium in water. The surface of granular activated carbon was grafted using a covalent organic polymer (COP-19) in order to enhance Prussian blue immobilization. To maximize the degree of immobilization and minimize subsequent detachment of Prussian blue, several immobilization pathways were evaluated. As a result, the highest cesium adsorption performance was achieved when Prussian blue was synthesized in-situ without solid-liquid separation step during synthesis. The sample obtained under optimal conditions was further analyzed by scanning electron microscope-energy dispersive spectrometry, and it was confirmed that Prussian blue, which is about 9.7% of the total weight, was fixed on the surface of the activated carbon; this level of fixing represented a two-fold improvement compared to before COP-19 modification. In addition, an elution test was carried out to evaluate the stability of Prussian blue. Leaching of Prussian blue and cesium decreased by 1/2 and 1/3, respectively, compared to those levels before modification, showing increased stability due to COP-19 grafting. The Prussian blue based adsorbent material developed in this study is expected to be useful as a decontamination material to mitigate the release of radioactive materials.

• 한국식품과학회지
• /
• 제36권6호
• /
• pp.900-904
• /
• 2004

현미의 수화속도를 개선하여 조리적성을 향상시키기 위해 0, 1, 3, 5kGy로 감마선을 조사한 후 수분흡수속도, 이화학적 특성 및 호화특성을 조사하였다. 현미의 수분흡수량은 수침온도 ($20-50^{\circ}C$)와 감마선 조사선량이 증가할 수록 증가하는 경향을 나타내었다. 수침온도 $50^{\circ}C$ 이상에서는 0 kGy와 1 kGy의 수분 흡수량은 큰 차이가 없었지만 5 kGy 조사구는 수침액 중에 가용성성분의 용출로 인해 오히려 수분흡수량이 감소하는 경향을 나타내었다. Amylograph에 의해 측정된 peak viscosity, setback, breakdown 및 consistency는 감마선 조사선량이 증가하면서 유의적으로 감소하는 경향을 보였다. Thermogravimetric analyzer에 의한 열중량분석 결과는 감마선 조사에 의해 고온 ($300^{\circ}C$ 이상)에서의 수분증발이 촉진되는 것으로 조사되었다.

• 한국환경농학회지
• /
• 제33권1호
• /
• pp.1-8
• /
• 2014

BACKGROUND: Recent studies using many amendments for heavy metal stabilization in soil were conducted in order to find out new materials. But, the studies accounting for the use of appropriate amendments considering soil pH remain incomplete. The aim of this study was to investigate the effects of initial soil pH on the efficiency of various amendments. METHODS AND RESULTS: Acid soil and alkali soil contaminated with heavy metals were collected from the agricultural soils affected by the abandoned mine sites nearby. Three different types of amendments were selected with hypothesis being different in stabilization mechanisms; organic matter, lime stone and iron, and added with different combination. For determining the changes in the extractable heavy metals, water soluble, Mehlich-3, Toxicity Characteristic Leaching Procedure, Simple Bioavailability Extraction Test method were applied as chemical assessments for metal stabilization. For biological assessments, soil respiration and root elongation of bok choy (Brassica campestris ssp. Chinensis Jusl.) were determined. CONCLUSION: It was revealed that lime stone reduced heavy metal mobility in acid soil by increasing soil pH and iron was good at stabilizing heavy metals by supplying adsorption sites in alkali soil. Organic matter was a good source in terms of supplying nutrients, but it was concerning when accounting for increasing metal availability.

• 자원환경지질
• /
• 제33권4호
• /
• pp.273-282
• /
• 2000

In order to investigate the extent and degree of arsenic and heavy metal contamination and the bioavailability of toxic elements around the abandoned mine in Korea, an environmental geochemical survey was undertaken in the Daduk mine. After appropriate preparation, tailings, soil, stream sediment, crop plant and fingernail samples were analysed for As, Cd, Cu, Pb and Zn by ICP-AES and ICP-MS. Elevated levels of 8,782 mg/kg As, 8.3 mg/kg Cd, 489 mg/kg Cu, 3,638 mg/kg Pb and 919 mg/kg Zn were found in tailings from the Daduk mine. These significant concentrations can impact on soils and sediments around the tailing ponds. Mean concentrations of As, Cd, Pb, Cu and Zn in soils are significantly higher than those in world average soil, especially for As and Pb. Element concentrations in sediments decrease with distance from the tailing ponds due to a dilution effect by the mixing of uncontaminated sediments. Arsenic and Cd are elevated in rice grains and stalks, and Cu and Zn concentrations in chinese cabbage, sesame and bean leaves are higher than the upper limit values for normal plant. Arsenic concentration in fingernails of farmers are higher than the normal level with a maximum value of 1.5 mg/kg. The post-ingestion bioavailability of toxic heavy metals in some paddy and farmland soils has been also investigated using the SBET (simple bioavailability extract test) method. The method utilises synthetic leaching fluids closelyanalogous to those of the human stomach. The quantities of As, Cd, Cu, Pb and Zn extracted from paddy soils after 1 hour indicated 15.9, 65.4, 46.2, 39.4 and 29.4% bioavailability, respectively and for farmland soils, 12.4, 26.0, 31.2, 29.3 and 19.4% bioavailability, respectively. The results of the SBET indicate that regular ingestion of soils by the local population could pose a potential health threat due to long-term toxic element exposure.

• 한국토양비료학회지
• /
• 제50권1호
• /
• pp.31-39
• /
• 2017

The effects of application of gypsum and fresh cattle manure on the yield of forage crop were investigated in Hwaong reclaimed land in Korea for 3 years from 2011 to 2013. This study was conducted to develop the practical application method of livestock manure as a fertilization source and a soil physico-chemical ameliorator for the cultivation of forage crop $Sorghum{\times}Sudangrass$ hybrid in newly reclaimed tidal land soil. Treatments with six applications were established with three replications; chemical fertilizer (CF), gypsum (G) $20Mg\;ha^{-1}$, G+fresh cattle manure (FCM) 100%, G+FCM 200%, G+FCM 300% and FCM 100% which referred to the application rate equivalent to the recommended amount of phosphate fertilization by soil test. The combined treatments of G+FCM increased soil organic matter, $Av.P_2O_5$ and exchangeable $Ca^{2+}$ contents while decreased exchangeable $Na^+$ and $Mg^{2+}$. The soil bulk density, soil hardness and soil aggregate formation were improved by G+FCM treatments. The dry matter yields of $Sorghum{\times}Sudangrass$ hybrid were significantly increased in proportion to the application rate of FCM. The phosphorus use efficiency showed the highest in the application level of G+FCM 100%, which seemed to be the results of reduced nutrient use efficiency by nutrient immobilization, leaching etc. when applied excessive amount of fresh animal manure.