• 동력기계공학회지
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• 제20권3호
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• pp.17-21
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• 2016

The corrosion behavior of aluminum alloys in the $H_2SO_4$ solution was investigated based on potentiodynamic techniques. Electrochemical properties, such as corrosion potential($E_c$), passive potential($E_p$), corrosion current density($I_c$), corrosion rate(mpy), of Al-Mg-Si, Al-Cu-Si and Al-Si alloys were characterized at room temperature. Passive aluminum oxide film, which including $Al_2(SO_4)_3$ and $3Al_2O_34SO_38H_2O$, were uniformly formed on the surface via the reaction of Al with $SO{_3}^{2-}$ or $SO{_4}^{2-}$ ions in the $H_2SO_4$ solution and the dependence of the corrosion behavior on the alloying element was discussed. The selective leaching of alloy element increased with increasing Cu content in the aluminum alloys.

• 한국농공학회논문집
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• 제48권5호
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• pp.73-80
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• 2006

The mono-layer cover system is composed of soils only as a filling material and various plants are planted on the surface to control the water balance in the cover system. In this paper, the mono-layer cover system was considered as an alternative landfill final cover system and developed a model that could utilize industrial by-product (especially, coal ash & phosphogypsum) as additive filling materials. The mixture of granite soil, coal ash, and phosphogypsum was placed as a cover material in a box constructed with cement. Laboratory tests were carried out to investigate the environmental effect on the utilization of coal ash & phosphogypsum and to determine the mxing ratio of each materials. In the leaching test, all materials showed lower heavy metal concentration than the threshold values of regulation. The optimum mixing ratio of materials which was applied to field model test was determined to soil (4) : coal ash (1) : phosphogypsum (1) on the volume base. Field model tests were continued from February to July, 2004 in the soil box that was constructed with cement block. It was verified that coal ash and phospogypsum mixed with soil was to be safe environmentally and the water balance of mono-layer cover system was reasonable.

• 동력기계공학회지
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• 제14권5호
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• pp.41-47
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• 2010

티타늄과 티타늄 합금은 재료적 특이성 때문에 심장 혈관 임플란트에서 일반적으로 사용되어 왔다. 일찍이 적용된 예로는 인공심장판막, 심박조율기의 보호케이스, 혈액 순환 장치 등이 있다. 하지만 물질유도혈전증(Material-induced thrombosis)은 혈전폐색에 의해 기인한 기능 손실로 심장혈관 임플란트 장치의 주된 합병증으로 존재하고 있으며, 심장혈관 임플란트의 혈전유전자는 심장혈관장치의 발달에 주된 난관 중 하나로 남아있다. 그리고 텍스처 혈액 접합 물질(Textured blood-contacting material)은 1960년대 초반 이후부터 혈액순환 보조 장치의 임상실험에 사용되고 있다. 접합 물질에 내장된 텍스처 섬유조직 표면은 형성, 성장, 안정적 부착, 생물학적 내벽(neointimal layer) 등 유도 혈액(entrapping blood) 성분에 의해 형성된다. 공동(cavity) 형상의 용해 가능한 미립자를 사용하는 SCPL법(Solvent casting/particulate leaching method)은 티타늄 기질 이전에 형성된 폴리우레탄 위에 텍스처(texture)를 생성하기 위해 사용되었다. 또한 콜라겐의 부동화(不動化)에 의한 공동(cavity)은 혈액 접합면에 잔존하기 위한 내피세포를 고정할 수 있는 효과가 있다. cpTi로 층화된 PU 기소공성(microporous)은 구조적 특성과 혈전증 감소를 위한 생물학적 내벽 사용의 잠재성을 평가하기 위한 세포 공동체 실험을 통해서 평가되었다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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• pp.323-323
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• 2007

Influence of $La_2O_3$ addition to $CaO-B_2O_3$-based glass on the water leaching resistance of the glass was first investigated. The optimized $La_2O_3-CaO-B_2O_3$(LCB) glass was ball milled for varying time, followed by mixing with $Al_2O_3$ crystalline phase to form $Al_2O_3$-LCB glass composites at $875^{\circ}C$ for 1h. Microwave dielectric properties of the composites were investigated as a function of the ball milling time of the LCB glass. Dielectric constant and quality factor of the composites were 6.31 and 13856 GHz, respectively, when the LCB glass was ball milled for 2h prior to mixing with $Al_2O_3$.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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• pp.324-324
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• 2007

Influence of $La_2O_3$ addition to $ZnO-B_2O_3$-based glass on the water leaching resistance of the glass was first investigated. The optimized $La_2O_3-ZnO-B_2O_3$ (LZB) glass was ball milled for varying time, followed by mixing with $Al_2O_3$ crystalline phase to form $Al_2O_3$-LZB glass composites at $875^{\circ}C$ for lh. Microwave dielectric properties of the composites were investigated as a function of the ball milling time of the LZB glass. Dielectric constant and quality factor of the composites were 6.01 and 11676 GHz, respectively, when the LZB glass was ball milled for 2h prior to mixing with $Al_2O_3$.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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• pp.326-326
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• 2007

Influence of $Nd_2O_3$ addition to $ZnO-B_2O_3$-based glass on the water leaching resistance of the glass was first investigated. The optimized $Nd_2O_3-ZnO-B_2O_3$ (NZB) glass was ball milled for varying time, mixing with followed by $Al_2O_3$ crystalline phase to form $Al_2O_3$-NZB glass composites at $875^{\circ}C$ for 1h. Microwave dielectric properties of the composites were investigated as a function of the ball milling time of the NZB glass. Dielectric constant and quality factor were 5.70 and 9497 GHz, respectively, when the NZB glass was ball milled for 6h prior to mixing with $Al_2O_3$.

• 한국재료학회지
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• 제24권5호
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• pp.249-254
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• 2014

Due to their unique properties, tungsten borides are good candidates for the industrial applications where certain features such as high hardness, chemical inertness, resistance to high temperatures, thermal shock and corrosion. In this study, conditions were investigated for producing tungsten boride powder from tungsten oxide($WO_3$) by self-propagating high-temperature synthesis (SHS) followed by HCl leaching techniques. In the first stage of the study, the exothermicity of the $WO_3$-Mg reaction was investigated by computer simulation. Based on the simulation experimental study was conducted and the SHS products consisting of borides and other compounds were obtained starting with different initial molar ratios of $WO_3$, Mg and $B_2O_3$. It was found that $WO_3$, Mg and $B_2O_3$ reaction system produced high combustion temperature and radical reaction so that diffusion between W and B was not properly occurred. Addition of NaCl and replacement of $B_2O_3$ with B successfully solved the diffusion problem. From the optimum condition tungsten boride($W_2B$ and WB) powders which has 0.1~0.9 um particle size were synthesized.

• Environmental Engineering Research
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• 제24권1호
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• pp.173-179
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• 2019

Prussian blue (PB) is known to be an effective material for radioactive cesium adsorption, but its nano-range size make it difficult to be applied for contaminated water remediation. In this study, a simple and versatile approach to immobilize PB in the supporting matrix via surface functionalization was investigated. The commercially available poly vinyl alcohol (PVA) sponge was functionalized by acrylic acid (AA) to change its major functional group from hydroxyl to carboxylic, which provides a stronger ionic bond with PB. The amount of AA added was optimized by evaluating the weight change rate and iron(III) ion adsorption test. The FTIR results revealed the surface functional group changing to a carboxyl group. The surface functionalization enhanced the attachment of PB, which minimized the leaching out of PB. The $Cs^+$ adsorption capacity significantly increased due to surface functionalization from 1.762 to 5.675 mg/g. These findings showed the excellent potential of the PB-PAA-PVA sponge as a cesium adsorbent as well as a versatile approach for various supporting materials containing the hydroxyl functional group.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2014년도 춘계 학술논문 발표대회
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• pp.248-249
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• 2014

Photocatalytic cement is receiving attention due to its high oxidation power that oxidizes nitrogen oxides (NOx), thus contributing to clean atmospheric environment. However, there has not been a thorough investigation on durability of a parent material, cementitious material, as a result of photocatalytic reactions. In this study, durability of photocatalytic cementitious materials exposed to nitrogen dioxide (NO₂) gas was examined. Titanium dioxide (TiO₂) nanoparticles containing cement paste samples were exposed to cycles of NO₂ with UV light, followed by wetting and drying to simulate environmental condition. The surface of samples was characterized mechanically, chemically, and visually during the cycling. The results indicate that the photocatalytic efficiency decreased with continued NO₂ oxidation due to calcium carbonate formation. The pits found from SEM demonstrate that chemical deterioration have occurred, such as acid attack or leaching. In conclusion, the photocatalytic reactions and its product could alter cementitious materials chemically and mechanically which could further affect long-term durability.

• 한국세라믹학회지
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• 제41권3호
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• pp.221-228
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• 2004

국내에서는 최근 구조물 증축에 필요한 경량골재를 중국 및 일본 등에서 수입해 사용하고 있는 실정이고, 환경오염에 대한 관심 또한 고조되면서 폐기물의 처리, 처분 문제가 심각하게 대두되고 있다. 이에 순수 국내 기술로 폐기물과 점토질 원료를 습식혼합, 로터리 킬른에서 소성하여 인공경량골재를 제조한 후 기본 물성을 평가하였고 경량콘크리트에 적용하여 강도특성을 고찰하였다. 인공경량골재의 절건비중은 1.4～1.7, 흡수율은 13～16%이었으며, 파쇄율은 약 30～55%로 강자갈이나 쇄석과 비교하여 10% 이상 높은 수치를 나타내었고 파쇄 형상에서도 차이를 보였다. 골재를 2mm 이하로 분쇄하여 TCLP 용출시험 후 추출된 여액을 ICP-AES로 분석한 결과, 검출한계 이하 또는 용출량 기준치 이하로 용출되었다. 제조된 인공경량골재를 사용한 경량콘크리트 공시체를 제작하여 슬럼프, 압축강도, 휨파괴변형 특성을 시험하였다. 시험 결과, 인공골재 치환율 30vo1%, 물시멘트비 45wt%인 공시체에서의 슬럼프 및 압축강도 특성이 가장 우수하였다. 경량골재 콘크리트의 슬럼프 및 압축강도 시험결과를 통해 도출된 최적배합을 바탕으로 경량콘크리트 패널을 제작하여 단열 및 차음특성을 시험한 결과, 평균 열관류율은 3.293W/$m^2$$^{\circ}C$로 쇄석콘크리트에 비해 약 15% 우수하였으며, 음향투과손실은 500Hz에서 50.9㏈로 기준치를 약 13% 상회하는 결과를 보였다.