• Journal of the Korean Chemical Society
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• v.50 no.4
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• pp.315-320
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• 2006

manganese oxides have been prepared by Chimie Douce redox reaction between permanganate and chalcogen element fine powder under acidic condition (pH = 1). According to powder X-ray diffraction analyses, the S- and Se-doped manganese oxides are crystallized with layered birnessite and tunnel-type -MnO2 structures, respectively. On the contrary, Te-doped compound was found to be X-ray amorphous. According to EDS analyses, these compounds contain chalcogen dopants with the ratio of chalcogen/manganese = 4-7%. We have investigated the chemical bonding character of these materials with X-ray absorption spectroscopic (XAS) analysis. Mn K-edge XAS results clearly demonstrated that the manganese ions are stabilized in octahedral symmetry with the mixed oxidation states of +3/+4. On the other hand, according to Se K- and Te L1-edge XAS results, selenium and tellurium elements have the high oxidation states of +6, which is surely due to the oxidation of neutral chalcogen element by the strong oxidant permanganate ion. Taking into account their crystal structures and Mn oxidation states, the obtained manganese oxides are expected to be applicable as electrode materials for lithium secondary batteries.

• Journal of architectural history
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• v.16 no.5
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• pp.55-66
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• 2007

Through analysing on construction cases of stupa built in A.D. 7,8th, I have researched about these : constructive methods of inner soil of stupa, spatial compositions, characteristics of structures, arrangements of inner soil and etc. And cases analysed are six ; Mireuksajiseoktap(stone pagoda of Mireuksa Temple site), Gameunsajisamcheumgseoktap(three storied stone pagoda of Gameunsa Temple site), Goseonsajisamcheungseoktap(three storied stone pagoda of Goseonsa Temple site), Wolseong nawolliocheungseoktap(five storied stone pagoda in Nawonri, Wolseong), Guksagokseoktap(three storied stone pagoda in Guksa valley), Giamgokseoktap(three storied stone pagoda in Giam valley). Additionally we researched about inner soil of Sacheonwangsaji tapji(basement of stone stupa site in Sacheonwang Temple site) to speculate on composition of Synthetically, the foundation could be divided as core space and outer space. ; the former as structural function and the latter as ornamental function. And the core area could be divided again as center column space and buffer space. The relationship between core spaces and its formation are as belows; First, according to the area of foundation and scale of stone pagoda, formations of core are differed. As the scale of stone pagoda goes bigger, and the area of foundation goes larger, the structure of stone pagoda comprised by center column type and layered-core which endure upper load independently. On the contrary, as the scale of stone pagoda goes smaller, and the area of foundation goes lesser, the structure of stone pagoda tend to use only center column to endure upper part. Second, spatial composition of core area is comprised as two spaces, one which endure upper load and buffer space which absorb side pressure and upper pressure. The buffer space tend to be used in case of those structures which could not endure side pressure or have lots of joint. In some cases, it was located below the cover stone of foundation and gained upper load. And in case that have not gained pressure from side stone, the buffer space are comprised by smalle stone or roof tile to get structural supplement.

• Journal of Ocean Engineering and Technology
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• v.29 no.1
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• pp.62-69
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• 2015

Coastlines are protected by breakwater structures against the erosion of sand or other materials along beaches due to wave action. This research examined the use of physical modeling to determine the effects of the tetrapod size and vertical walls of a rubble mound on the volume of wave overtopping under irregular wave conditions in coastal areas in Busan Yacht Harbor. In this analysis model, the structures were studied using irregular waves and the JONSWAP wave energy spectrum. To understand the effects of the tetrapod size and heights of the vertical wall, the study considered vertical walls of 0, 1.78, 6.83, and 9.33 cm with armor double layered material tetrapods of 8, 12, 16, and 20 tons. An extensive number of experiments covering a relatively large range of variables enabled a comprehensive discussion. First, in the presence of a short vertical wall, the water level played a key role in the overtopping discharge. In such circumstances, the values of the wave overtopping discharge decreased with increasing freeboard size. In the presence of a tall freeboard and middle, the value of the wave overtopping discharge was equally influenced by the vertical wall factor. Moreover, the tetrapod size decreased by an increase in the vertical wall factor, and relationship between them resulted in a short wall height. From an engineering point of view, considering a small water level may allow the choice of a shorter vertical wall, which would ultimately provide a more economical design.

• Journal of the Korean Ceramic Society
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• v.42 no.9 s.280
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• pp.602-606
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• 2005

[ $LiCoO_{2}$ ] is the most common cathode electrode materials in Lithium-ion batteries. $LiCo_{0.97}Mg_{0.03}O_2$ was synthesized by the solid-state reaction method. We investigated crystal structures, electrical conductivities and electrochemical properties. The crystal structure of $LiCo_{0.97}Mg_{0.03}O_2$ was analyzed by X-ray powder diffraction and Rietveld refinement. The material showed a single phase of a layered structure with the space group R-3m. The lattice parameter(a, c) of $LiCo_{0.97}Mg_{0.03}O_2$ was larger than that of $LiCoO_2$. The electrical conductivity of sintered samples was measured by the Van der Pauw method. The electrical conductivities of $LiCoO_2$ and $LiCo_{0.97}Mg_{0.03}O_2$ were $2.11{\times}10^{-4}\;S/cm$ and $2.41{\times}10^{-1}\;S/cm$ at room temperature, respectively. On the basis of the Hall effect analysis, the increase in electrical conductivities of $LiCo_{0.97}Mg_{0.03}O_2$ is believed due to the increased carrier concentrations, while the carrier mobility was almost invariant. The electrochemical performance was investigated by coin cell test. $LiCo_{0.97}Mg_{0.03}O_2$ showed improved cycling performance as compared with $LiCoO_2$.

• Fibers and Polymers
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• v.3 no.1
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• pp.8-13
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• 2002

The effect of block sequence on the self-assembly of ABC-type triblock copolymers in the ordered state is investigated using an isothermal-isobaric molecular dynamics simulation. The block sequence has an important effect ,on the ]norphology of ABC triblock copolymers. Different morphologies are observed depending on the block sequence as well as the block composition. The triblock copolymers with the volume fraction of 1 : 1 : 1 ($f_A$=$f_B$=$f_C$= 0.33) show the three phase and four layered lamellar structures irrespective of the block sequence. The $A_{32}$$B_{16}$$C_{32}$triblock copolymer with $f_B$=0.2 shows a morphology In which cylinders of midblock B are formed at the interface between A and C lamellae, whereas the morphology of triblock copolymer $B_{16}$$C_{32}$ $A_{32}$ and $C_{32}$ $A_{32}$ $B_{16}$ show a cylindrical core-shell structure and a lamellar type morphology, respectively. The $A_{20}$$B_{40}$$C_{20}$the triblock copolymer with the block B as a major component shows a tricontinuous structure, whereas both $B_{40}$$C_{20}$$A_{20}$ and $C_{20}$$A_{20}$$B_{40}$ triblock coolymers exhibit the lamellar structures. When the block B has larger volrome fraction with $f_B$=0.75, the matrix is composed of block B, and other two blocks A and C form spherical domains.

• The Journal of the Korea Contents Association
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• v.13 no.6
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• pp.9-19
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• 2013

In this paper, we develop a Spatio-Temporal graph as of a key component of our knowledge representation Scheme. We design an integrated representation scheme to depict not only present and past but future in parallel with the spaces in an effective and intuitive manner. An event in general occupies not only a space but a time. Hence a crucial premise for the simulation of virtual situations is to position events in the multi-dimensional context, that is, 3-D space extended by the temporal dimension. Furthermore an event tends to have physical, social and mental aspects intertwined. As a result we need diverse information structures and functions to model entities and relations associated with events and to describe situations in different stances or perspectives of the virtual agents. These structures and functions are implemented in terms of integrated and intuitive representation schemes at different levels such as Ontology View, Instance View, ST View, Reality View. The resulting multi-dimensional comprehensive knowledge structure accommodates multi-layered virtual world developing in the time to maximize the diversity of situations in the historical context. The viability of this knowledge representation scheme is demonstrated with a typical scenario applied to a simulator implemented based on the ST Graph. The virtual stage based on the ST graph can be used to provide natural contexts for situated learning or next-generation simulation games.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.10 no.2
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• pp.67-78
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• 1990

An inverse self-iterative procedure is developed to determine layer moduli which are significant for the structural evaluation of pavements in developing rational and analytical rehabilitation technique. Falling weight deflectometer(FWD) is adopted as a non-destructive testing(NDT)device. The layer elastic theory is used to interpret NDT data. The theoretical deflection basins of pavement structures obtained by full factorial design are used for a parametric study on the characteristics of deflection basins and regression analyses. Regression equations to estimate layer moduli of flexible pavements are proposed through the regression analyses of theoretical deflection basins. The relationships between the rate of change of moduli and deflections are developed for the efficient iteration. An inverse self-iterative procedure to ensure the accuracy of the layer moduli is proposed. Validity and applicability of the developed procedure are verified through various numerical model tests.

• Journal of Surface Science and Engineering
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• v.42 no.2
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• pp.86-94
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• 2009

Various types of multilayer coatings including Al/$Al_2O_3$ structure have been prepared on Nd-Fe-B permanent magnet to modify the morphology of the coating and to enhance the corrosion resistance of the magnet. Magnetron sputtering has been employed to make the multilayer coatings. $Al_2O_3$sputtering conditions were optimized in reactive sputtering by varying the deposition parameters. The formation of $Al_2O_3$ film was confirmed from the binding energy shift measured by electron spectroscopy for chemical analysis. 3 types of coating structures were designed and prepared by magnetron sputtering. The coating structures consist of (1) single Al coating, (2) modified coatings having oxide or plasma treated layer in the middle of coating structure, and (3) Al/$Al_2O_3$ multilayer coatings. Surface and cross-sectional morphologies showed that Al/$Al_2O_3$ multilayer grew as a layered structure, and that very compact Zone 3 like structure were formed. X-ray diffraction peak showed that the crystal orientations of multilayer coatings were similar to that of the bulk powder pattern. Hardness increased drastically when the Al thickness was around 1im in the Al/$Al_2O_3$ multilayer. From the salt spray test and pressure cooker test, it has been shown that the multilayer coatings showed good corrosion resistance compared to Al single or modified layer coatings.

• Journal of the Korean Geotechnical Society
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• v.18 no.3
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• pp.33-41
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• 2002

Soil nailing type of retaining structures has been widely used in Korea far the purpose of the temporary and permanent support in excavations and slope stability. The important factors in application of soil nailing systems in urban excavation site nearby the existing structures are the displacement of the wall and tensile farce of the nails, etc. In this paper, the fled back analyses are carried out at 11 excavation sites to investigate the behavior of tensile farce of nails at stepwise excavation in the multi-layered strata including various rock layers. The results of the fled back analysis are less than about 50% of the measured ones. The distance of active zone by measurements are shown almost larger than that of fled back analysis when the distance of active Bone is defined from the surface of wall to the potential failure surface. And the results of fled back analysis are within the range proposed by the project CLOUTERRE and Cartier & Gigan (1983) which were 0.3$H_f$, and 0.5$H_f$, of the final excavation depth ($H_f$,) respectively, but the values of the measurement were larger than these values.

• Journal of Korean Association for Spatial Structures
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• v.12 no.4
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• pp.109-118
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• 2012

The large-space single-layer lattice dome is relatively simpler in terms of the arrangement of the various framework members and of the design of the junction than the multi-layered lattice dome, can reduce the numbers and quantity of the framework members, and has the merit of exposing the beauty of the framework as it stands. The single-layer lattice dome, however, requires a stability investigation of the whole structure itself, along with an analysis of the stress of the framework members, because an unstable phenomenon called "buckling" occurs when its weight reaches critical levels. Many researchers have systematically conducted researches on the stability evaluation of the single-layer lattice dome. No construction case of a single-layer lattice dome with a 300-m-long span, however, has yet been reported anywhere in the world. The large-space dome structure is difficult to erect due to the gigantic span and higher ceiling compared with other common buildings, and its construction cost is generally huge. The method of erecting a structure causes major differences in the construction cost and period. Therefore, many researchers have been conducting various researches on the method of erecting such structure. The step-up method developed by these authors can reduce the construction cost and period to a great extent compared with the other general methods, but the application of this method inevitably requires the development of system supports in the center section as well as pre-existing supports in the boundary sections. In this research, the safety during the construction of a single-layer lattice dome with 300-m-long span using pre-existing materials was examined in the aspect of structural strength, and the basic data required for manufacturing the supports in the application of the step-up method developed by these authors during the erection of the roof structure were obtained.