• Title/Summary/Keyword: Layered structure

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A Study on the Preparation and Flame Retardancy of Compatibilized Blend/Layered Silicate Nanocomposites with Inorganic Flame Retardant (무기계난연제 첨가형 상용화블렌드/층상실리케이트 나노복합재료의 제조 및 난연특성에 관한 연구)

  • Kang, Young-Goo;Song, Jong-Hyeok
    • Journal of the Korean Society of Safety
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    • v.21 no.1 s.73
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    • pp.79-85
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    • 2006
  • Olefinic compatibilized blend(R-PP/R-PE)/layered silicate composites have been prepared by melt intercalation technique directed from $Na^{+}$ montmorillonite(MMT) or organophilic montmorillonites while using magnesium hydroxide as flame retardant. Morphology and flammability properties were characterized by X-ray diffraction(XRD), transmission electron microscopy(TEM), scanning electron microscopy(SEM), thermogravimetry analysis(TGA), limiting oxygen index(LOI), UL94 test. It is found that the compatibilized blend/layered silicate(Cloisite 20A) nanocomposites have a mixed immiscible-intercalated structure and there is better intercalation when a compatibilizer is combined with the polymer and layered silicate to be melt blended. A very large increase in the LOI value was observed with hybrid filler addition and further enhancement in thermal stability and compatibility of blend was obtained for the compatibilized blend containing small amount of layered silicate.

An Analysis of the Wave Propagation of the flow-induced Elastic Stress Waves in the Layered Structure and it's 1 D.O.F. Modelling (적층구조물내의 유체유발 탄성응력파의 전파해석 및 1 자유도계 모델링)

  • Lee, J.K.;Lee, U.S.
    • Journal of the Korean Society for Precision Engineering
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    • v.12 no.11
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    • pp.132-139
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    • 1995
  • Turbulent boundary layer pressure fluctuation exerted on the surface of a structure can give rise to a elastic stress wave on the surface of the structure. The stress wave so called surface wave, will not only propagate along the surface of structure but also penerate into the structure. To reduce the transmission of stress wave into the structure the elastomer layer is usually attactched on the surface of structure. The transfer function, which is defined herein as the ratio of stress waves at the surface and bottom of the elastomer layer, is derved by use of the cylindrical coordinates system. The elastodynamics of the elastomer layer subjected to the turbulent boundary layer pressure fluctuation is represented by the simplified one degree-of-freedom model for easy prediction of the stress wave transmission as well as efficient design of the elastomer layer.

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Fabrication of Double-layered Porous Materials (이중 기공구조를 갖는 다공질체의 제조)

  • Yun, Jung-Yeul;Kim, Hai-Doo;Park, Chun-Hong
    • Journal of the Korean Ceramic Society
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    • v.39 no.10
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    • pp.919-927
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    • 2002
  • In order to fabricate double-layered porous materials powders of different particle sizes were pressed stepwise. Ford's equation which predicts the fired density with the change in pressed density was employed in order to adjust the difference in sintering shrinkage of the green body with double-layered porous structure. Double-layered porous materials were characterized by investigating microstructures and permeability. SEM micrographs showed the distinct difference in pore sizes of double-layered porous material. Permeability of single-layered porous material increased by increasing the starting particle sizes and porosity as well. Permeability of the double-layered porous material depends largely on the layer of small pore diameter.

Magnetism in the Layered Structure Compound (C_18H_37NH_3)_2 MNCL_4

  • Lee, K. W.;Lee, C. H.;C. Rhee;Lee, Cheol-Eui;J. K. Kang;Lee, K.-S.
    • Journal of Magnetics
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    • v.2 no.4
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    • pp.126-129
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    • 1997
  • We have studied magnetostructural phase transitions in the perovskite-type layered structure compound (C18H37NH3)2 MnCl4 by means of electron paramagnetic resonance (EPR) and superconducting quantum interference device (SQUID) measurements. Distinct slopes were observed in the linear temperature dependences of the Mn++ EPR linewidth in the low and high temperature phases. Besides, linewidth anomalies at the transition temperatures sensitively reflect the magnetic changes arising from the MnCl6 octahedra.

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Phase Stability and Electronic Properties of $Bi_2BaLnCuO_{6+δ}$ Cuprates with Structure 2201 Type

  • V. E. Fedorov;N. G. Naumov;P. P. Samoilov;N. F. Zakharchuk;N. I. Matskevich;백우현
    • Bulletin of the Korean Chemical Society
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    • v.16 no.6
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    • pp.484-489
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    • 1995
  • The synthesis of new bismuth-barium containing members of layered cuprates with 2201 type structure was reported. By solution calorimetry the formation enthalpies for Bi2MLaCuO6.5 (M=Ba, Ba0.5Sr0.5, Sr) were obtained. Crucial influence of partial oxygen pressure and size of lanthanoid on stability of layered cuprates was shown. Electronic states of variable valence atoms were studied by voltammetry of solids.

An Experimental Study on Shaping Flat-Topped Element Patterns of a Multi-layered Disk Array Structure Excited by Cross-Dipole Elements (교차 다이폴 소자 여기에 의한 다층 원형 도체 배열 구조의 구형 빔 패턴 형성에 관한 실험적 연구)

  • 엄순영;박한규
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.14 no.7
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    • pp.712-720
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    • 2003
  • In this paper, a multi-layered metallic disk array structure(MDAS) excited by cross-dipole elements was proposed for efficiently shaping of flat-topped element patterns(FTEP) with circular polarization. The MDAS excited by cross-dipole elements has advantages to decrease in volume and weight of an overall array antenna and so, it is appropriate for the FTEP applications of a ralativlely low frequency band. In order to verify the effectness of this structure, the MDAS breadboard operated at X-band(7.9 ∼ 8.4 GHz) was fabricated, and its design parameters were experimentally optimized on the basis of the previous design experience. The experimental results were shown that the MDAS could shape good FTEPs of ${\pm}$20$^{\circ}$beam width at least within a 6.1 % frequency band.

A New Nanohybrid Photocatalyst between Anatase (TiO2) and Layered Titanate

  • Lee, Hyun-Cheol;Jeong, Hyun;Oh, Jae-Min;Choy, Jin-Ho
    • Bulletin of the Korean Chemical Society
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    • v.23 no.3
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    • pp.477-480
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    • 2002
  • A new microporous TiO2-pillared layered titanate has been successfully prepared by hybridizing the exfoliated titanate with the anatase TiO2 nano-sol. According to the X-ray diffraction analysis and N2 adsorption-desorption isotherms, the TiO2-pillared layered titanate showed a pillar height of ~2 nm with a high surface area of ~460 m2/g and a pore size of ~0.95 nm, indicating that a microporous pillar structure is formed. Its photocatalytic activity was evaluated by measuring the photodegradation rate of 4-chlorophenol during irradiation of catalyst suspensions in an aqueous solution. An enhancement in activity of ca. 170% was obtained for TiO2-pillared layered titanate compared to that of the pristine compound such as layered cesium titanate.

Multiple-Layered Colloidal Assemblies via Dipping Method with an External Electric Field

  • Im, Sang-Hyuk;Park, O-Ok;Kwon, Moo-Hyun
    • Macromolecular Research
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    • v.11 no.2
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    • pp.110-114
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    • 2003
  • When using the dipping method for crystal formation, mono-layered colloidal crystal structures depend upon the lift-up rate of a glass substrate. The mono-layered colloidal crystals showed the highest quality when the glass substrate was raised at a rate of 3 mm/min at 25 $^{\circ}C$ in a 1 wt% polystyrene colloidal suspension (ethanol medium). In addition, in order to obtain multiple-layered colloidal crystals, an external electric Held was introduced. Multiple-layered colloidal crystals were successfully obtained via this method. The colloidal particles were well ordered over large areas and assembled into a homogeneous structure.

Mechanical Behavior of Layered YSZ Thermal Barrier Coatings using Indentation Test (압입시험법에 의한 YSZ 층상 열차폐 코팅재의 기계적 거동)

  • Lee, Dong-Heon;Lee, Kee-Sung
    • Journal of the Korean Ceramic Society
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    • v.48 no.5
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    • pp.396-403
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    • 2011
  • In this study, we investigated the mechanical behaviors of layered thermal barrier coatings by indentations. Various single and double-layered thermal barrier coatings were deposited by air plasma spray process using different type of commercialized YSZ (Yttria stabilized zirconia) starting powders. Indentation stress-strain curve, load-displacement curve and hardness of the single and the double-layered thermal barrier coatings were obtained experimentally and analyzed. The indentation damages at the same loads were compared, and thus, the results depend on the structure of each coating. The result indicates improvement in damage resistances from tailoring of layered structures in the component of gas turbine system is expected.