• 태양에너지
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• 제11권3호
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• pp.53-61
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• 1991

본 연구에서는 심야전력 및 폐열의 회수이용을 위한 잠열축열재를 개발하기 위하여, 상변화 온도가 $50{\sim}80^{\circ}C$의 범위에 있는 상변화 물질중 잠열량이 크고, 물성안정이 비교적 용이한 Octacosane($C_{28}H_{58}$)과 Sodium Acetate Trihydrate($CH_3COONa{\cdot}3H_2O$)를 선택하여 상변화 온도의 변화특성과 물성안정방법 그리고 잠열특성을 분석하여 다음과 같은 결과를 얻었다. 1. 공업용 수준 Octacosane과 Sodium Acetate Trihydrate의 상변화 온도는 각각 $60.7^{\circ}C,\;57.4^{\circ}C$로서 시약용 수준에 비하여 Octacosane은 $1.1^{\circ}C$, Sodium Acetate Trihydrate는 $0.6^{\circ}C$ 낮았으며, 잠열량에 있어서는 Octacosane은 60.6kcal/kg으로 시약용 수준과 비슷한 값을 보였으나, Sodium Acetate Trihydrate는 51.1kcal/kg으로 시약용 수준에 비하여 5.4% 작은 값을 나타내었다. 2. Octacosane의 상변화 사이를 증가에 따른 잠열량을 분석한 결과, 초기에는 60.6kcal/kg이었으나, 시약용의 증가와 더불어 점차로 감소하여 200cycle에서 47.2kcal/kg이 되었고, 그 이후에는 거의 일정한 값을 유지하고 있는 것으로 보아 더 이상의 잠열량 감소는 없을 것으로 판단된다. 3. Sodium Acetate Trihydrate의 과냉현상을 제어하기 위한 조핵제로서 SPD(Sodium Pyrophosphate Decahydrate)를 3wt 이상 첨가하여 $25.7^{\circ}C$의 과냉도를 $1^{\circ}C$ 미만으로 줄였고, 증점제로서 CMC-Na를 3wt% 이상 첨가하여 상분리 현상을 해결하였으며, 안전성을 고려한 조핵제 및 중점제의 적정 첨가량은 4wt%였다. 4. UREA($NH_2CONH_2$)를 첨가하여 Sodium Acetate Trihydrate($CH_3COONa{\cdot}3H_2O$)의 상변화 온도를 $57.4^{\circ}C$에서 $46.2^{\circ}C$까지 다양하게 변화시켜 이용온도 수준에 적합한 잠열축열재를 선택할 수 있도록 하였으며, UREA 함량에 따른 잠열량을 분석한 결과 UREA의 함량이 증가함에 따라 잠열량이 점차로 감소하여 10wt%의 UREA를 첨가하였을 경우에는 38.3kcal/kg였으며, UREA의 함량이 20wt%까지 증가하는 동안 더 이상의 잠열량 감소는 없었다. 5. $30^{\circ}C$에서 $90^{\circ}C$까지의 가열과정에서 현열재인 물, 그리고 돌(화강암)과 잠열축열재의 축열량을 비교 분석한 결과, Octacosane은 상변화 온도 $60{\sim}70^{\circ}C$에서의 축열량이 물의 2.45배, 돌의 12.5배였으며, S.A.T.(Sodium Acetate Trihydrate)는 상변화 온도 $57.4^{\circ}C$에서의 축열량이 물보다 2.53배, 돌보다는 12.91배 큰 것으로 나타났다.

• Journal of Biosystems Engineering
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• 제31권3호
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• pp.161-167
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• 2006

The purpose of this study is to find the optimal conditions of PCM slurry manufacturing equipment for saving the marketing cost and keeping the original quality of products. In addition, the characteristics of the movable container for shipping or distributing products is analysed. The major results are as follows. 1. PCM thermal storage system is designed with the conditions of temperature($-5{\sim}10^{\circ}C$), cold chain time(30 minutes), and one time usage(50 liter). This system includes tank, freezer, circulating pump, cycle type heat exchanger, swelling tank, equipment of supplying PCM supplying unit includes cold tank, cycle type heat exchanger, suction unit and control equipments, etc. 2. After ability test of PCM thermal storage system, it shows that the required freezing time of PCM thermal storage system is less than one of the previous system. The reason is that churn (top and bottom) and compulsion circulation are occurred simultaneously and unit cooler type method is better than chiller type method. 3. By the experiment of transportation latent heat container, it is decided that the best container is $K_1$ with latent heat temperature($0{\sim}5^{\circ}C$) and density(0.15%). However, for $K_l\;and\;K_2$, it is necessary more studies on latent heat thermal conditions and conditions of making method.

• 한국자동차공학회논문집
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• 제4권3호
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• pp.187-198
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• 1996

In this study, the performance of an automobile heat storage system using PCM is numerically simulated. For the analysis of system performance. The phase-change of the PCM and the transient forced convective heat transfer for the HTF are considered simultaneously as a conjugate problem. The phase-change behavior is effectively analyzed using a concept of thermal resistance. From the correlations of phase change rate and heat transfer due to the variations of flow rate of HTF around PCM, the automobile heat storage system performance is predicted. The present results amy be used as the fundamental information for the design of automobile heat storage system.

• Journal of Biosystems Engineering
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• 제16권4호
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• pp.399-407
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• 1991

In Korea, the cultivation area under the plastic greenhouse was 1,746 ha in 1975, and 36,656 ha in 1989, it shows that the greenhouse cultivation area was increased by 21 times during last 14 years. The greenhouse cultivation area of 90~93% has been kept warm with double layers of plastic film and thermal curtain knitted with rice straw, and the rest area of 7~10% has been heated by fossil fuel energy. The use of rice straw thermal curtain is inconvenient to put it on and off, on the other hand the use of fossil fuel heating system results in the increase of production cost. To solve these problems, at first the heating load and the storable solar energy in greenhouse during the winter season were predicted to design solar utilization system, secondly a solar thermal storage system filled with latent heat storage materials was developed in this study. And then finally the thermal performance of greenhouse-solar energy storage system was analyzed theoretically and experimentally.

• 설비공학논문집
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• 제27권3호
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• pp.123-127
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• 2015

Thermochemical heat storage is a cutting-edge technology which can balance the energy usage between supplies and demands. Recent studies have suggested that thermochemical heat storage has significant advantages, compared to other storage methods such as latent heat storage or sensible heat storage. Nevertheless, ongoing research and development studies showed that the thermochemical heat storage has some serious problems. To bring the thermochemical heat storage method into market, we introduce experimental setup with composite material using perlite that supports calcium chloride sorbent. Also, to compare thermal properties with composite material, we used pure thermochemical material. Then, we found that the composite material has higher heat storage density by mass than pure calcium chloride. Moreover, it can be easily regenerated, which was impossible in the pure thermochemical materials.

• 융복합기술연구소 논문집
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• 제4권2호
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• pp.51-54
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• 2014

Energy storage not only reduces the mismatch between supply and demand but also improves the performance and reliability of energy systems. The different forms of energy that can be stored, including mechanical, electrical and thermal energy. Phase change materials (PCM) are latent heat storage materials. A large number of phase change materials (organic, inorganic and eutectic) are available in any required temperature range. We concentrated on eutectic materials and made a eutectic by mixing urea and choline chloride. Heat capacity ($C_p$) is one of the most important properties to be considered when a process is developed using the eutectic and currently DSC (Differential Scanning Calorimetry) has been proved as an effective technique to measure the heat capacity. This study focused on measuring heat capacity ($C_p$) of the mixing urea and choline chloride by DSC.

• 태양에너지
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• 제10권1호
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• pp.38-46
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• 1990

고밀도 잠열축열장치의 최적설계와 효율적인 작동을 위해서는 그 전열특성과 축열효율이 규명되어야 한다. 본 연에서는 수직이중관형 잠열축열장치의 방열과정에서의 전열특성을 이론 및 실험적으로 분석하였으며 두 결과는 잘 일치하였다. 그리고 컴퓨터 시뮬레이션을 통하여 방열효율에 대한 설계 및 작동피라미터의 영향을 분석하였다.

• 폴리머
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• 제34권3호
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• pp.261-268
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• 2010

본 연구에서는 상전이 온도가 36 $^{\circ}C$인 n-eicosnae을 열가소성 폴리올레핀 고분자인 폴리프로필렌과 블렌드하였으며, 또한 최근의 형태안정성 PCM(SSPCM)의 연구검토를 통하여 폴리프로필렌과 n-eicosnae의 특성과 잠열저장체로서의 적용 가능성을 확인하였다. 상전이 온도가 36 $^{\circ}C$인 n-eicosane과 폴리프로필렌을 멜팅방법과 흡수방법을 이용하여 시료를 제조하였다. 제조된 형태안정성 PCM(SSPCM)을 DSC, WAXD, FTIR spectroscopy, ARES로 분석결과 형태안정성, 열용량의 향상을 확인하였다.

• 한국에너지공학회:학술대회논문집
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• 한국에너지공학회 1992년도 학술발표회 초록집
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• pp.65-66
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• 1992

• 한국농업기계학회:학술대회논문집
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• 한국농업기계학회 1997년도 하계 학술대회 논문집
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• pp.113-120
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• 1997