• 제목/요약/키워드: Laser Induced Fluorescence(LIF)

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Application of Laser-Induced Fluorescence for EDC monitoring in aquatic system

  • Ko Eun-Joung;Kim Kyoung-Woong
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2005년도 총회 및 춘계학술발표회
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    • pp.117-121
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    • 2005
  • In order to monitor the levels and seasonal variations of EDCs, samples of the discharged effluent from sewage & wastewater treatment plants and river waters were collected. The target EDCs including bisphenol A and alkylphenols were determined by Laser-induced fluorescence(LIF) as in-situ monitoring technique. The category of EDCs showed similar fluorescence spectra and nearly equal decay time. This point makes it hard to distinguish each EBCs from the EDCs mixture by LIF and LIF results were expressed only by the total EDCs. However, LIF monitoring results and GC-MS results was comparable. The correlation coefficient between EDCs concentration acquired from GC-MS and fluorescence intensity from LIF was significant. This study supports the feasibility of the application of LIF into EDCs monitoring In aquatic system.

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Fluorescence Characteristic Spectra of Domestic Fuel Products through Laser Induced Fluorescence Detection

  • Wu, Ting-Nien;Chang, Shui-Ping;Tsai, Wen-Hsien;Lin, Cian-Yi
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제19권5호
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    • pp.18-25
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    • 2014
  • Traditional investigation procedures of soil and groundwater contamination are followed by soil gas sampling, soil sampling, groundwater sampling, establishment of monitoring wells, and groundwater monitoring. It often takes several weeks to obtain the analysis reports, and sometimes, it needs supplemental sampling and analysis to delineate the polluted area. Laser induced fluorescence (LIF) system is designed for the detection of free-phase petroleum pollutants, and it is suitable for on-site real-time site investigation when coupling with a direct push testing tool. Petroleum products always contain polycyclic aromatic hydrocarbon (PAH) compounds possessing fluorescence characteristics that make them detectable through LIF detection. In this study, LIF spectroscopy of 5 major fuel products was conducted to establish the databank of LIF fluorescence characteristic spectra, including gasoline, diesel, jet fuel, marine fuel and low-sulfur fuel. Multivariate statistical tools were also applied to distinguish LIF fluorescence characteristic spectra among the mixtures of selected fuel products. This study successfully demonstrated the feasibility of identifying fuel species based on LIF characteristic fluorescence spectra, also LIF seemed to be uncovered its powerful ability of tracing underground petroleum leakages.

고온고압 조건에서 Two-Photon LIF를 이용한 CO 측정에 관한 연구 (CO Two-photon Laser Induced Fluorescence Measurements in High Temperature and Pressure Conditions)

  • 오승묵;김득상
    • 한국연소학회지
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    • 제12권4호
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    • pp.1-7
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    • 2007
  • Carbon monoxide (CO) is not only an important intermediate species in chemical reaction mechanisms of hydrocarbon fuel combustion, but also a crucial pollutant species emitted from automotive engines. To better understand the physical processes impacting CO emissions, the development of laser-based measurement techniques that can visualize in-cylinder CO distributions is desirable. Among these techniques, Laser-Induced Fluorescence (LIF) is a sensitive and species-selective detection technique capable of good spatial resolution. However, some technical matters such as deep UV excitation, severe pressure dependency of the LIF signal, and potential interference from other species have been major challenges for CO LIF application. This study is focused on investigating the feasibility of CO two-photon LIF in a direct-injection diesel engine operating at typical pressure and temperature conditions with commercial grade diesel fuel. Spectroscopic analysis shows that the CO fluorescence signal can be separated from $C_2$ Swan band or broadband fluorescence from PAHs when the signal is collected near 483 nm. The signal-to-noise ratio of CO LIF deteriorate rapidly as pressure is increased, following $P^{-1.49}$ which matches the theoretical signal pressure dependency.

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입자 이동 방식에서 Laser Induced Fluorescence와 뭉침에 관한 연구 (A Study on Laser Induced Fluorescence and Coagulation in Particle Transport Mode)

  • 김기준
    • 한국응용과학기술학회지
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    • 제23권4호
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    • pp.340-346
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    • 2006
  • The influences of fluorescence, scattering, and flocculation in turbid material by light scattering were interpreted for the scattered fluorescence intensity and wavelength, it has been studied the molecular properties by the spectroscopy of laser induced fluorescence (LIF). The effects of optical properties in scattering media have been found by the optical $parameters({\mu}_s,\;{\mu}_a,\;{\mu}_t)$. Flocculation is an important step in many solid-liquid separation processes and is widely used. When two particles approach each other, interactions of several colloid particles can come into play which may have major effect on the flocculation and LIF process, The value of scattering coefficient ${\mu}_s$ is large by means of the increasing particles of scatterer it has been found that the slope decays exponentially as a function of distance from laser source to detector. It may also aid in designing the best model for oil chemistry, biopharmaceutical products, laser medicine and application of medical engineering on LIF and coagulation in particle transport mode.

LIF를 이용한 Hg-Ar 플라즈마 특성 평가 (Evaluation of Plasma Characteristics for Hg-Ar Using LIF)

  • 문종대
    • 전기학회논문지P
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    • 제57권2호
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    • pp.79-83
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    • 2008
  • In this paper, we introduced a LIF measurement method and summarized the theoretical side. When an altered wavelength of laser and electric power, lamp applied electric power, we measured the relative density of the metastable state in mercury after observing a laser induced fluorescence signal of 404.8nm and 546.2nm, and confirmed the horizontal distribution of plasma density in the discharge lamp. Due to this generation, the extinction of atoms in a metastable state occurred through collision, ionization, and excitation between plasma particles. The density and distribution of the metastable state depended on the energy and density of plasma particles, intensely. This highlights the importance of measuring density distribution in plasma electric discharge mechanism study. The results confirmed the resonance phenomenon regarding the energy level of atoms along a wavelength. change, and also confirmed that the largest fluorescent signal in 436nm, and that the density of atoms in 546.2nm ($6^3S_1{\to}6^3P_2$) were larger than 404.8nm ($6^3S_1{\to}6^3P_2$). According to the increase of lamp applied electric power, plasma density increased, too. When increased with laser electric power, the LIF signal reached a saturation state in more than 2.6mJ. When partial plasma density distribution along a horizontal axis was measured using the laser induced fluorescence method, the density decreased by recombination away from the center.

L-Aspartic Acid의 무질서하게 분포된 매질에서 파동전개와 변동에 관한 연구 (Studies on the Wave Propagation and Fluctuation in Randomly Ditribution Media of L-Aspartic Acid)

  • 김기준;이주엽
    • 한국응용과학기술학회지
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    • 제29권1호
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    • pp.122-128
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    • 2012
  • L-arpartic acid의 산란혼탁매질에서 형광, 산란과 응집의 영향은 파장과 산란된 형광세기로 나타내는데, laser induced fluorescence(LIF) 분광학에 의한 분자특성으로 나타난다. 산란매질에서 광학적 효과는 광학적 파라미터들(${\mu}_s$, ${\mu}_a$, ${\mu}_t$)에 의해 표현되고 응집은 고-액상 분리공정에서 중요하게 활용되고 있다. 따라서 입자가 서로 접근될 때 콜로이드 입자들의 상호작용을 LIF와 응집효과로 분석하였다. 레이저 광원에서 검출기까지 농도의 함수에 의해 농도가 묽어짐에 따라 산란세기가 기하급수적으로 감소함을 알 수 있다. 이는 유지화학, 생의학 생성물, 레이저 의학, 의공학 분야적용에 LIF와 입자이동 현상은 아주 적합한 모델 연구에 큰 도움이 될 것이다.

N-propyl-N,N-dimethylethanolamine의 Phantom에서 Laser Induced Fluorescence의 스펙트라에 관한 연구 (A Study on Spectra of Laser Induced Flourescence in Phantom of N-propyl-N,N-dimethylethanolamine)

  • 김기준;이주호;이주엽;성완모
    • 한국응용과학기술학회지
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    • 제32권2호
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    • pp.330-338
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    • 2015
  • N-propyl-N,N-dimethylethanolamine의 산란혼탁매질에서 형광, 산란과 응집의 영향은 파장 과 산란된 형광세기로 나타내는데, laser induced fluorescence(LIF) 분광학에 의한 분자특성으로 나타난다. 산란매질에서 광학적 효과는 광학적 파라미터들(${\mu}_s$, ${\mu}_a$, ${\mu}_t$)에 의해 표현되고 응집은 고-액상 분리 공정에서 중요하게 활용되고 있다. 따라서 입자가 서로 접근될 때 콜로이드 입자들의 상호작용을 LIF와 응집효과로 분석하였다. Monte Carlo simuation과 실험으로 레이저 광원에서 검출기까지 거리의 함수에 의해 농도가 묽어짐에 따라 산란세기가 기하급수적으로 감소함을 알 수 있었다. 이는 유지화학, 생의학, 레이저 의학, 의공학 분야적용에 LIF와 입자이동 현상은 아주 적합한 모델 연구에 큰 도움이 될 것이다.

Planar Laser-Induced Fluorescence (PLIF) Measurements of a Pulsed Electrothermal Plasma Jet

  • Kim, Jong-Uk;Kim, Youn J.;Byungyou Hong
    • Journal of Mechanical Science and Technology
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    • 제15권12호
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    • pp.1808-1815
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    • 2001
  • The characteristics of a pulsed plasma jet originating from an electrothermal capillary discharge have been investigate using laser-induced fluorescence (LIF) measurement. Previous emission measurements of a 3.1 kJ plasma jet show trial upstream of the Mach disk the temperature and electron number density are about 14,000 K and and 10$\^$17/ cm$\^$-3/, while downstream of the Mach dick tole values are about 25,000 K and 10$\^$18/ cm$\^$-3/, respectively. However, these values are barred on line-of-sight integrated measurements that may be misleading. Hence, LIF is being used to provide both spatially and temporally resolved measurements. Our recent work has been directed at using planar laser-induced fluorescence (PLIF) imaging of atomic copper in the plasma jet flow field. Copper is a good candidate for PLIF studies because it is present throughout the plasma and has electronic transitions that provide an excellent pump-detect strategy. Our PLIF results to date show that emission measurements may give a misleading picture of the flow field, as there appeals to be a large amount of relatively low temperature copper outside the barrel shock. which may lead to errors in temperature inferred from emission spectroscopy. In this paper, the copper LIF image is presented and at the moment, relative density of atomic copper, which is distributed in the upstream of the pulsed plasma jet, is discussed qualitatively.

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마이크로 채널 내부의 Micro-LIF 측정을 위한 마이크로 레이저 평면빔과 혼합용매의 적용 (Application of Micro-Thin Laser sheet and Mixed Solvent for Micro-LIF Measurement in a Microchannel)

  • 윤상열;김재민;김경천
    • 한국가시화정보학회:학술대회논문집
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    • 한국가시화정보학회 2004년도 추계학술대회 논문집
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    • pp.86-89
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    • 2004
  • One most feasible way to measure the concentration field in the micro-channel is using micro-LIF(Laser Induced Fluorescence) method. However, an accurate concentration field at a given cross plane in a micro-channel has not been successfully achieved so far due to various limitations in the light illumination and fluorescence signal detection. The present study demonstrates a novel method to provide an ultra thin laser sheet beam having five(5) microns thickness by use of a micro focus laser line generator. The laser sheet beam illuminates an exact plane of concentration measurement field to increase the signal to noise ratio and considerably reduce the depth uncertainty. Nile Blue A was used as fluorescent dye for the present LIF measurement. The enhancement of the fluorescent intensity signals was performed by a solvent mixture of water $(95\%)$ and ethanol (EtOH)/methanol (MeOH) $(5\%)$ mixture. To reduce the rms errors resulted from the CCD electronic noise and other sources, an expansion of grid size was attempted from $1\times1$ to 3(3 or 5(5 pixel data windows and the pertinent signal-to-noise level has been noticeably increased accordingly.

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LIF Conforcal Microscope을 이용한 Y-channel 마이크로믹서의 최적설계 연구 (The Study of Optimum Design of Y-Channel Micro-Mixer by Using LIF Conforcal Microscope)

  • 김상우;현석호;신태석;이도형
    • 대한기계학회논문집B
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    • 제33권5호
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    • pp.311-317
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    • 2009
  • Due to extremely small device size and velocity scale, mixing in microchannel take place very slowly by way of molecular diffusion transport. Mixing enhancement becomes a central issue in microfluidics for biomedical and chemical applications. In this work, The optimization results and validation through experiment and fabrication. In this efficient micromixer design, it is essential to evaluate mixing efficiency with good precision. Mixing efficiency for Y-channel micromixer is measured by fluorescence intensity using LIF(Laser Induced Fluorescence) Confocal Microscope. The Y-channel micromixers are fabricated with polydimethylsiloxane(PDMS). Nile Blue A is injected into the micromixer as a fluorescence dye for measuring of fluorescence intensity by He/Ne laser. Throughout the experiments and computer simulation, accurate mixing efficiency evaluation process for a PDMS Y-channel micromixer is established.