• 제목/요약/키워드: Langmuir films

검색결과 367건 처리시간 0.022초

ITO전극위의 Hetero형 폴리피리딘Ru착체 LB막의 표면측정과 전기화학적 감광특성 (Photoelectrochemical and Microscopic Studies in Hetero Type LB Films of Polypyridine Ru Complexes on ITO Electrodes)

  • 최인희;박수길;임기조;이주성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1995년도 추계학술대회 논문집
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    • pp.240-243
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    • 1995
  • The basic electrochemical and photochemical behavior of ultrathin mono- and hetero-type LB film of amphiphilic Ru bipyridine complex adsorbed on ITO electrode by the Langmuir- Blodgett(LB) method as monolayer and alternating multilayer state. With theoretical equation of cyclic voltammetry for redox species, the cyclic voltammogram were simulated successfully taking account the interaction parameters. We could fit almost all measured voltammograms with k$^{\circ}$=72s$\^$-1/, ${\alpha}$$\sub$a/=0.44, ${\alpha}$$\sub$c/=0.54, $\Gamma$$\sub$T/=1.4${\times}$10$\^$-10/, k=0.015s$\^$-1/ values. The AFM images of mono and hetero type LB film surfaces on ITO were also studied.

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DMPC LB박막의 유전완화현상 (Dielectric Relaxation Phenomena of DMPC LB Thin Film)

  • 최영일;송진원;조수영;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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    • pp.822-825
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    • 2003
  • Maxwell displacement current (MDC) measurement has been employed to study the dielectric property of Langmuir-films. A method for determining the dielectric relaxation time $\tau$ of floating monolayers on water surface is presented. WC flowing across monolayers is analyzed using a rod-like molecular model. It is revealed that the dielectric relaxation time $\tau$ of monolayers in the isotropic polar orientational phase is determined using a liner relationship between the monolayer compression speed ${\alpha}$ and the molecular area Am. Compression speed ${\alpha}$ was about 30, 40, 50mm/min.

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공기와 물이 형성하는 계면에서 발생하는 유기적으로 기능화된 은 나노 입자들의 2차원 조립 (Two-dimensional Assembly of Organically Functionalized Ag Nanoparticles at Air-water Interface)

  • 정성욱
    • 공업화학
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    • 제28권1호
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    • pp.125-131
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    • 2017
  • 본 연구에서는 유기적으로 기능화된 은 나노 입자들은 공기와 물이 형성하는 계면에서 자발적 조립 과정을 통해 새로운 2차원 상부 구조들(superstructures)을 생성하는 것을 발견하였다. 상부 구조의 분석은 금속 나노 입자의 심형과 입자계면에 결합된 유기 분자의 크기를 바꿈으로써 입자 간 특징적 상호 작용(characteristic inter-particle interaction)을 조절할 수 있고 이들 사이의 미묘한 상호 작용(subtle interplay)을 통해 은 나노 입자의 2차원 조립이 발생함을 시사한다. 본 연구를 통해 발견한 새로운 구조들은 기능성 나노 소재, 촉매 및 소자 응용 분야에 매우 중요한 잠재적 용도가 있을 것이라 사료된다.

유기 한분자학의 광자극 전달에 관한 연구 (A Study on the Light Stimulated Transmit of Organic Monolayers)

  • 강용철;권영수;조수영;박석순;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 추계학술대회 논문집
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    • pp.156-159
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    • 1996
  • Detection of displacement current across spreading organic Azodyes was investigated using a displacement current measuring technique. It was found that displacement current was generated only when dynamical motion of organic monolayers was initiated on the water surface by photo-isomerization and application of surface pressure. Displacement current was generated only in the range before the initial rise of Surface pressures for azo dyes(8A5H) we are using the Langmuir-Blodgett(LB) films deposition apparatus. We are obtain displacement current by pressure and light

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CuTBP(Copper-tetra-tert-butylphthalocyanine) 화학 저항 장치를 이용한 NO$_2$ 가스 탐지기의 개발에 관한 연구 (A study on the NO$_2$ gas detector development using the CuTBP (Copper-tetra-te rt-butylphthalocyanine) chemiresistor device)

  • 구자룡;이창희;김태완;김정수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 추계학술대회 논문집
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    • pp.417-420
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    • 1996
  • We have investigated air/200ppm NO$_2$ gas-detector characteristics of using CuTBP (Copper-tetra-tert-butylphthalocyanine) chemiresistor devices. The CuTBP films were made by Langmuir-Blodgett (LB) techniques. Sensitivity, response time, recovery time, and repoducibility of the devices were measured by current-voltage characteristics. To increase sensitivity, interdigital electrode was used. It was found that a conductance G increases monotonically as the number of interdigital electrode increases, and a Sensitivity, Reproducibility is stable. As far as a current is concerned, the current when N=25 is greater than that when N=1 by 70 or so. It indicates that the number of interdigital electrodes affects the current, sensitivity and stability We have also investigated applicability of the CuTBP chemiresistor device for a gas detector.

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수정진동자를 이용한 메로시아닌 색소 LB막의 광반응 특성 (The analysis of the optical response of merocyanine LB films using QCM)

  • 강기호;김정명;장정수;권영수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 추계학술대회 논문집 학회본부 C
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    • pp.434-436
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    • 2000
  • In this study, we investigate the optical characteristics of merocyanine dye Langmuir-Blodgett(LB) film using the oscillation characteristics of quartz crystal. As results, the resistance and frequency shift at the parallel resonance under the UV irradiation is to be going down. This behaviour of resistance and frequency is different from the case of general mass adsorption into the organic film on the quartz crystal. Generally the frequency decrease of quartz crystal oscillator, which has been considered as mass loading, goes along with the resistance increase. Thus it has been suggested that the J-aggregate dissociation in merocyanine dye LB film by UV irradiation give rise to transformation of oscillation characteristics of quartz crystal.

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금속이온 착체에 의한 IMI-O 고분잔 LB막의 전기적 특성 (Electrical Properties of IMI-O Polymer LB Films in Complexed Metal Ion)

  • 정상범;유승엽;박재철;권영수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1997년도 하계학술대회 논문집 C
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    • pp.1519-1521
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    • 1997
  • In this paper, poly (N-(2-4-imidazolyl) ethyl) maleimide-alt-1-octadecene (IMI-O) polymer which can complex metal ion was used to confirm the possibility of molecular device made by Langmuir-Blodgett method. Metal/Insulator/Metal (MIM) device was fabricated for investigation of electric properties. In the ${\pi}$-A isotherm, surface pressure at collapse point was different as to the molecular weight of metal ion complexed respectively, In I-V characteristics, currents of MiM devices were different at the same voltage. It was thought that phenomena was occurred by interaction between function group and metal ion.

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pH변화에 대한 Palmitic Acid LB막의 유기가스 반응특성 (The Response Properties of Organic Gas for the Palmitic Acid LB films by the Effect of pH)

  • 강기호;김정명;장정수;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 추계학술대회 논문집
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    • pp.317-319
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    • 2000
  • We fabricated the QCM with Langmuir-Blodgett(LB) film deposited at the different subphase pH and investigated the resonant frequency response by the injection of organic gas response. In the $\pi$-A isotherms, the monolayer on the air/water interface had different limiting area per molecule and showed more condensed status as increasing the subphase pH. When palmitic acid LB film was deposited on the QCM, the resonant frequency shift was proportional to the deposited layer and had more resonant frequency shift in the case of the higher pH range as expected. In the resonant frequency for the injection of organic gas, it has been improved in the case of LB film fabricated at the lower subphase pH range and dependant upon the molecular weight of organic gas.

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Arac.acid의 유전완화현상 (Dielectric Relaxation Phenomena of Arac.acid)

  • 송진원;조수영;이영길;이경섭
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 하계학술대회 논문집 C
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    • pp.1583-1585
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    • 2003
  • Maxwell displacement current(MDC) measuring technique has been employed to study the dielectric property of Langmuir-films. A method for determining the dielectric relaxation time ${\tau}$ of floating monolayers on the water surface is presented. MDC flowing across monolayers is analyzed using a rod-like molecular model. It is revealed that the dielectric relaxation time ${\tau}$ of monolayers in the isotropic polar orientational phase is determined using a liner relationship between the monolayer compression speed ${\alpha}$ and the molecular area Am. Compression speed ${\alpha}$ was about 30, 40, 50mm/min.

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펄스 마그네트론 스퍼터링으로 합성된 카본 박막의 수분 투습도와 물리적 에너지와의 상관관계에 대한 고찰 (A Study of physical energy and water vapor transmission rate of carbon films synthesized by pulse magnetron sputtering)

  • 진수봉;김성일;송두훈;한전건
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2007년도 추계학술대회 논문집
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    • pp.33-34
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    • 2007
  • DLC를 포함한 탄소 박막은 우수한 특성으로 인해 세계적으로 많은 연구들이 진행 되고 있다. 본 연구에서는 탄소 박막의 산소 및 수분 차단 특성 및 광투과율의 특성과 플라즈마 변수와의 상관관계를 규명 하고자 하였으며, 이러한 상관관계를 Langmuir probe, UV-spectroscopy, MOCON 의 분석기구를 통하여 플라즈마 변수와 박막의 특성을 분석 하였으며, 수분 투과도는 4g/m$^2$/day까지 감소하는 결과를 얻었다.

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