• 제목/요약/키워드: Langmuir films

검색결과 367건 처리시간 0.021초

$C_{22}$-Quinolium(TCNQ) LB Film의 평면 전기전도 특성 (Characteristics of Surface Electrical Conduction in $C_{22}$-Quinolium(TCNQ) LB Films)

  • 박승규;유덕수;김태완;강도열
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1992년도 춘계학술대회 논문집
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    • pp.77-81
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    • 1992
  • $C_{22}$-Quinolium-TCNQ LB films were deposited on the glass substrates by Langmuir-Blodgett technique at room temperature. Transfer ratios and UV-visible absorption spectra were studied for X, Y and Z-Types. Absorption in Z-Type was higher than X and Y-Types, which indicates a better arrangement in this type. We have also investigated dc electrical conductivities and ac responses along the horizontal and vertical direction to the film surface. As a result, we are able to determine the capacitance of film and the measured horizontal conductivity was about $10^{-7}$~$10^{-8}$ S/cm.

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N-docosyl pyridinium(TCNQ) LB막의 NO$_2$가스탐지 특성에 관한 연구 (A Study of The NO$_2$Gas Detect Properties of N-docosyl pyridinium(TCNQ) LB Film)

  • 유병호;조형근;김형석;이창희;김정수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1994년도 춘계학술대회 논문집
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    • pp.75-78
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    • 1994
  • Organic ultra thin films about 500${\AA}$ in thickness are fabricated by LB(Langmuir-Blodgett) technique and their gas detect properties are investigated. The LB films deposited are made of the specimen named as N-docosyl pyridinium(TCNQ) and the deposition is verified by capacitance conductivity measurement. From the study of gas detect properties with I-V characteristics and UV spectrum we have found that their conductivities were increased about 3 times of magnitude and peaks of UV spectrum were decreased.

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유기박막의 자격속도에 따른 응답특성에 관한 연구 (A Study on the Response Characteristic by Stimulus Speed of Organic Thin Films)

  • 조수영;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 추계학술대회 논문집
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    • pp.385-388
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    • 1997
  • We hate examined the electrical properties of L-${\alpha}$-DLPC Langmuir(L) films by using a displacement current measuring technique with pressure stimulation. Displacement current was generated when the sample spread volume was about 280${\mu}\ell$, 360${\mu}\ell$ and compression velocity was about 30, 40, 50mm/min. Displacement current was generated in the range of gas state, gas/fluid state and fluid state in the course of monolayer compression. From the result, it is known that displacement current is generated in the range of high surface pressures as compression velocity become faster.

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실리콘 웨이퍼 위에 제작된 DLPC 지질막의 전기적특성 (Elctrical Properties of DLPC Lipid Membrane Fabricated on the Silicon Wafer)

  • 이우선;김충원;이강현;정용호;김남오;김상용
    • 한국전기전자재료학회논문지
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    • 제11권12호
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    • pp.1115-1121
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    • 1998
  • MLS capacitor with lipid ultra thin films were deposited by Langmuir-Blodgett (LB) method on the silicon wafer. The current versus voltage and capacitance versus voltage relationships are depend on the applied voltage, electrode area and electrode materials. LB films deposited were made of L-$\alhpa$-DLPC, the 1 layer’s thickness of 35${\AA}$ was measured by ellipsometer. And MLS capacitor with different electrode materials, the work function of these materials was investigated to increase the leakage current. The result indicated the lower leakage current and very high saturation value of capacitance was reached within 700-800 pF when the two electrode was Ag. And $\varepsilon$1, $\varepsilon$2 versus photon energy showed good film formation.

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감광성 polyimide LB막의 pattern형성에 관한 연구 (A study on patterning of photosensitive polyimide LB film)

  • 김현종;채규호;김태성
    • E2M - 전기 전자와 첨단 소재
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    • 제9권1호
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    • pp.59-66
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    • 1996
  • Polyimides containing cyclobutane ring in main chain is known to be thermally stable and able to be developed in organic solvents after photolysis with 254 nm UV light. This type of polyimides can be used as promising positive photoresist in VLSI fabrication process. In the current VLSI process, photoresist films are formed by spin coating. The film thickness is more than several hundred nano meters. It seems that there is room for improvement of film coating process by introducing Langmuir Blodgett technique. Thereby ultra thin film photoresist can be formed, and higher density of integration in VLSI be achieved. In the present work, depositing procedure of LB films of this polyimide was investigated. LB film thickness was measured by ellipsometry to evaluate deposited film status. Chemical imidization procedure was studied to avoid several problems in thermal imidization. The pattern of submicron dimension has successfully formed on LB film of 8nm thick, which found showing good contrast.

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고분자 감웅성 LB막을 이용한 One-channel 가스센서의 개발연구 (A Study on Development of One-channel Gas Sensor Using Polymeric Sensitive LB Films)

  • 강현욱;김정명;권영수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 추계학술대회 논문집 학회본부
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    • pp.261-263
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    • 1996
  • The study on the development of one-channel gas sensor using the quartz crystal analyzer were attempted. The adsorption and desorption behavior of organic gases were investigated using the resonant frequency and resistance method of quartz crystal. The sensitive materials were deposited on the quartz crystal analyzer(QCA) by using Langmuir-Blodgett method. To investigate the response characteristics of organic vapours and response mechanism, resonant frequency-resonant resistance (F-R) diagram was used. In our experimental results, the response mechanism between sensitive LB film and organic vapours was obtained using F-R diagram. And the position of each organic vapour were different as to the kind and injection amount. Thus F-R diagram can be applied to one-channel gas sensor using the QCA and useful to analyze the response mechanism between organic vspours and sensitive LB films.

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Arachidic Acid의 누독막(累讀膜)과 전기적특성(電氣的特性) (Electrical properties and deposited films of Arachidic Acid)

  • 조수영;전동규;이경섭;이우선;정헌상
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 추계학술대회 논문집 학회본부
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    • pp.215-217
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    • 1996
  • We have examined the electrical properties of arachidic acid Langmuir(L)films by using a displacement-current-measuring technique with pressure stimulation, displacement current peak appeared at a area per molecule around $90{\AA}^2$, possibly due to the orientational change in hydrophobic part of arachidic acid molecules. The displacement current is the transient current, it is generated when charged particles existing in single monolayers are displaced with the external stimulation. In this report, we mainly describe the displacement current generation from arichidic acid monolayers with pressure stimulation.

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Effect of ligand orientation on hepatocyte attachment onto the poly(N-p-vinyl benzyl-o-$\beta$-D-galactopyranosyl-D-gluconamide)

  • 조종수
    • 대한의용생체공학회:학술대회논문집
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    • 대한의용생체공학회 1996년도 춘계학술대회
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    • pp.123-125
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    • 1996
  • The orientation effect of galactose ligand on hepatocyte attachment was investigated. Poly(N-p-vinyl benzyl-o-${\beta}$-D-galactopyranosyl-D-gluconamide) (PVLA), a ${\beta}$-galactose-carrying styrene homo-polymer, was used as a model ligand for the asialoglycoprotein receptors on hepatocytes. PYVA was transferred onto the poly(${\gamma}$-benzyl L-glutamate)(PBLG) or PBLG/ poly(ethylene glycol)(PEG)/PBLG Langmuir-Blodgett (LB) films as the monolayer level. The dichroic fluorescence values of confocal microscope indicated that the PVLA transferred onto the LB films was located with a preferential orientation of its molecular axes with regard to the direction of the a-helix of polypeptide. Hepatocyte recognized well-oriented galactose moieties of the surface of PVLA through asialoglycoprotein receptors.

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Alkyloxyazobenzene 유도체의 광이성질화 현상에 관한 연구 (A Study on the Photoisomerization of the Akyloxyazobenzene Derivatives)

  • 박근호;김성일;김동완;김범준;박태곤
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.467-470
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    • 2000
  • We synthsized the P-nonyloxyazobenzene derivatives with functiona1 structures and carried out this experiment to observe Photoisomerization irradiated by alternate lights. We found that it was reversibly induced to cis-trans photoisomerization in several solvents. Spreading solutions for the LB films were prepared in chloroform(1.2${\times}$10$\^$-2/ mmol). As a result it is found that the absorption spectra of the Langmuir-Blodgett(LB) monolayer films was induced to photoisomerization by alternative irradiation lights, temperatures respectively.

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DPPC 유기박막의 상전이에 관한 연구 (A Study on the Phase Transition of DPPC Organic Films)

  • 김동관;이순형;최영일;최충석;장희동;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.491-494
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    • 2000
  • Conductive Langmuir-Blodgett(LB) films have recently attracted much interest from the viewpoint of ultrathin film conductors at the molecular level. The result shows that the Maxwell-displacement-current(MDC) measuring technique is useful in the detection of phase-transition over the entire range of molecule areas. At the liquid-solid phase transition, a striking feature in the present current measurement was observed; the I-A isotherm for a DPPC monolayer has sharp bend. Dynamic behavior of monolayers in the presence of an external field was also investigated using the current-measuring technique. Dynamic behavier of DPPC monolayer was measured by displacement current when the molecules are stimulated by pressure velocity. As result, it is known that current is generated of higher current pe마 as compression velocity become faster. Also, in order to clarify the reorganization of the lipid monolayers, it is instructive to plot the relationship between I and 1/$A^2$.

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