• 한국연소학회:학술대회논문집
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• 2001.06a
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• pp.133-138
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• 2001

In this study, quantitative nitric oxide concentration distributions are investigated in the laminar nonpremixed $H_2/N_2$ flames by laser-induced fluorescence (LIF). The measurements are taken in flames for different $N_2$ dilution ratios varying from 20${\sim}$80%, and fuel now rate is fixed as lslpm. The NO A-X (0,0) vibrational band around 226 nm is excited using a XeCl excimer-pumped dye laser. We applied same excitation line used in $CH_4$ premixed flame. Overall, NO concentration was rapidly decreased with $N_2$ addition and we could not measure the concentration any longer for $N_2$ dilution above 80%.

• Journal of the Korean Society of Combustion
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• v.16 no.4
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• pp.38-45
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• 2011

Coal-derived syngas has been utilized by main fuel at IGCC power plant. Research efforts for investigating the characteristics of premixed and nonpremixed flames at gas-turbine condition have been conducted. The present study has been mainly motivated to evaluate the capability of the detailed chemical kinetics to predict the syngas laminar flame speed. Special emphasis is given to the effects of pressure, temperature, syngas composition, and dilution level on the characteristics of premixed and nonpremixed flames. The predicative capability of a number of detailed mechanism for laminar flame speed is compared to experimental data. From these results, detailed kinetics of Davis et al. and Li et al. have the best conformity with the experiments in the all the case of parametric studies.

• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.6
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• pp.80-89
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• 2002

The flame structure and soot formation in Acetylene-Air nonpremixed jet flame are numerically analyzed. We employed two variable approach to investigate the soot formation and oxidation processes. The present soot reaction mechanism involves nucleation, surface growth, particle coagulation, and oxidation steps. The gas phase chemistry and the soot nucleation, surface growth reactions are coupled by assuming that the nucleation and soot mass growth has the certain relationship with the concentration of pyrene and acetylene. We also employed laminar flamelet model to calculate the thermo-chemical properties and the proper soot source terms from the information of detailed chemical kinetic model. The numerical and physical model used in this study successfully predict the essential features of the combustion processes and soot formation characteristics in the reaction flow field.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.24 no.12
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• pp.1582-1582
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• 2000

Rayleigh scattering and laser induced predissociative fluorescence are employed for capturing two-dimensional images of temperature and species concentration in a laminar nonpremixed flame of a diluted hydrogen jet. Rayleigh scattering cross-sections are experimentally obtained at 248nm. Dispersed LIPF spectra of OH and O₂ are also measured in a flame in order to confirm the excitation of single vibronic state of OH and O₂are excited on the P₁(8) line of the A ²∑+ (v＇=3) - X ²∏(v˝=0) band and R(17) line of the Schumann-Runge band B ³∑u- (v＇=0) - X ³∑g-∏(v˝=6), respectively. Fluorescence spectra of OH and Hot O₂ are captured and two-dimensional images of the hydrogen flame field are successfully visualized.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.24 no.12
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• pp.1580-1587
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• 2000

Rayleigh scattering and laser induced predissociative fluorescence are employed for capturing two-dimensional images of temperature and species concentration in a laminar nonpremixed flame of a diluted hydrogen jet. Rayleigh scattering cross-sections are experimentally obtained ar 248nm. Dispersed LIPF spectra of OH and O$_2$ are also measured in a flame in order to confirm the excitation of single vibronic state of OH and O$_2$ .OH and O$_2$ are excited on the P$_1$(8) line of the A $^2\Sigma ^+(v^`=3) - X^2\pi (V^"=0)$ band and R(17) line of the Schumann-Runge band B $^3\Sigma _u^-(v^`=0) - X ^3\Sigma _g^-(v^"=6)$, respectively. Fluorescence spectra of OH and Hot O$_2$ are captured and two-dimensional images of the hydrogen flame field are successfully visualized.

• Journal of the Korean Society of Combustion
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• v.4 no.1
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• pp.131-139
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• 1999

A Numerical Analysis of NOx production in Hydrogen-Air flame is performed using the quasi-laminar reaction modelling. As results, in low global strain rate region, $U_F/D_F\;{\leq}\;50,000$, the quasi-laminar reaction modelling reproduces the experimentally observed EINOx half power scaling that the ratio of EINOx and flame residence time, $L_f^3(D_F^2U_F)$, is proportional to the square root of global strain rate. Thus, it suggests that turbulence-chemistry interaction has a minor impact on the trend of NOx production in low global strain rate region. However, the quasi-laminar reaction modelling predicts the higher temperature and NOx than experimentally observed. This overprediction may be due to the lack of radiation and quasi-laminar reaction modelling.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.31 no.11
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• pp.926-935
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• 2007

The NOx emission characteristics of DME in laminar coaxial jet and counterflow nonpremixed flames were investigated using experimental and numerical approaches, respectively. The flame structure and NOx emission of DME were compared with those of $C_2H_6$ and $C_3H_8$. The DME flame was calculated using the Kaiser's mechanism, while the $C_2H_6$ and $C_3H_8$ flames were calculated using the $C_3$ mechanism. These mechanisms were combined with the modified Miller-Bowman mechanism for the analysis of NOx. Experimental results show in coaxial jet flame that DME flame has the characteristics of partial premixed flame and the flame length decreases up to 1/3 than that of $C_3H_8$ in the same condition of fuel mass flowrate. Then, the NOx emission of DME decreases to 40% approximately, comparing with that of $C_3H_8$. In the calculated results of counterflow nonpremixed flame, DME flame shows the $EI_{NO}$ decreases up to 50% approximately than those of$ C_2H_6$ and $C_3H_8$ flames when the equivalent fuels are consumed per unit mass and time. Although the overall NOx reaction path of DME is similar with other hydrocarbon fuels, it can be identified that DME flame has a distinct NO reduction mechanism due to the reburning NO chemistry in fuel rich region. From these results, we can conclude that the different NOx emission characteristics of DME flame with other hydrocarbon fuels are attributed to not the temperature increase and the activation of NO reactions due to O atom in DME fuel but the rapid processes of pyrolysis/oxidation.

• Journal of the Korean Society of Combustion
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• v.4 no.2
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• pp.51-62
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• 1999

NOx formation in turbulent flames is strongly coupled with temperature, superequilibrium concentration of O radical, and residence time. This implies that in order to accurately predict NO level, it is necessary to develop sophisticated models able to account for the complex turbulent combustion processes including turbulence/chemistry interaction and radiative heat transfer. The present study numerically investigates the turbulent nonpremixed hydrogen jet flames using the laminar flamelet model. Flamelet library is constructed by solving the modified Peters equations and the turbulent combustion model is extended to nonadiabatic flame by introducing the enthalpy defect. The effects of turbulent fluctuation are taken into account by the presumed joint PDFs for mixture fraction, scalar dissipation rate, and enthalpy defect. The predictive capability of the present model has been validated against the detailed experimental data. Effects of nonequilibrium chemistry and radiative heat loss on the thermal NO formation are discussed in detail.

• 한국연소학회:학술대회논문집
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• 1999.10a
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• pp.93-104
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• 1999

NOx formation in turbulent flames is strongly coupled with temperature, superequilibrium concentration of O radical, and residence time. This implies that in order to accurately predict NO level, it is necessary to develop sophisticated models able to account for the complex turbulent combustion processes including turbulence/chemistry interaction and radiative heat transfer. The present study numerically investigates the turbulent nonpremixed hydrogen jet flames using the laminar flamelet model. Flamelet library is constructed by solving the modified Peters equations and the turbulent combustion model is extended to nonadiabatic flame by introducing the enthalpy defect. The effects of turbulent fluctuation are taken into account by the presumed joint PDFs for mixture fraction, scalar dissipation rate, and enthalpy defect. The predictive capability of the present model has been validated against the detailed experimental data. Effects of nonequilibrium chemistry and radiative heat loss on the thermal NO formation are discussed in detail.

• Journal of ILASS-Korea
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• v.7 no.4
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• pp.42-49
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• 2002

In this study, quantitative measurement of nitric oxide concentration distributions were investigated in the laminar CH4/O2/N2 premixed flame by laser-induced fluorescence (LIF). The NO A-X (0,0) vibrational band around 226nm was excited using a XeCl excimer-pumped dye laser. Selecting an appropriate NO transition minimizes interference from Rayleigh scattering and O2 fluorescence. The measurements were taken in CH4/O2/N2 premixed flame with equivalence ratios varying from $1.0{\sim}1.6$, and a fixed flowrate of 5slpm. NO was found to produce primarily between an inner premixed and an outer nonpremixed flame front, and total NO concentration is raised when equivalence ratios increase. These results suggest that prompt NO is likely to contribute to NO formation in CH4/O2/N2 premixed flame. Furthermore, this trend was well matched with previous works.