• Journal of Environmental Science International
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• v.11 no.5
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• pp.419-436
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• 2002

The current paper reports on the enhancement of O$_3$, CO, NO$_2$, and aerosols during the Asian dust event that occurred over Korea on 1 May 1999. To confirm the origin and net flux of the O$_3$, CO, NO$_2$, and aerosols, the meteorological parameters of the weather conditions were investigated using Mesoscale Meteorological Model 5(MM5) and the TOMS total ozone and aerosol index, the back trajectory was identified using the Hybrid Single-Particle Lagrangian Integrated Trajectory Model(HYSPLIT), and the ozone and ozone precursor concentrations were determined using the Urban Ashed Model(UAM). In the presence of sufficiently large concentrations of NO$\sub$x/, the oxidation of CO led to O$_3$ formation with OH, HO$_2$, NO, and NO$_2$ acting as catalysts. The sudden enhancement of O$_3$, CO, NO$_2$ and aerosols was also found to be associated with a deepening cut-off low connected with a surface cyclone and surface anticyclone located to the south of Korea during the Asian dust event. The wave pattern of the upper trough/cut-off low and total ozone level remained stationary when they came into contact with a surface cyclone during the Asian dust event. A typical example of a stratosphere-troposphere exchange(STE) of ozone was demonstrated by tropopause folding due to the jet stream. As such, the secondary maxima of ozone above 80 ppbv that occurred at night in Busan, Korea on 1 May 2001 were considered to result from vertical mixing and advection from a free troposphere-boundary layer exchange in connection with an STE in the upper troposphere. Whereas the sudden enhancement of ozone above 100 ppbv during the day was explained by the catalytic reaction of ozone precursors and transport of ozone from a slow-moving anticyclone area that included a high level of ozone and its precursors coming from China to the south of Korea. The aerosols identified in the free troposphere over Busan, Korea on 1 May 1999 originated from the Taklamakan and Gobi deserts across the Yellow River. In particular, the 1000m profile indicated that the source of the air parcels was from an anticyclone located to the south of Korea. The net flux due to the first invasion of ozone between 0000 LST and 0600 LST on 1 May 1999 agreed with the observed ground-based background concentration of ozone. From 0600 LST to 1200 LST, the net flux of the second invasion of ozone was twice as much as the day before. In this case, a change in the horizontal wind direction may have been responsible for the ozone increase.

• Korean Journal of Remote Sensing
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• v.30 no.5
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• pp.597-605
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• 2014

The continuous observations for atmospheric aerosols were conducted during 3 years (2009 to 2011) by using Gwangju Institute of Science and Technology (GIST) multi-wavelength Raman lidar at Gwangju, Korea ($35.10^{\circ}N$, $126.53^{\circ}E$). The aerosol depolarization ratios calculated from lidar data were used to identify the Asian dust layer. The optical properties of Asian dust layer were different according to its vertical distribution. In order to investigate the difference between the optical properties of each individual dust layers, the transport pathway and the transport altitude of Asian dust were analyzed by Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model. We consider that the variation of optical properties were influenced not only their transport pathway but also their transport height when it passed over anthropogenic pollution source regions in China. The lower particle depolarization ratio values of $0.12{\pm}0.01$, higher lidar ratio of $67{\pm}9sr$ and $68{\pm}9sr$ at 355 nm and 532 nm, respectively, and higher ${\AA}ngstr\ddot{o}m$ exponent of $1.05{\pm}0.57$ which are considered as the optical properties of pollution were found. In contrast with this, the higher particle depolarization ratio values of $0.21{\pm}0.09$, lower lidar ratio of $48{\pm}5sr$ and $46{\pm}4sr$ at 355 nm and 532 nm, respectively, and lower ${\AA}ngstr\ddot{o}m$ exponent of $0.57{\pm}0.24$ which are considered as the optical properties of dust were found. We found that the degree of mixing of anthropogenic pollutant aerosols in mixed Asian dust govern the variation of optical properties of Asian dust and it depends on their altitude when it passed over the polluted regions over China.

• Journal of Environmental Science International
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• v.29 no.1
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• pp.55-68
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• 2020

The purpose of this study is to investigate the relationship of fine dust PM₁₀ and heavy metals in PM₁₀ in Asian dust flowing into Gwangju from 2013 to 2018. The migration pathways of Asian dust was analyzed by backward trajectory analysis using HYSPLIT (Hybrid Single Particle Lagrangian Integrated Trajectory) model, and the change of heavy metal concentration and heavy metal content per 1 ㎍/㎥ of fine dust PM₁₀ in Gwangju area were analyzed. Also, the characteristics of the heavy metals were analyzed using the correlation between the heavy metals in PM₁₀. As a result of analyzing Asian dust entering the Gwangju region for 6 years, the average concentration of PM₁₀ measured in Asian dust was 148 ㎍/㎥, which was about 4.5 times higher than in non-Asian dust, 33 ㎍/㎥. A total of 13 Asian dust flowed into the Gwangju during 6 years, and high concentration of PM10 and heavy metals in that were analyzed in the C path flowing through the Gobi/Loess Plateau-Korean Peninsula. As a result of the correlation analysis, in case of Asian dust, there was a high correlation between soil components in heavy metals, so Asian dust seems to have a large external inflow. On the other hand, in case of non-Asian dust, the correlation between find dust PM₁₀ and artificial heavy metal components was high, indicating that the influence of industrial activities in Gwangju area was high.

• Korean Journal of Remote Sensing
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• v.30 no.6
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• pp.743-754
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• 2014

In this present paper, we, for the first time, calculated $SO_2$ inflow from China to Korea peninsula based on OMI $SO_2$ products and HYSPLIT (Hybrid Single Particle Lagrangian Integrated Trajectory Model) backward trajectory calculations. The major factors used to estimate $SO_2$ flux are long range transported $SO_2$ concentration, transport speed of air mass, and thickness of transported air mass layer. The mean and maximum $SO_2$ fluxes are estimated to be 0.81 and $2.11g{\cdot}m^{-2}{\cdot}h^{-1}$, respectively based on OMI products while, those of $SO_2$ fluxes are 0.50 and $1.18g{\cdot}m^{-2}{\cdot}h^{-1}$ respectively using insitu data obtained at the surface. For most cases, larger $SO_2$ inflow values were found at the surface than those estimated for the air mass layer which extends from surface up to 1.5 km. However, increased transport speed of air mass leads to the enhanced $SO_2$ flux at the altitude up to 1.5 km at the receptor sites. Additionally, we calculate uncertainties of $SO_2$ flux using error propagation method.

• Journal of Environmental Science International
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• v.26 no.2
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• pp.183-200
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• 2017

The classification of airflow patterns during high ozone ($O_3$) and $PM_{10}$ episodes on Jeju Island in recent years (2009-2015), as well as their correlation with meteorological conditions according to classified airflow patterns were investigated in this study. The airflow patterns for $O_3$ and $PM_{10}$ were classified into four types (Types A-D) and three types (Types E-G), respectively, using the HYbrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model and synoptic weather charts. Type A was the most dominant airflow pattern for $O_3$ episodes, being characterized by the transport of airflows from urban and industrial areas in China with the highest frequency (about 69%, with a mean of 67 ppb). With regard to the $PM_{10}$ episodes, Type E was the most dominant airflow pattern, and was mostly associated with long distance transport from Asian dust source regions along northwesterly winds, having the highest frequency (about 92%, with a mean of $136{\mu}g/m^3$). The variations in the concentration of $O_3$ and $PM_{10}$ during the study period were clarified in correlation with two pollutant and meteorological variables; for example, the high (low) $O_3$ and $PM_{10}$ concentrations with high (low) air temperature and/or wind speed and vice versa for precipitation. The contribution of long-range transport to the observed $PM_{10}$ levels in urban sites for different airflow patterns (Types E-F), if estimated in comparison to the data from the Gosan background site, was found to account for approximately 87-93% (on average) of its input. The overall results of the present study suggest that the variations in $O_3$ and $PM_{10}$ concentrations on Jeju Island are mainly influenced by the transport effect, as well as the contribution of local emissions.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.2
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• pp.165-174
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• 2010

The numerical modeling of a coal gasification reaction occurring in an entrained flow coal gasifier is presented in this study. The purposes of this study are to develop a reliable evaluation method of coal gasifier not only for the basic design but also further system operation optimization using a CFD(Computational Fluid Dynamics) method. The coal gasification reaction consists of a series of reaction processes such as water evaporation, coal devolatilization, heterogeneous char reactions, and coal-off gaseous reaction in two-phase, turbulent and radiation participating media. Both numerical and experimental studies are made for the 1.0 ton/day entrained flow coal gasifier installed in the Korea Institute of Energy Research (KIER). The comprehensive computer program in this study is made basically using commercial CFD program by implementing several subroutines necessary for gasification process, which include Eddy-Breakup model together with the harmonic mean approach for turbulent reaction. Further Lagrangian approach in particle trajectory is adopted with the consideration of turbulent effect caused by the non-linearity of drag force, etc. The program developed is successfully evaluated against experimental data such as profiles of temperature and gaseous species concentration together with the cold gas efficiency. Further intensive investigation has been made in terms of the size distribution of pulverized coal particle, the slurry concentration, and the design parameters of gasifier. These parameters considered in this study are compared and evaluated each other through the calculated syngas production rate and cold gas efficiency, appearing to directly affect gasification performance. Considering the complexity of entrained coal gasification, even if the results of this study looks physically reasonable and consistent in parametric study, more efforts of elaborating modeling together with the systematic evaluation against experimental data are necessary for the development of an reliable design tool using CFD method.