• Corrosion Science and Technology
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• v.7 no.1
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• pp.61-67
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• 2008

In this paper, electrochemical and microstructural characteristics of nickel-plated Alloy 600 were investigated in order to identify the performance of electroless Ni-plating on Alloy 600 in high-temperature aqueous condition with the comparison of electrolytic nickel-plating. For high temperature corrosion test of nickel-plated Alloy 600, specimens were exposed for 770 hours to typical PWR primary water condition. During the test, open circuit potentials (OCP's) of all specimens were measured using a reference electrode. Also, resistance to flow accelerated corrosion (FAC) test was examined in order to check the durability of plated layers in high-velocity flow environment at high temperature. After exposures to high flow rate aqueous condition, the integrity of surfaces was confirmed by using both scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). For the field application, a remote process for electroless nickel-plating was demonstrated using a plate specimen with narrow gap on a laboratory scale. Finally, a practical seal design was suggested for more convenient application.

• Corrosion Science and Technology
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• v.2 no.5
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• pp.207-211
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• 2003

The weather resistance of five coatings systems based on alkyd, chlorinated rubber, epoxy, polyurethane and fluoropolymer were studied by natural exposure test and accelerated test. The coatings were exposed at Hanoi station with urban industry atmosphere and at Baichay station with marine atmosphere. The degradation of coatings was evaluated by gloss measurement and surface analysis by scanning electronic microscopy. The results obtained show that among coatings tested the gloss of polyurethane and fluoropolymer coatings remained highly and those of alkyd, chlorinated rubber and epoxy coatings were very low after two years of atmospheric exposure. Under accelerating conditions the gloss of fluoropolymer coatings remained highly after 80 cycles of testing. By comparison with accelerating test in UV-condensation chamber the conditions at atmospheric stations are more aggressive.

• Corrosion Science and Technology
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• v.10 no.4
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• pp.151-155
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• 2011

The iron oxide particles could be resulted from the corrosion of the circulating water system of a power plant. Because it may be one of the trouble materials which affect the power generation efficiency due to the deposition on steam generator tube and turbine blade, the continuous observation of its concentration is very important. The laser induced break-down detection (LIBD) technology was applied to monitor continuously the concentration of corrosion products with the detection limit of ppb level. The measurement system consists of a Nd:YAG pulsed laser, a polarizing beam splitter, a flow-type sample cell, an acoustic emission sensor, a high speed data acquisition board, a personal computer, etc.. The performance test results confirmed that this technology can be effective to monitor the corrosion product concentration of the circulating water system of a power plant.

• Korean Journal of Metals and Materials
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• v.48 no.4
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• pp.277-288
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• 2010

The hot corrosion properties of heat-resistant steels were investigated in an oxidation atmosphere including artificial ash and sulfur dioxide. The heat-resistant steels of T22, T92, T122, T347HFG, Super304H and HR3C were evaluated at 620, 670 and $720^{\circ}C$ for 400 hours. The relationship between the corrosion rate and the temperature followed a bell-shaped curve with a peak rate at around $670^{\circ}C$. The corrosion rates showed a decreasing tendency as the chrome contents of these steels increased from 2.15 wt.% to 24.5 wt.%, and austenitic steels had a lower corrosion rate than ferritic steels. Sulfidation by $SO_2$ as well as molten salt corrosion also had an effect on the total corrosion rate, especially showing an increase in the corrosion rate in ferritic steels. Regardless of the chrome content in the steels and irrespective of the test temperature, the corrosion scale was composed of an outer oxide and an artificial ash mixed layer, a middle oxide layer and inner sulfide, and a mixed oxide layer. As the chrome content increased, the proportion of chrome oxide in the corrosion scale increased. Before spalling of the corrosion scale, voids and cracks were initiated in the sulfide and the mixed oxide layer or at the interface with the substrate.

• Journal of the Korea Concrete Institute
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• v.11 no.6
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• pp.129-135
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• 1999

Reinforced concrete structures are constructed under the basic assumption of perfect bonding between steel and concrete. The corrosion of steel in the reinforced concrete beams results in the excessive cracks and gradual deterioration of concrete. This paper are concerned about the slip characteristics of reinforced concrete between steel and concrete. The accelerated test by external power supply was conducted with the three corrosion rates in the laboratory. As a result, it was obtained as follows: (1) the yield strength of steel was reduced according to corrosion states. (2) the equivalent steel area should be considered for detailed analysis. (3) According to the use of corroded steel or not, slip amounts between concrete and steel in test beams increased as the corrosion rate increased. These results can be explained from the bond loss between concrete and steel in test beams.

• Nuclear Engineering and Technology
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• v.54 no.6
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• pp.1972-1981
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• 2022

A typical ferritic/martensitic (F/M) steel sheet was subjected to pulsed laser surface remelting (LSR) and corrosion test in lead-bismuth eutectic (LBE) at 550 ℃. There present two modification zones with distinct microstructures in the LSRed specimen: (1) remelted zone (RZ) consisting of both bulk δ-ferrite grains and martensitic plates and (2) heat-affected zone (HAZ) below the RZ, mainly composed of martensitic plates and high-density precipitates. Martensitic transformation occurs in both the RZ and the HAZ with the Kurdjumov-Sachs and Nishiyama-Wassermann orientation relationships followed concurrently, resulting in scattered orientations and specific misorientation characteristics. Hardnesses of the RZ and the HAZ are 364 ± 7 HV and 451 ± 15 HV, respectively, considerably higher than that of the matrix (267 ± 3 HV). In oxygen-saturated and oxygen-depleted LBE, thicknesses of oxide layers developed on both the as-received and the LSRed specimens increase with prolonging corrosion time (oxide layers always thinner under the oxygen-depleted condition). The corrosion resistance of the LSRed F/M steel in oxygen-saturated LBE is improved, which can be attributed to the grain-refinement accelerated formation of dense Fe-Cr spinel. In oxygen-depleted LBE, the growth of oxide layers is very low with both types of specimens showing similar corrosion resistance.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.04a
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• pp.129-134
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• 1999

Recent construction activities and maintenance of marine facilities have been accelerating to keep up with rapid economic growth in Korea. Marine concrete structures are to salts and chloride from ocean environments. The corrosion of reinforcement steel caused by chloride-penetration into concrete may severely affect the durability of concrete structures. the objective of this research is to develop a durable concrete by investigating the resistance of various corrosion protection systems utilizing different water/cement ratio, silica fumes, corrosion inhibitors, etc. A two-year verification test on various corrosion protection system has been doing in the laboratory. Corrosion investigations on reinforcement steel are now under progress for more than 63 concrete specimen. Corrosion-related measurements include microcell corrosion current.

• Corrosion Science and Technology
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• v.2 no.1
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• pp.53-57
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• 2003

The MarM247 based superalloy (8wt.%Cr- 9wt.%Co- 3wt.%Ta- 1.5wt.%Hf- 5.6%wt.Al- 9.5wt.%W- Bal. Ni) specimens were diffusion aluminized by for types of pack cementation methods, and their coating structure and their high temperature oxidation resistance were investigated. The coated specimens treated at 973K in high aluminum concentration pack had a coating layer containing large hafunium rich precipitates, which were originally included in substrate alloy. After the high temperature oxidation test in air containing 30 vol.% $H_2O$ at 1273K ~ 323K, the deep localized corrosion which reached to the substrate were observed along with these hafnium rich precipitates. On the other hand, the coated specimens treated at 1323K using low aluminum concentration pack showed the coating layer without the large hafunium rich precipitates, and after the high temperature oxidation test at 1273K for 1800 ksec, it did not show the deep localized corrosion. The nickel electroplating before the aluminizing forms thick hafnium free area, and its high temperature oxidation resistance were comparable to platinum modified aluminizing coatings at 1273K.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.2
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• pp.203-208
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• 2016

In this study, to clarify the differences rebar corrosion beginning, through the actual corrosion accelerated test in corrosion time and laboratory test chamber of the structure of the marine environment results in both environments, it is an object of correlation coefficient derived. The accelerated corrosion test was carried out by two case, I.e., one is $20^{\circ}C$ of low temperaure codition(case 1), and the other is $65^{\circ}C$ of high temperaute codition(case 2). Whether corroions occurs, it was measures using half-cell potential method. The results indicated that case 2 is to acclerate the corrosion of rebar about 1.7~1.8 times as compared with case 1, thenthe corrosion of rebar embadded in concrete occurred according to the order of OPC60, FA, BS, OPC35. Correlation coefficient between acclerated corrosion test and long-term exposure test, case 1 is 2.45 to 2.94, and case 2 is 4.37~4.99.

• Proceedings of the KWS Conference
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• 2003.05a
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• pp.257-259
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• 2003

Sulfide Stress Corrosion Cracking(SSCC) of welded Steel pipe has been investigated. A specimens are stressed into the synthetic sea water saturated with H$_2$S. Therefore SSCC occur at the hardnest point. we are discusses the test methods used for laboratory corrosion testing of welded steel pipe and the results of test.