• Journal of Surface Science and Engineering
• /
• v.49 no.6
• /
• pp.498-506
• /
• 2016

Electrochemical measurement using a LSCF6428 electrode was performed to estimate the oxygen potential gradient in the electrode layer and a long time stability test was performed by applied potential to learn the overpotential effect on the LSCF6428 electrode. By fitting the observed impedance spectra, it was obtained that the amount of faradic current decreased with distance from cathode/electrolyte interface. Oxygen potential gradient was estimated to occur within 1 um region from the cathode/electrolyte interface at an oxygen partial pressure of 10-1 bar. The segregation of cation rich phases in the LSCF6428 electrode suggests that kinetic decomposition took place. However, impedance response after applying the potential showed no changes in the electrode compared with before applying potential. The obtained results suggest that segregation of a secondary phase in a LSCF6428 cathode is not related to performance degradation for solid oxide fuel cells (SOFCs).

• Journal of the Korean Ceramic Society
• /
• v.56 no.5
• /
• pp.497-505
• /
• 2019

Lanthanum-based transition metal cations containing perovskites have emerged as potential catalysts for the intermediate-temperature (600-800℃) oxygen reduction reaction (ORR). Here, we report a facile acetylacetone-assisted combustion route for the synthesis of nanostructured La_0.6Sr_0.4Co_0.2Fe_0.8O_3-δ (LSCF6428) cathodes for intermediate-temperature solid-oxide fuel cells (IT-SOFCs). The as-prepared powder was analyzed by thermogravimetry analysis-differential scanning calorimetry. The powder calcined at 800℃ was characterized by X-ray diffraction, scanning electrode microscopy, energy dispersive X-ray spectroscopy, and Brunauer-Emmett-Teller surface area measurements. It was found that the porosity of the air electrode significantly increased by utilizing the nanostructured LSCF6428 instead of commercial powder. The performance of a single cell fabricated with the nanostructured LSCF6428 cathode increased by 112%, from 0.4 to 0.85 W cm^-2, at 700℃. Electrochemical impedance spectroscopy showed a considerable reduction in the area-specific resistance and activation energy from 133.5 to 61.5 kJ/mol, resulting in enhanced electrocatalytic activity toward ORR and overall cell performance.

• Journal of Hydrogen and New Energy
• /
• v.35 no.1
• /
• pp.48-55
• /
• 2024

The electrochemically active site of mixed ionic and electronic conductor (MIEC) as a cathode material is restricted to the triple phase boundary in protonic ceramic fuel cells (PCFCs) due to the insufficient of proton-conducting properties of MIEC. This study primarily focused on expanding the electrochemically active site by La_0.6Sr_0.4Co_0.2Fe_0.8O_3-δ(LSCF6428)-BaZr_0.4Ce_0.4Y_0.1Yb_0.1O_3-δ (BZCYYb4411) composite cathode. The electrochemical properties of the composite cathode were evaluated using anode-supported PCFC single cells. In comparison to the LSCF6428 cathode, the peak power density of the LSCF6428-BZCYYb4411 composite cathode is much enhanced by the reduction in both ohmic and non-ohmic resistance, possibly due to the increased electrochemically active site.