• 한국가스학회:학술대회논문집
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• 1999.09a
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• pp.61-68
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• 1999

• Journal of Energy Engineering
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• v.23 no.3
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• pp.88-95
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• 2014

In general, odorants are added to fuel gases, such as LPG, LNG and city gas, to prevent gas poisoning, ignition, explosion, or other accident caused by fuel gases, and to enable immediate and easy detection of fuel-gas leakage by emitting an offensive smell. This study describes a study on the performance and exhaust emissions (CO, THC, $CO_2$, $NO_x$, $SO_2$) characteristics of liquefied petroleum gas (LPG) engine using LPG fuel with new sulfur free odorant (K-Petro S-Free). New sulfur free odorant (40 mg/kg) was added to 2 type LPG fuels for summer, and winter and it was used in performance and exhaust emissions, compare to LPG fuel with sulfur containing odorant (EM, ethyl mercaptan). Engine performance using LPG with sulfur free odorant was similar to LPG with sulfur-containing odorant. Exhaust emissions (CO, THC, $CO_2$, $NO_x$) of LPG with sulfur free odorant were also similar characteristics, compare with sulfur containing odorant. Especially, $SO_2$ emission using LPG with K-Petro S-Free odorant was more reduced 83 % than LPG with sulfur containing odorant(EM) at 2000 rpm.

• Proceedings of the KIEE Conference
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• 2003.07c
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• pp.1475-1477
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• 2003

본 논문에서는 LNG/LPG 센서와 솔벤트 센서를 국산화한 결과를 보고한다. LNG/LPG 센서는 $SnO_{2-}\;WO_3$ 모물질에 Pd, Pt 촉매를 첨가하여 제작하였다. 센서를 $400^{\circ}C$ 이상에서 동작시키면 CO가 촉매층에서 거의 $CO_2$로 산화되어 감지막의 저항변화에 아무런 기여도 못하기 때문에 팔라듐 촉매 센서부와 백금촉매 센서부의 신호로부터 탄화수소와 CO를 구별할 수 있다. 또한 촉매층 위에 다공성 보호층를 형성하여 촉매층과 감지막을 보호함으로써 장기 안정성이 크게 향상 되었다. 한편, 감지물질로 $BaSnO_3$를 사용해 제작된 솔벤트 센서는 에탄올에 매우 우수한 감도와 선택성을 나타내었다.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 1997.11a
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• pp.260-268
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• 1997

The safety of LPG vessel storage has been simply designed and controled with blast wave barrier structure concept regardless of its quantity or hazardous situation. The limit of regal controls on LPG vessel storage need to be identified in terms of safety buffer distance from LPG explosion. The level of overpressure effect and heat radiation In the safety structure and neighbouring human activity required to be estimated to find the gap between existing controls on such storage. To this content the paper discuss the issues on the approach In the blast wave barrier and safety separation distances.

• Journal of Korean Institute of Fire Investigation
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• v.11 no.1
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• pp.1-8
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• 2008

The purpose of this paper is to report gas fire accident based on classification of the major gas fire causes (including handling mistakes, inferior goods, etc.), fire classifications (fire, explosion, leakages, etc.), damage levels(1st, 2nd, 3rd, 4th grade levels), casualties (death, serious wound, slight injury) since gas fire has been generated according to growth of gaseous fuel consumption on home and enterprises with various accident causes. Among gaseous fuels, LPG facility can be c1assified as gas container, pressure regulator, gas hose, interim valve, combustion port. Any fire or any explosion can be caused from handling mistakes, inferior goods on each parts as stated above. Exact gas fire causes shall be identified based on previous case studies on similar fires with consideration of lesson learns.

• Journal of the Korean Institute of Gas
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• v.7 no.2 s.19
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• pp.33-41
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• 2003

There exists high hazard when transporting LPG as well as using, storing, and producing. For small scale LPG consumer, retailers deliver LPG to customers via a truck loading many LPG cylinders. Suppose there occurred a accident during LPG cylinder transfer, this could result in serious damages to the life and properties in the near or neighbor of the accident spot. In this regard, we made a quantitative risk analysis to estimate the possible damages and the probability through the identification of accidents causes and the simulation of the possible scenario. In this study, we made the Excel & Visual Basic computer program to perform quantitative LPG accident analysis. The simulation showed the following results. In case of UVCE(Unconfined Vapor Cloud Explosion), the effect within l0m of the accident spot showed very severe structural damages and even the accident can break the window glasses of the area of 150 m apart from accident spot. In case of TNT corresponding probit analysis, after 10 minutes LPG leaking, $75\%$ window glasses of 40 m distance was expected to be broken. And $16\%$ frames of 20m distance, $10\%$ frames of 40m distance was expected to be collapsed.

• Journal of the Korean Institute of Gas
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• v.18 no.5
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• pp.52-59
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• 2014

In general, sulfur containing odorants are added to fuel gases, such as LPG, and city gas, to prevent gas poisoning, ignition, explosion, or other accident caused by fuel gases, and to enable immediate and easy detection of fuel-gas leakage by emitting an offensive smell. In this study, sulfur free odorant for low sulfur fuel and prevention of metal corrosion were developed to replace current sulfur containing odorant for gas fuel. They were selected from 12 odorant containing non-sulfur organic compounds and evaluated by odor olfactory method (odor quality, odor intensity). Finally, selected mixture odorants were methyl isovalerate, methyl acrylate, 2-ethyl-3-methyl pyrazine with blending ratio of 50% : 40% : 10%. Final Sulfur free odorant was added 40 wt ppm in LPG fuels and evaluated fuel quality characteristics, metal corrosion test and long term stability of LPG fuel. It were limit in current LPG fuel standard in fuel quality characteristics. Final Sulfur free odorant also had no influence on metal corrosion and long term stability test with 60 days by adding in LPG fuels. Finally, they were shown to be warning agent candidates to reduce sulfur content and metal corrosion for LPG fuel.

• Journal of the Korean Institute of Gas
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• v.13 no.3
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• pp.54-60
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• 2009

The advancement of industry have increased domestic energy demands and energy facilities such as storage facility, compressed gas pipe, station, and tank lorry. Also, concern about environment have diversified energy source to clean energy such as LNG. In these major energy facilities, major accident can happen to result in fire, explosion, toxic release and etc. In addition, it may cause chain accidents to the adjacent energy facilities. In this research, safety assessment was performed through the consequence analysis of LPG liquefied petroleum gas) station, gasoline station and LNG(liquiefied natural gas) station. The obtained result will be helpful to make a safety guideline of the LPG/LNG station built adjacent to the gasoline station.

• Journal of the Korean Institute of Gas
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• v.12 no.3
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• pp.56-63
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• 2008

We have garnered 3,593 data of gas [Natural Gas (NG) and Liquefied Petroleum Gas (LPG)] accidents reported for 16 years from 1991, and then analyzed the accidents according to their types and causes based on the classified database. According to the results the gas leak has been the most common accident followed by the explosion and then fire accidents. The most frequent accident-occurring locations for fire, explosion and leak are recognized around the valve, hose and pipeline, respectively. In addition, we have applied the Poisson analysis to predict the most-likely probabilities of fire, explosion and release in the upcoming 5 years. From this research we have assured the successive database updating will highly improve the anticipating-probability accuracy and thus it will play a key role as a significant safety-securing guideline against the gas disasters.

• Journal of the Korea Safety Management & Science
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• v.14 no.1
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• pp.65-73
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• 2012

We studied the risk analysis of fire and explosion caused by gas leak in underground-parking of gas vehicle. However, an entrance regulation of gas vehicles (H2/LPG/CNG etc.) to underground garages has not been enacted in Korea. Incase, a gas explodes in an underground parking garage placed in overcrowded residential area, such as an apartment, the scale of the damage would cause tremendous disaster. Faults of vehicle parts and management problems were evaluated by using the Failure mode and effect analysis (FMEA), which is a qualitative analysis method. The range of the damaged area by the explosion and the damage scale by the explosion pressure were analyzed by using the process hazard analysis software tool (PHAST). The study is expected to facilitate enactment of the regulation for the underground parking to restrict the gas vehicle.