• 제목/요약/키워드: LN

검색결과 1,261건 처리시간 0.033초

초 냉각 가공에서의 LN2 의 감찰 효과 연구 -공구 마모에 의한 마찰 계수 이론적 전개- (Investigation of LN2 Lubrication Effect in Cryogenic Machining -Part 2: Friction Coefficient related to Tool Wear with Mathematical Evaluation-)

  • Seong-Chan, Jun;Woo-Cheol Jeong
    • 대한안전경영과학회:학술대회논문집
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    • 대한안전경영과학회 2002년도 춘계학술대회
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    • pp.215-219
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    • 2002
  • In this paper some physical evidences indicate that reduced friction occurs in an cryogenic machining process, in which LN2 is applied to the selected cutting zone. LN2 also reduced the tool wear rate to a great extent and elongated the tool life up to four times compared to emulsion cooling.

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BaPr$_{0.8}Ln_{0.2}O_{3-{\deta}}$($Ln=Yb^{3+}$, $Dy^{3+}$, $Gd^{3+}$, $Sm^{3+}$, $Nd^{3+}$)계 perovskite 산화물의 생성상, 전기전도도 및 수송율 (Phase Analysis, Electrical Conductivity and Transport Number of $BaPr_{0.8}Ln_{0.2}O_{3-{\deta}}$($Ln=Yb^{3+}$, $Dy^{3+}$, $Gd^{3+}$, $Sm^{3+}$, $Nd^{3+}$) perovskite oxides)

  • 박형경;최순목;김신;이홍림
    • 한국세라믹학회:학술대회논문집
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    • 한국세라믹학회 2000년도 추계총회,초청강연,특별강연,연구발표회
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    • pp.102.1-102
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    • 2000
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Luminescent Lanthanide Complexes for Advanced Photonics Applications

  • Eom, Yu Kyung;Ryu, Jung Ho;Kim, Hwan Kyu
    • Rapid Communication in Photoscience
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    • 제1권1호
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    • pp.1-9
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    • 2012
  • Luminescent lanthanide complexes have been overviewed for advanced photonics applications. Lanthanide(III) ions ($Ln^{3+}$) were encapsulated by the luminescent ligands such as metalloporphyrins, naphthalenes, anthracene, push-pull diketone derivatives and boron dipyrromethene(bodipy). The energy levels of the luminescent ligands were tailored to maintain the effective energy transfer process from luminescent ligands to $Ln^{3+}$ ions for getting a higher optical amplification gain. Also, key parameters for emission enhancement and efficient energy transfer pathways for the sensitization of $Ln^{3+}$ ions by luminescent ligands were investigated. Furthermore, to enhance the optophysical properties of novel luminescent $Ln^{3+}$ complexes, aryl ether-functionalized dendrons as photon antennas have been incorporated into luminescent $Ln^{3+}$ complexes, yielding novel $Ln^{3+}$-cored dendrimer complex such as metalloporphyrins, naphthalenes, and anthracenes bearing the Fr$\acute{e}$chet aryl-ether dendrons, namely, ($Er^{3+}-[Gn-Pt-Por]_3$ (terpy), $Er^{3+}-[Gn-Naph]_3$(terpy) and $Er^{3+}-[Gn-An]_3$(terpy)). These complexs showed much stronger near-IR emission bands at 1530 nm, originated from the 4f-4f electronic transition of the first excited state ($^4I_{13/2}$) to the ground state ($^4I_{15/2}$) of the partially filled 4f shell. A significant decrease in the fluorescence of metalloporphyrins, naphthalenes and anthracene ligand were accompanied by a strong increase in the near IR emission of the $Ln^{3+}$ ions. The near IR emission intensities of $Ln^{3+}$ ions in the lanthanide(III)-encapsulated dendrimer complexes were dramatically enhanced with increasing the generation number (n) of dendrons, due to the site-isolation and the light-harvesting(LH) effects. Furthermore, it was first attempted to distinguish between the site-isolation and the light-harvesting effects in the present complexes. In this review, synthesis and photophysical studies of inert and stable luminescent $Ln^{3+}$ complexes will be dealt for the advanced photonics applications. Also, the review will include the exploratory investigation of the key parameters for emission enhancement and the effective energy transfer pathways from luminescent ligands to $Ln^{3+}$ ions with $Ln^{3+}$-chelated prototype complexes.

란탄족 원소의 전기화학적 환원에 관한 연구 (제 1 보) (Electrochemical Studies on the Lanthanides)

  • 박종민;강삼우;도이미;한양수;손병찬
    • 대한화학회지
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    • 제34권6호
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    • pp.561-568
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    • 1990
  • 수용액에서 가벼운 란탄족 금속이온의 전기화학적 거동을 직류 폴라로그래피, 펄스차이 폴라로그래피 및 순환 전압전류법으로 연구하였다. La$^{3+}$, Pr$^{3+}$ 및 Nd$^{3+}$의 환원은 0.1 M LiCl 지지전해질에서 3전자가 관여하는 비가역적인 반응이었다. Sm$^{3+}$의 환원은 0.1 M TMAI 지지전해질에서 1전자에 이어 2전자가 관여하는 비가역적인 반응이었으며, Eu$^{3+}$의 환원은 0.1 M LiCl 지지전해질에서 1전자에 이어 2전자가 관여하는 유사가역반응 및 비가역반응이었다. 펄스차이 폴라로그래피에 의하면 pH 4 이하에서는 수소이온의 촉매효과에 의하여 가수분해된 란탄족 금속이온 (Ln(OH)$^{2+}$)은 란탄족 금속이온(Ln$^{3+}$)보다 양전위에서 환원되었으며, 봉우리 전류의 크기는 Eu$^{3+}$ < Sm$^{3+}$ < Nd$^{3+}$ < Pr$^{3+}$ < La$^{3+}$ 순으로 증가하였다. 순환 전압전류법에서 주사속도 변화에 대한 전류함수의 크기는 [H$^{+}$]/[Ln$^{3+}$]의 비에 의존하였으며, pH 및 란탄족 금속이온의 농도가 낮을수록 수소이온에 의한 반응 또는 촉매전류가 증가하였다.

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녹용약침과 웅담.우황(BU)약침이 정상인의 심박변이도(HRV)에 미치는 영향 (The Effects of Cervi Pantotrichum Cornu Pharmacopuncture and Bovis calculus.Fel Ursi Pharmacopuncture on the Heart Rate Variability)

  • 이휘용;이진복;조이현;송범용;육태한
    • Journal of Acupuncture Research
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    • 제27권1호
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    • pp.65-74
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    • 2010
  • Objectives : This study was to investigate the effects of Cervi Pantotrichum Cornu Pharmacopuncture and Bovis calculus Fel Ursi Pharmacopuncture on autonomic nervous system with Heart Rate Variability(HRV). Purpose of the trial was to observe what influence Cervi Pantotrichum Cornu Pharmacopuncture and Bovis calculus Fel Ursi pharmacopuncture have on the autonomic nervous system. Methods : 40 healthy male volunteers were divided into two experimental groups, such as Cervi Pantotrichum Cornu Pharmacopuncture group and Bovis calculus Fel Ursi Pharmacopuncture group. Study design was a randomized, double-blind clinical trial. 20 subjects in one experimental group were injected Cervi Pantotrichum Cornu Pharmacopuncture, 20 subjects in other experimental group were injected hydrolyzed Bovis calculus Fel Ursi Pharmacopuncture at GB21(Kyonjong). We measured HRV 7 times : baseline measurement and every 5 minutes for 30 minutes after injection. The SPSS 15.0 for Windows was used to analyze the data by the paired t-test(in group) and independent sample t-test(between the groups). Results A. Time Domain Analysis 1. Analysis of Mean HRV, SDNN and Complexity After injection of Cervi Pantotrichum Cornu Pharmacopuncture, Mean HRV was significantly decreased all the times after injection. SDNN was significantly increased at immediate and 25 minute after injection. Complexity was significantly decreased only at 15 minute after injection. After injection of Bovis calculus Fel Ursi Pharmacopuncture, Mean HRV was significantly decreased all the times after injection. Complexity was significantly decreased at 15 minutes after injection. 2. Analysis of HRV index, pNN50 After injection of Cervi Pantotrichum Cornu Pharmacopuncture, HRV index was significantly increased immediately after injection. pNN50 was significantly decreased at immediately, 20 and 25 minutes after injection. After injection of Bovis calculus Fel Ursi Pharmacopuncture, HRV index was significantly increased immediately after injection. pNN50 was significantly decreased at immediate and 25 minutes after injection. B. Frequency Domain Analysis 1. Analysis of Ln(TP), Ln(HF), Ln(LF), Ln(VLF) After injection of Cervi Pantotrichum Cornu Pharmacopuncture, Ln(TP) was significantly increased at immediate and 25 after injection. Ln(HF) was significantly increased all the times after injection. Ln(LF) was significantly increased at 15, 20 and 25 minutes after injection. Ln(VLF) was significantly increased at immediate and 25 minutes after injection. After injection of Bovis calculus Fel Ursi Pharmacopuncture, Ln(TP) was significantly increased at immediately and 25 after injection. Ln(LF) was significantly increased at 20 and 25 minutes after injection. Ln(VLF) was significantly increased at immediate and 25 minutes after injection. Conclusions : We results suggest that Cervi Pantotrichum Cornu Pharmacopuncture and Bovis calculus Fel Ursi Pharmacopuncture in healthy adult men tend to activate the autonomic nervous system and sympathetic nervous system within normal range.

자침수기가 뇌파에 미치는 영향 (The Effect of Manual Acupuncture on the Waves of the Electroencephalogram)

  • 선종인;이승덕;한승무;박미주;강중원;남동우;윤가영;최도영;이재동
    • Journal of Acupuncture Research
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    • 제28권2호
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    • pp.27-41
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    • 2011
  • Objectives : The aim of this study was to examine the effect of manual acupuncture at the bilateral $LI_4$, $ST_{36}$ and $LR_3$ on normal human every 3 minute time interval by using power spectrum analysis. Methods : 25 healthy volunteers participated in this study. 32 channel EEG(Electroencephalogram) measurements were carried out before, during and after acupuncture treatments. In this study, power spectrum was used as a measure of complexity. Statistical analysis was performed using repeated measure ANOVA and Bonferroni method. Results : 1. In acupuncture group, Mean HRT, PSI, Normalized HF decreased significantly. SDNN, Ln(TP), Ln(LF), Ln(VLF), Normalized LF and LF/HF ratio increased significantly. RMSSD, Ln(HF) were not affected. 2. In sham acupuncture group, all indicators were not affected. 3. In control group, mean HRT, Ln(TP) decreased significantly. SDNN, RMSSD, PSI, Ln(LF), Ln(HF), Ln(VLF), normalized LF, normalized HF and LF/HF ratio were not affected. Conclusions : This results suggest that manipulation needling of 6 acupoints induced increase of delta, theta, beta waves. Both manipulation and simple needling induced decrease of alpha wave during 12~15 time intervals.

PE/$LN_2O$ 하이브리드 로켓 모터의 연소특성에 관한 연구 (A Study on the Combustion Characteristic in Hybrid Rocket Motor using PE/$LN_2O$)

  • 김기훈;이정표;김수종;조정태;김학철;우경진;성홍계;문희장;김진곤
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2009년도 춘계학술대회 논문집
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    • pp.233-236
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    • 2009
  • 산화제는 $LN_2O$, 고체연료는 HDPE(High Density PolyEthlene)를 사용하여 산화제의 상 및 연료포트 직경에 따른 하이브리드 로켓 모터의 연소특성을 비교 분석하였다. 불완전한 액적의 기화와 연료와 산화제의 혼합으로 인해 산화제로 $GN_2O$ 보다 $LN_2O$를 적용했을 때, 연소효율이 낮게 나타났다. O/F비에 따른 화염온도변화 및 끝 단면적에서의 연소반응으로 인해 $LN_2O$$GN_2O$를 사용하였을 경우 고체연료의 초기 포트 직경에 따른 후퇴율의 경향이 달리 나타났다.

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316LN 및 Cr-Mo 스테인리스강의 Monkman-Grant 파라메타 평가 (Estimation of Monkman-Grant Parameter for Type 316LN and Cr-Mo Stainless Steels)

  • 김우곤;김성호;이경용;류우석
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집A
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    • pp.223-230
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    • 2001
  • The Monkman-Grant (M-G) and its modified parameters were estimated for modified type 316LN and $9{\sim}12Cr-1Mo$ steels with chemical variations. Several sets of creep data were obtained by constant-load creep tests in $550-650^{\circ}C$ ranges. The relation parameters, m, $m^*$, C and $C^*$ were proposed and discussed for two alloy systems. In creep fracture mode, type 316LN steel showed domination of the intergranular fracture caused by growth and coalescence of cavities. On the other hand, the Cr-Mo steel showed transgranular fracture of the ductile type caused from softening at high temperature. In spite of the basic differences in creep fracture modes as well as creep properties, the M-G and its modified relations demonstrated linearity within the $2{\sigma}$ standard deviation. The value of the m parameter of the M-G relation was 0.90 in the 316LN steel and 0.84 in the Cr-Mo steel. The value of the $m^*$ parameter of the modified relation was 0.94 in the 316LN steel and 0.89 in Cr-Mo steel. The modified relation was superior to the M-G relation because the $m^*$ slopes almost overlapped regardless of creep testing conditions and chemical variations to the two alloy systems.

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