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Stabilization of LiMn2O4 Electrode for Lithium Secondary Battery(I) - Electrode Characteristics on the Substitution of Metal Oxides in LiMn2O4 Cathode Material - (리튬이차전지용 정극활물질 LiMn2O4의 안정화(I) - LiMn2O4에 대한 금속산화물의 치환에 따른 전극 특성 -)

  • Lee, Jin-Sik;Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.774-780
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    • 1998
  • For the stabilization of the spinel structured $LiMn_2O_4$, a fraction of manganese was substituted with various metals such as Mg, Fe, V, W, Cr, Mo with Mn that had a similar ionic radii ($LiM_xMn_{2-x}O_4(0.05{\leq}x{\leq}0.02)$). The $LiM_xMn_{2-x}O_4$ showed a substantial improvement as lower capacity loss than that of the spinel structured $LiMn_2O_4$ when it was used as a cathode material. And with the partial substitution, the chemical diffusion coefficient for $LiMg_{0.05}Mn_{1.9}O_4$ and $LiCr_{0.1}Mn_{1.9}O_4$ was increased by and order of magnitude compared to that of the $LiMn_2O_4$ with spinel structure. The results showed that significant improvement can be made on the electrochemical characteristics as the structure of the $LiMn_2O_4$ electrode material was stabilized by the partial substitution.

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A Research on Autonomous Mobile LiDAR Performance between Lab and Field Environment (자율주행차량 모바일 LiDAR의 실내외 성능 비교 연구)

  • Ji yoon Kim;Bum jin Park;Jisoo Kim
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.22 no.4
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    • pp.194-210
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    • 2023
  • LiDAR plays a key role in autonomous vehicles, where it is used to detect the environment in place of the driver's eyes, and its role is expanding. In recent years, there has been a growing need to test the performance of LiDARs installed in autonomous vehicles. Many LiDAR performance tests have been conducted in simulated and indoor(lab) environments, but the number of tests in outdoor(field) and real-world road environments has been minimal. In this study, we compared LiDAR performance under the same conditions lab and field to determine the relationship between lab and field tests and to establish the characteristics and roles of each test environment. The experimental results showed that LiDAR detection performance varies depending on the lighting environment (direct sunlight, led) and the detected object. In particular, the effect of decreasing intensity due to increasing distance and rainfall is greater outdoors, suggesting that both lab and field experiments are necessary when testing LiDAR detection performance on objects. The results of this study are expected to be useful for organizations conducting research on the use of LiDAR sensors and facilities for LiDAR sensors.

Determination of Li generated from 10B(n·α)7Li reaction in Boric acid solution (붕산수용액에서 10B(n·α)7Li 핵반응에 의해 생성된 Li 정량)

  • Choi, Ke-Chon;Jung, Yongju;Yoon, Jei-Won;Kim, Won-Ho
    • Analytical Science and Technology
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    • v.16 no.6
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    • pp.443-449
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    • 2003
  • Thermal neutron irradiation experiment of boric acid solution was carried out using HANARO in following three conditions: (A) $^{10}B$ concentration = $203.0{\mu}g/mL$, irradiation time = 1 hr; (B) $^{10}B$ concentration = $381.4{\mu}g/mL$, irradiation time = 1 hr; (C) $^{10}B$ concentration = $381.4{\mu}g/mL$, irradiation time = 0.5 hr. The amount of lithium produced from $^{10}B(n{\cdot}{\alpha})^7Li$ reaction which was generated on neutron irradiation, was measured by flameless atomic absorption spectroscopy. The concentration of $^7Li$ measured in the three experiments was $0.18{\mu}g/mL$ (78.3% of theoretical value, $0.23{\mu}g/mL$) in (A), $0.31{\mu}g/mL$ (70.5% of theoretical value, $0.44{\mu}g/mL$) in (B) and $0.16{\mu}g/mL$ (71.6% of theoretical value, $0.22{\mu}g/mL$) in (C). The pH value of irradiated boric acid was shifted to considerably low. It is estimated that boric acid would be transformed into the polyborate fonn, by radiolysis products of water, which has high dissociation constant.

Implementation and Evaluation of a Robot Operating System-based Virtual Lidar Driver (로봇운영체제 기반의 가상 라이다 드라이버 구현 및 평가)

  • Hwang, Inho;Kim, Kanghee
    • KIISE Transactions on Computing Practices
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    • v.23 no.10
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    • pp.588-593
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    • 2017
  • In this paper, we propose a LiDAR driver that virtualizes multiple inexpensive LiDARs (Light Detection and Ranging) with a smaller number of scan channels on an autonomous vehicle to replace a single expensive LiDAR with a larger number of scan channels. As a result, existing SLAM (Simultaneous Localization And Mapping) algorithms can be used with no modifications developed assuming a single LiDAR. In the paper, the proposed driver was implemented on the Robot Operating System and was evaluated with an existing SLAM algorithm. The results show that the proposed driver, combined with a filter to control the density of points in a 3D map, is compatible with the existing algorithm.

Taxonomic Review of the Psocids (Psocoptera) in Korea (한국산 다듬이벌레목의 분류학적 정리)

  • Soysouvanh, Pheophanh;Cho, Geonho;Hong, Ki-Jeong
    • Korean journal of applied entomology
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    • v.56 no.1
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    • pp.69-76
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    • 2017
  • The psocids of Korea are reviewed based on museum collections and recently collected material. To date, only 14 species of 7 families in 3 suborders (Trogiomorpha, Troctomorpha and Psocomorpha) of Psocoptera have been recorded. In the present study, 10 additional species belonging to 2 suborders [Troctomorpha] Amphientomidae: Ancylentomus macrourus (Li, 1997); [Psocomorpha] Amphipsocidae: Amphipsocus japonicus (Enderlein, 1906), Caeciliusidae: Valenzuela oyamai (Enderlein, 1906), Paracaecilius japonicus (Enderlein, 1906), Stenopsocidae: Cubipilis aphidiformis (Enderlein, 1906), Stenopsocus immaculatus (Stephens, 1836), Peripsocidae: Peripsocus didymus Roesler, 1939, Psocidae: Amphigerontia anchorae Li, 2002, Psococerastis tokyoensis (Enderlein, 1906) and Trichadenopsocus alternatus Li, 2002, were found to occur in Korea for the first time. Adult morphology, taxonomic diagnosis and photographs of diagnostic characters of the newly recorded species in Korea are provided.

The Research and Development Trend of Cathode Materials in Lithium Ion Battery (리튬이차전지용 양극재 개발 동향)

  • Park, Hong-Kyu
    • Journal of the Korean Electrochemical Society
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    • v.11 no.3
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    • pp.197-210
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    • 2008
  • The cathode materials for lithium ion battery have been developed in accordance with the battery performance. $LiCoO_2$ initially adapted at lithium ion battery is going to be useful even at the charging voltage of 4.3 V by surface treatment or doping which drastically improved the performance of $LiCoO_2$. On the other hand, the complicate and multiple functions of recent electronic equipments required higher operational voltage and higher capacity than ever, which is going to be driving force for developing new cathode materials. Some of them are $LiNi_{1-x}{M_xO_2}$, $Li[Ni_{x}Mn_{y}Co_{z}]O_{2}$, $Li[{Ni}_{1/2}{Mn}_{1/2}]O_{2}$. Other new type of cathode materials having high safety is also developed to apply for HEV (hybrid electrical vehicle) and power tool applications. ${LiMn}_{2}{O}_{4}$ and $LiFePO_4$ are famous for highly stable material, which are expected to give contribution to make safer battery. In near future, the various materials having both capacity and safety will be developed by new technology, such as solid solution composite.

Effect of a Li2O Additive on the Sintering Behavior of UO2 in the H2 and CO2 Atmospheres

  • Kim, Si-Hyung;Joung, Chang-Young;Kim, Yeon-Gu;Lee, Soo-Chul;Kim, Ban-Soo;Na, Sang-Ho;Lee, Young-Woo;Suhr, Dong-Soo
    • Journal of the Korean Ceramic Society
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    • v.41 no.8
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    • pp.567-572
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    • 2004
  • The variation of the sintered density and grain size of UO$_2$ as a function of the Li$_2$O amount and sintering atmosphere was observed. Li$_2$O enhanced the grain growth of the UO$_2$ pellet in H$_2$, but rather hindered it in $CO_2$ atmosphere. Grain size of the UO$_2$ and UO$_2$-0.1 wt%Li$_2$O pellets was, respectively, 8 $\mu$m and 100 $\mu$m at 168$0^{\circ}C$ in the H$_2$ atmosphere, and that of each pellet was, respectively, 24 $\mu$m and 17 $\mu$m at the same temperature in the $CO_2$ atmosphere. As-received Li$_2$O powder, which had been composed of Li$_2$O and LiOH, was converted to the Li$_2$CO$_3$ phase after heating to 80$0^{\circ}C$ in $CO_2$. On the other hand, the Li$_2$O and LiOH phases remained unchanged in H$_2$ atmosphere. In the H$_2$, the as-received Li$_2$O powder began to evaporate at about 105$0^{\circ}C$ and then about 20 wt% residue was left at 150$0^{\circ}C$. But, most of the Li elements evaporated at 150$0^{\circ}C$ in the $CO_2$ atmosphere.

Synthesis and Electrochemical Characteristics of Carbon added Li3V2(PO4)3 (탄소첨가한 Li3V2(PO4)3의 합성 및 전기화학적 특성)

  • Jo, Yeong-Im;Na, Byung-Ki
    • Journal of the Korean Electrochemical Society
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    • v.15 no.2
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    • pp.101-108
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    • 2012
  • The purpose of this study was to improve the conductivity of $Li_3V_2(PO_4){_3}$ by adding carbon source so that the discharge rate and cyclic properties were improved. Glucose and CNT were added to $Li_3V_2(PO_4){_3}$ and the structure and electrochemical properties were studied. $Li_3V_2(PO_4){_3}$, $Li_3V_2(PO_4){_3}$/C and $Li_3V_2(PO_4){_3}$/CNT were synthesised by solid state reaction using hydrogen reduction method at 600, 700, 800, $900^{\circ}C$. The cathode materials were assembled to coin cell type 2032 with Lithium metal as a counter electrode. The coin cell was galvanostatically evaluated in the voltage range of 3.0~4.8 V.

Emission Characteristics of OLEDs Using LiF/Al/LiF Structure (LiF/Al/LiF 구조를 적용한 OLED 소자의 발광 특성)

  • Park, Yeon-Suk;Yang, Jae-Woong;Ju, Sung-Hoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.9
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    • pp.696-700
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    • 2010
  • We fabricated red and blue organic light emitting display (OLEDs) which had the two kinds of multi-structure of ITO/HIL/HTL/EML/ETL/LiF/Al and ITO/HIL/HTL/EML/ETL/LiF/Al/LiF. In the case of red OLED that had LiF/Al/LiF structure compared to LiF/Al structure, the current density increased from 4.3 mA/$cm^2$ to 7.3 mA/$cm^2$, and the brightness increased from 488 cd/$m^2$ to 1,023 cd/$m^2$ at 7.0 V, and as a result the current efficiency was improved from 11.28 cd/A to 13.95 cd/A. Also in the case of blue OLED that had LiF on Al cathode layer, the current density increased from 1.2 mA/$cm^2$ to 1.8 mA/$cm^2$, and the brightness increased from 45 cd/$m^2$ to 85 cd/$m^2$ at 7.0 V, and as a result the current efficiency was improved from 3.69 cd/A to 4.82 cd/A. Through these experimental results it could be suggested that the LiF layer formed on Al prevents the oxidation of Al surface, and the electrode resistance become low with increase of supplied electrons, therefore the brightness and the efficiency are improved from the influence to the well-balanced bonding of electron and hole at emitting layer.

Comparative Accuracy of Terrestrial LiDAR and Unmanned Aerial Vehicles for 3D Modeling of Cultural Properties (문화재 3차원 모델링을 위한 지상 LiDAR와 UAV 정확도 비교 연구)

  • Lee, Ho-Jin;Cho, Gi-Sung
    • Journal of Cadastre & Land InformatiX
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    • v.47 no.1
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    • pp.179-190
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    • 2017
  • A terrestrial LiDAR survey was conducted and unmanned aerial vehicle(UAV) images were taken for target cultural properties to present the utilization measures of terrestrial LiDAR and UAV in three-dimensional modeling of cultural properties for the identification of the status and restoration of cultural properties. Then the accuracy of the point clouds generated through this process was compared, an overlap analysis of the 3D model was conducted, and a convergence model was created. According to the results, the modeling with terrestrial LiDAR is more appropriate for precise survey because 3D modeling for the detection of displacement and deformation of cultural properties requires an accuracy of mm units. And UAV model has limitation as the impossibility of detailed expression of parts with sharp unevenness such as cracks of bricks. However, it is found that the UAV model has a wide range of modeling and has the advantage of modeling of real cultural properties. Finally, the convergence model created in this study using the advantages of the terrestrial LiDAR model and the UAV model could be efficiently utilized for the basic data development of cultural properties.