• Title/Summary/Keyword: LFL

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A flammability limit model for hydrogen-air-diluent mixtures based on heat transfer characteristics in flame propagation

  • Jeon, Joongoo;Choi, Wonjun;Kim, Sung Joong
    • Nuclear Engineering and Technology
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    • v.51 no.7
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    • pp.1749-1757
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    • 2019
  • Predicting lower flammability limits (LFL) of hydrogen has become an ever-important task for safety of nuclear industry. While numerous experimental studies have been conducted, LFL results applicable for the harsh environment are still lack of information. Our aim is to develop a calculated non-adiabatic flame temperature (CNAFT) model to better predict LFL of hydrogen mixtures in nuclear power plant. The developed model is unique for incorporating radiative heat loss during flame propagation using the CNAFT coefficient derived through previous studies of flame propagation. Our new model is more consistent with the experimental results for various mixtures compared to the previous model, which relied on calculated adiabatic flame temperature (CAFT) to predict the LFL without any consideration of heat loss. Limitation of the previous model could be explained clearly based on the CNAFT coefficient magnitude. The prediction accuracy for hydrogen mixtures at elevated initial temperatures and high helium content was improved substantially. The model reliability was confirmed for $H_2-air$ mixtures up to $300^{\circ}C$ and $H_2-air-He$ mixtures up to 50 vol % helium concentration. Therefore, the CNAFT model developed based on radiation heat loss is expected as the practical method for predicting LFL in hydrogen risk analysis.

Study on the Fire Safety Estimation for a Pilot LNG Storage Tank (PILOT LNG저장탱크의 화재안전성 평가에 관한 연구)

  • 고재선;김효
    • Fire Science and Engineering
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    • v.18 no.3
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    • pp.57-73
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    • 2004
  • Quantitative safety analysis through a fault tree method has been conducted for a fire broken out over the spilling LNG from a pilot LNG tank, which may have 4 types of scenarios causing potentially risky results. When we consider LNG release from venting pipelines as a first event, any specific radius of Low Flammable Limit(LFL) has not been built up. The second case of LNG outflow from the rupture of storage tank which will be the severest has been analyzed and the results revealed various diffusion areas to the leaking times even with the same amount of LNG release. As a third case LNG leakage from the inlet/outlet pipelines was taken into consider. The results showed no significant differences of LFL radii between the two spilling times of 10 and 60 minutes. Hence, we have known the most affecting factor on the third scenario is an initial amount of LNG release. Finally, the extent of LFL was calculated when LNG pipelines around the dike area were damaged. In addition, consequence analysis has been also performed to acquire the heat radiation and flame magnitude for each case.

Analysis of Parameters Affecting the Consequence of the Flash Fire Accident by the Release of Heavy Gas (무거운 가스의 누출에 의한 플래쉬화재사고에서 사고결과에 미치는 매개변수의 영향 분석)

  • Kim, Tae-Ok;Lee, Hern-Chang;Ham, Byeong-Ho;Cho, Ji-Hoon;Shin, Dong-Il;Jang, Seo-Il
    • Journal of the Korea Safety Management & Science
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    • v.8 no.6
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    • pp.29-39
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    • 2006
  • The effect of parameters on the consequence of the flash fire accident by the release of heavy gas(in this study, xylene vapor) was analyzed. Simulation results showed that the distance with the lower flammable limit($X_{LFL}$) was increased with the increase of the release hole diameter. For the case of the elevated release, $X_{LFL}$ was increased with the increase of the wind speed and the release height, but $X_{LFL}$ was not affected by the wind speed for the release on the ground level. Therefore, the accident in the elevated release was more dangerous than the release on the ground level. In this condition, the release height had more effect on $X_{LFL}$ at the night time than the daytime and in the urban area than the rural area.

Review on the Process Safety of $SiH_{4}$ Gas used in Semiconductor and FPD Field (반도체 및 FPD 분야에 사용되는 $SiH_{4}$ 가스의 공정 안전 고찰)

  • Kim, Joung-Cho;Kim, Hong
    • Journal of the Korean Society of Safety
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    • v.22 no.4
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    • pp.32-36
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    • 2007
  • When the vacuum system for the process of $SiH_{4}$ gas used in the semiconductor and FPD field is partially vented from vacuum to atmospheric state, a fire often occurs due to auto-ignition of $SiH_{4}$ gas. In order to prevent the fire, the concentration of $SiH_{4}$ should be kept under LFL. This means that the higher capacity pump is needed to meet the process conditions as well as the condition that the concentration of $SiH_{4}$ should be kept under LFL. In this article, we conducted the injection of the dilution gas at the manifold between booster pump and dry pump compared with the typical method that the dilution gas was injected into inlet port of booster pump using computer simulation. According to the result, we can flow further more purge gas for safety without any change of the condition in the process chamber, which means that the higher capacity pump is not required for safety in some cases.

A Study on Determination of Range of Hazardous Area Caused by the Secondary Grade of Release of Vapor Substances Considering Material Characteristic and Operating Condition (물질특성 및 운전조건을 고려한 증기상 물질의 2차 누출에 따른 폭발위험장소 범위 선정에 관한 연구)

  • Seo, Minsu;Kim, Kisug;Hwang, Yongwoo;Chon, Youngwoo
    • Journal of the Korean Institute of Gas
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    • v.22 no.4
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    • pp.13-26
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    • 2018
  • Currently, local regulations, such as KS Code, do not clearly specify how to calculate the range of hazardous area, so the dispersion modeling program should be used to select dispersion. The purpose of this study is to present a methodology of determining the range of hazardous area which is simpler and more reasonable than modelling by using representative materials and process conditions. Based on domestic and overseas regulations that are currently in effect, variables affecting distance to LFL(Lower Flammable Limit) were selected. A total of 16 flammable substances were modelled for substance variables, process conditions variables, and weather conditions variables, and the statistical analysis selected the variables that affect them. Using the selected variables, a three-step classification method was prepared to select the range of locations subject to explosion hazard.

The Hazard Assessment of Release and Dispersion of CNG Service Station (CNG 충전소의 누출$\cdot$확산에 대한 위험성 평가)

  • Choi Jong-Woon;Lee Su-Kyung
    • Journal of the Korean Institute of Gas
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    • v.4 no.3 s.11
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    • pp.53-58
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    • 2000
  • It was carried out consequence analysis(CA) of CNG (compressed natural gas) service station and we compared the results of CA of CNG service station with LPG service station which was installed by high Pressure gas law. The results of CA were that distance of CNG LFL was 1.5 times than the length of LPG LFL. Thermal radiation effect about CNG may not be showed damage of process facilities, but in the case of LPG, it was enough to have an large damage effect on a downtown. The thermal radiation of 37.5 $kw/m^2$ extended 12.6 m. Also, in the case of 12.5 $kw/m^2$ which was able to burn wood, the radiation effect of LPG is 3 times than CNG.

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Numerical Study on the Effect of Area Changes in Air Inlets and Vent Ports on the Ventilation of Leaking Hydrogen (급·배기구 면적 변화가 누출 수소 환기에 미치는 영향에 관한 수치해석적 연구)

  • Lee, Chang-Yong;Cho, Dae-Hwan
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.28 no.2
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    • pp.385-393
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    • 2022
  • Hydrogen has reduced greenhouse gas (GHG) emissions, the main cause of global warming, and is emerging as an eco-friendly energy source for ships. Hydrogen is a substance with a lower flammability limit (LFL) of 4 to 75% and a high risk of explosion. To be used for ships, it must be sufficiently safe against leaks. In this study, we analyzed the effect of changes in the area of the air inlet / vent port on the ventilation performance when hydrogen leaks occur in the hydrogen tank storage room. The area of the air inlet / vent port is 1A = 740 mm × 740 mm, and the size and position can be easily changed on the surface of the storage chamber. Using ANSYS CFX ver 18.1, which is a CFD commercial software, the area of the air inlet / vent port was changed to 1A, 2A, 3A, and 5A, and the hydrogen mole fraction in the storage chamber when the area changed was analyzed. Consequently, the increase in the area of the air inlet port further reduced the concentration of the leaked hydrogen as compared with that of the vent port, and improved the ventilation performance of at least 2A or more from the single air inlet port. As the area of the air inlet port increased, hydrogen was uniformly stratified at the upper part of the storage chamber, but was out of the LFL range. However, simply increasing the area of the vent port inadequately affected the ventilation performance.

The Consequence Analysis for Unconfined Vapor Cloud Explosion Accident by the Continuous Release of Butane Vapor in the Debutanizing Process of Naphtha Cracking Plant (나프타분해플랜트의 부탄추출공정에서 부탄증기의 연속누출에 의한 증기운 폭발사고의 영향평가)

  • 손민일;이헌창;장서일;김태옥
    • Journal of the Korea Safety Management & Science
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    • v.2 no.4
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    • pp.33-43
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    • 2000
  • The consequence analysis for the unconfined vapor cloud explosion(UVCE) accident by the continuous release of butane vapor was performed and effects of process parameters on consequences were analyzed in standard conditions. For the case of continuous release(87.8 kg/s) of butane vapor at 8 m elevated height in the debutanizing process of tile naphtha cracking plant operating at 877 kPa & 346.75 K, we found that combustion ranges of dispersed vapor estimated by HMP model were 11.2~120.2 m and overpressures estimated by TNT equivalency model at 200 m were about 37.35~55.1 kPa. Also, overpressures estimated by Model UVCE I based on advective travel time to $X_{LFL}$ were smaller than those estimated by Model UVCE IIbased on real travel time between $X_{UFL}$ and $X_{LFL}$. At the same time, damage intensities at 200 m and effect ranges by overpressure could be predicted. Furthermore, simulation results showed that effects of operating pressures on consequences were larger than those of operating temperatures and results of accidents were increased with increasing operating pressures. At this time, sensitivities of overpressures for UVCE accident by the continuous release were about 5 kPa/atm.

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Hybrid fuzzy model to predict strength and optimum compositions of natural Alumina-Silica-based geopolymers

  • Nadiri, Ata Allah;Asadi, Somayeh;Babaizadeh, Hamed;Naderi, Keivan
    • Computers and Concrete
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    • v.21 no.1
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    • pp.103-110
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    • 2018
  • This study introduces the supervised committee fuzzy model as a hybrid fuzzy model to predict compressive strength (CS) of geopolymers prepared from alumina-silica products. For this purpose, more than 50 experimental data that evaluated the effect of $Al_2O_3/SiO_2$, $Na_2O/Al_2O_3$, $Na_2O/H_2O$ and Na/[Na+K] on (CS) of geopolymers were collected from the literature. Then, three different Fuzzy Logic (FL) models (Sugeno fuzzy logic (SFL), Mamdani fuzzy logic (MFL), and Larsen fuzzy logic (LFL)) were adopted to overcome the inherent uncertainty of geochemical parameters and to predict CS. After validating the model, it was found that the SFL model is superior to MFL and LFL models, but each of the FL models has advantages to predict CS. Therefore, to achieve the optimal performance, the supervised committee fuzzy logic (SCFL) model was developed as a hybrid method to combine the benefits of individual FL models. The SCFL employs an artificial neural network (ANN) model to re-predict the CS of three FL model predictions. The results also show significant fitting improvement in comparison with individual FL models.

A Study on the Determination of Optimal Lot Size in Distribution System (물류시스템에서의 최적 로트크기 결정원칙에 관한 연구)

  • 김상직;김영식;김영겸
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.18 no.35
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    • pp.39-46
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    • 1995
  • This study is to find the optimal lot size method in the distribution system. In general, the lot size methods used in the distribution system is the same as the methods of the MRP system. The lot size methods used in this study are LFL, EoQ, LTC and POQ.. Resulting in case study, LTC is the optimal lot size method in the distribution system. In distribution system, VRP and VSP shall be investgated.

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