• Transactions of the Korean hydrogen and new energy society
• /
• v.30 no.1
• /
• pp.29-34
• /
• 2019

Safety of hydrogen handling facilities is needed as supply of hydrogen cars has been expanded recently. In this study, the adequacy of safety regulations of hydrogen handling facilities and the risk of damage with hydrogen leakage were studied. The range of explosion hazard location of the hydrogen filling plant was investigated using the computational fluid dynamics (CFD) method, Explosive hazardous area is influenced by leakage type, hole size and sectional area. When the conditions of KS standard are applied, range explosive hazardous area is expanded 7.05 m, maximum. It is about 7 times larger than exceptional standard of hydrogen station. Meanwhile, distance from leakage point to 25% LEL of hydrogen is investigated 1.6 m. Considering the shape of charging hose, regulation of hydrogen station is appropriate.

• Journal of the Korean Vacuum Society
• /
• v.10 no.3
• /
• pp.289-297
• /
• 2001

Highly-porous $SnO_2$thin films were prepared for recognizing and detecting of the inflammable gases, like butane, propane, LPG, carbon monoxide. To obtain sensing films, Sn, Pt/Sn, Au/Sn, and Pt,Au/Sn films were deposited employing a thermal evaporator for Sn film and a sputter for novel metals of Pt or/and Au. These films were annealed for 2 h at $700^{\circ}C$ to form $SnO_2$-based thin films. The films showed the tetragonal structure and also exhibited many defects and porosity, which could give high sensitivity to thin films. The thin films showed high sensitivity and reproductivity to the tested gases(butane, propane, LPG, and carbon monoxide) to even to low gas concentrations in range of workplace environmental standards. Especially, Pt/$SnO_2$film showed the highest sensitivity to butane, LPG, and carbon monoxide. And pure $SnO_2$ film manifested the highest sensitivity to propane. By using the sensing patterns from the films, we could reliably recognize the kinds and the quantities of the tested inflammable gases within the range of the threshold limit values(TLV) and the lower explosion limit(LEL) through the principal component analysis(PCA).

• Korean Journal of Soil Science and Fertilizer
• /
• v.45 no.6
• /
• pp.882-889
• /
• 2012

This study was surveyed that water physiochemical characteristics and phytoplankton incidence of main stream and Lake Doam near to Daegwallyeong agricultural area. Based on above results, it was conducted to get information overall water characteristics in south Han upstream river. COD value of Lake Doam was $6.1mg\;L^{-1}$ and T-P (Total phosphorous) from there was $0.26mg\;L^{-1}$ which was higher than the value of grade VI based on lake water living environment standard. Suspended solid was an average of 9.77 NTU which was higher than value of lake living standard. Concentration of phytoplankton was over $2.0{\times}10^3Cell\;mL^{-1}$ from July to September. It was considered that cyanobacteria were occurred due to massive influx of nutrient material by high temperature and rainfall during this season. Compare to Ontario's sediment quality guidelines, T-N and T-P was middle value between LEL and SEL in Lake Doam. This value means that contamination in water is serious. Therefore, it is considered that systematic management was needed to reduce and block contamination source.

• Journal of Korean Society of Occupational and Environmental Hygiene
• /
• v.19 no.4
• /
• pp.381-389
• /
• 2009

Confined spaces are inherently dangerous workplace and many fatal and nonfatal accidents have been reported. Even though these accidents occur in various kinds of confined spaces, there has rarely been reported on the health hazard agent, i.e., the types of gases and their concentration ranges. Therefore in this study, we evaluated several toxic and asphyxiating gas concentrations in various confined spaces. We surveyed 57 manholes, 3 sewage treatment plants, 2 yellow radish manufacturing companies and 7 barges to measure the concentrations of oxygen($O_2$), hydrogen sulfide($H_2S$), carbon monoxide(CO), ammonia($NH_3$). Lower Explosion Limits(LEL) and Volatile Organic Compounds (VOCs). Those four types of confined spaces occupies 56% of accidents during last 9 years in Korea. In 57 manholes, the concentration varied according to the types of manholes; rainfall and sewage, and by location; residential and industrial areas. Sewage manhole in industrial area was evaluated as the most hazardous than other types of manhole like rainfall manholes, residential sewage manholes. The highest $H_2S$ concentration and the lowest $O_2$ concentration at sewage manhole in industrial area were 300 ppm, 8.7% respectively. In 3 sewage treatment plants, $H_2S$ and $NH_3$ concentrations were reached up to the 500 ppm and 200 ppm respectively. Two yellow radish manufacturing companies showed the concentrations of 316 ppm, 505.2 ppm, 90 ppm and 15.7% for $H_2S$, CO, VOCs and $O_2$, respectively. Seven barges showed 15.9%~20.9% oxygen concentration. Gas species and concentration ranges varied by the types and location of confined spaces; CO, $H_2S$, $O_2$ could be hazardous in manhole, especially manhole connected to sewage plants. CO, $H_2S$, LEL, $O_2$, $NH_3$ should be controlled in sludge silo and sluge pumping confined spaces in sewage treatment plant. The activity of lifting out radish from the storage tank was evaluated more hazardous rather than the other activities in yellow radish manufacturing industry. The employers must conduct the survey to identify all possible confined spaces in their local workplace prior to performing the tasks. At the national level to reduce the accidents in the confined spaces, we suggest that systemic approach and active education program including possible hazards, standard operation procedures, ventilation plan, and personal protective equipment in confined spaces should be implemented.

• Korean Chemical Engineering Research
• /
• v.57 no.6
• /
• pp.790-803
• /
• 2019

The dioctyl terephthalic acid (DOTP) process produces plastic plasticizers by esterification of terephthalic acid with powder in the form of octanol. In this study, the dust explosion characteristics of terephthalic acid directly injected into the manhole in the form of powder in the presence of flammable solvent or vapor in the reactor of this process were investigated. Dust particle size and particle size distribution dust characteristics were investigated, and pyrolysis characteristics of dust were investigated to estimate fire and explosion characteristics and ignition temperature. Also, the minimum ignition energy experiment was performed to evaluate the explosion sensitivity. As a result, the average particle size of terephthalic acid powder was $143.433{\mu}m$. From the thermal analysis carried out under these particle size and particle size distribution conditions, the ignition temperature of the dust was about $253^{\circ}C$. The lower explosive limit (LEL) of the terephthalic acid was determined to be $50g/m^3$. The minimum ignition energy (MIE) for explosion sensitivity is (10 < MIE < 300) mJ, and the estimated minimum ignition energy (Es) based on the ignition probability is 210 mJ. The maximum explosion pressure ($P_{max}$) and the maximum explosion pressure rise rate $({\frac{dP}{dt}})_{max}$ of terephthalic acid dust were 7.1 bar and 511 bar/s, respectively. The dust explosion index (Kst) was 139 mbar/s, corresponding to the dust explosion grade St 1.

• Korean Chemical Engineering Research
• /
• v.59 no.4
• /
• pp.521-531
• /
• 2021

Vacuum Pressure Impregnation (VPI) is a process that enhances physical properties by coating some types of epoxy resins on windings of stator used in large rotators such as generators and motors. During vacuum and pressurization of the VPI process, resin gas is generated by vaporization of epoxy resin. When the tank is opened for curing after finishing impregnation, resin gas is leaked out of the tank. If the leaked resin gas spreads throughout the workplace, there are safety and environmental problems such as fire, explosion and respiratory problems. So, exhaust system for resin gas is required during the process. In this study, a case study of exhaust efficiency by location of vent was conducted using Computational Fluid Dynamics (CFD) in order to design a system for exhausting resin gas generated by the VPI process. The optimal exhaust system of this study allowed more than 90% of resin gas to be exhausted within 1,800 seconds and reduced the fraction of resin gas below the Low Explosive Limit (LEL).

• Journal of the Korean Institute of Gas
• /
• v.26 no.4
• /
• pp.27-35
• /
• 2022

When LPG leaks from the storage tank, the gas try to sink to the ground because LPG is heavier than air. The gas easily creates vapor clouds causing aggressive accidents in no airflow. Therefore, It is important to prevent in advance by analyzing the damaged range caused from LPG leakage and vapor clouds. So, this study analyzed the range of damaged by LPG leakage and vapor clouds with consideration of the cold air flow which is generated by the topographical characteristics and the land use status at night time in the Jeju Hagari. As a result of the cold air flow using KLAM_21, about 2 m/s of cold air was introduced in from the southeast due to the influence of the terrain. The range of damaged by LPG leakage and vapor cloud was analyzed using ALOHA. When the leak hole size is 10 cm at the wind speed of 2 m/s, the range corresponding to LEL 60 % (12,600 ppm) was 61 m which range is expected to influence in nearby residential areas. These results of this study can be used as basic data to prepare preventive measures of accidents caused by vapor cloud. Forward, it is necessary to apply CFD modeling such as FLACS to check the vapor cloud formation due to LPG leakage in a relatively narrow area and to check the cause analysis.

• Journal of the Korean Institute of Gas
• /
• v.17 no.6
• /
• pp.33-38
• /
• 2013

For the safe handling of 3-hexanone(ethyl propyl ketone), this study was investigated the explosion limits of 3-hexanone in the reference data. The flash points and AITs(auto-ignition temperatures) by ignition delay time were experimented. The lower flash points of 3-hexanone by using closed-cup tester were experimented at $18^{\circ}C$. The lower flash points of 3-hexanone by using open cup tester were experimented in $27^{\circ}C{\sim}32^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for 3-hexanone. The experimental AIT of 3-hexanone was at $425^{\circ}C$. The lower explosion limit( LEL) by the measured lower flash point of 3-hexanone was calculated as 1.21 Vol%.

• Journal of the Korean Institute of Gas
• /
• v.10 no.1 s.30
• /
• pp.19-25
• /
• 2006

Explosion limit is one of the major physical properties used to determine the fire and explosion hazards of the flammable substances. Explosion limits are used to classify flammable materials according to their relative flammability. Such a classification is important for the safe handling, storage, transportation of flammable substances. In this study, the lower explosion limits(LEL) of the flammable mixtures predicted with the appropriate use of the vapor composition and the heat of combustion of the individual components which constitute mixture. The values calculated by the proposed equations were a good agreement with literature data within a few percent. From a given results, It is to be hoped that this methodology will contribute to the estimation of the explosive properties of flammable mixtures with improved accuracy and the broader application for other flammable substances.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.25 no.11
• /
• pp.624-630
• /
• 2013

A truck refrigeration system using phase change material (PCM) is expected to have a lower noise level, reduced energy cost, and much lower local greenhouse gas emission. Recently, a forced convection type PCM refrigeration module has been developed. As the operation time increases, the PCM around the air inlet melts, because of a large temperature difference between the PCM and air. Therefore, the latent heat transfer area decreases and the heat transfer rate of the module decreases even though there is a lot of PCM which does not melt around the air outlet. A computational fluid dynamic modeling of the PCM refrigeration module was developed and validated by the experiment. Using the CFD, the design parameters, such as the mass flow rate of the air and roughness of the slab, were investigated to improve the heat transfer inhomogeneity. As a result, the adoption of partial roughness on the slabs improved the heat transfer inhomogeneity and reduced a fan power.