• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 추계학술대회 논문집
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• pp.545-548
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• 1999

The electro-optical characteristics of photo-aligned vertical-alignment (VA)-liquid crystal display (LCD) with non-polarized ultraviolet (UV) light irradiation of 45\`on homeotropic polyimide (Pl) surface were investigated. LC alignment on photo-aligned VA-LCD is attributed to photo-depolymerized reaction of the polymer with non-polarized UV light irradiation on PI surface. We had good voltage-transmittance (V-T) characteristics of photo-aligned VA-LCD. The response time of photo-aligned VA-LCD was slower than that of the rubbing-aligned VA-LCD. Finally, we suggest that the slow response time of photo-aligned VA-LCD depends on the LC domain.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.I
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• pp.755-758
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• 2005

The mechanism responsible for liquid crystal (LC) alignment on solid substrates treated with mechanical rubbing or polarized UV is not understood. The results of x-ray reflectivity study of LC alignment on a large number of different alignment layers show that the anisotropy in the surface roughness of the substrate completely determines the LC alignment. The anchoring energy depends on the degree of roughness anisotropy and chemical interactions between the substrate and LC molecules.

• 폴리머
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• 제29권4호
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• pp.413-417
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• 2005

LCD 배향막으로 응용하기 위하여 광반응성 polyvinylcinnamate 필름 위에서 액정 분자들의 배향에 관한 연구를 수행하였다. 선편광 UV를 polyvinylcinnamate 필름에 노광하면 선택적인 광반응에 의하여 필름 내에 이방성이 형성되고, 필름 표면에 인접한 액정 분자는 고분자와 분자간 상호작용으로 고분자 배향 방향과 동일한 방향으로 늘어선다. 광배향막을 사용한 액정 셀의 열 및 빛에 대한 안정성은 배향막에 UV를 다시 노광하고 열을 가한 후 유도된 액정 배향 변화를 측정하여 조사하였다. 선편광 UV를 여러번 노광한 필름의 경우 처음 노광 방향에 관계없이 최종으로 노광한 편광 UV의 방향에 따라 액정 배향이 유도되었다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1999년도 하계학술대회 논문집 D
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• pp.1762-1764
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• 1999

We investigated the annealing effect on generating pretilt angle and aligning liquid crystal (LC) using the photo-depolymerization reaction in this study. In case of rubbing polyimide (PI) surface with the side chain, pretilt angle tends to increase with increasing the annealing time. It is considered because the steric interaction is increased by annealing which cause the side chain to come back to original position. For obliquely irradiating ultraviolet (UV) light on PI surface, pretilt angle shows to $0^{\circ}$ and is increased by annealing. The pretilt angle in rubbed PI surface is much higher than in photo-aligned PI surface. It is attributed to the steric interaction and the number of LC molecular arrangement on azimuthal direction. In addition. in case of obliquely irradiating UV light on PI surface. it showed LC alignment to increase by annealing. It can be regarded due to the fact that the re-alignment of LC molecule is improved to residual polymer direction by annealing.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2001년도 추계학술대회 논문집 전기물성,응용부문
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• pp.182-185
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• 2001

A photoalignment material based N-(phenyl)maileimide were synthesized and the liquid crystal (LC) aligning capabilities on the photopolymer layer were studied. A goof LC alignment with UV exposure on the PM15CA(N-(phenyl)maileimide with 5-carbon chain cinnamoyl group) can be obtained However, the LC alignment defects were observed on the PM13CA (N-(phenyl)maileimide with 3-carbon cam cinnamoyl group) and PMIF (N-(Phenyl)maileimide including fluoro cinnamoyl group). Also, the good LC alignment with UV exposure on the PM15CA surface was observed at until $150^{\circ}C$ of annealing temperature. The LC aliging ability on the photopolymer layer based N-(phenyl)maleimide depends on the side chin length of photopolymer.

• 폴리머
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• 제32권3호
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• pp.290-294
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• 2008

러빙한 고분자 필름이 액정 분자와 증착된 분자의 배향을 유도하는 메커니즘을 이해하고자 $\pi$ 전자들의 공액구조가 주사슬과 곁사슬에 각각 있는 polyimide와 polyyinylcinnamate를 사용하여 필름과 LC 셀을 만들어 편광 UV/Vis 분광실험으로 조사하였다. 러빙한 필름 내에 형성되는 이방성, LC 셀의 액정 방향자, 그리고 종착된 pentacene의 배열방향을 측정하여, 액정배향은 microgroove 영향보다는 분자간 상호작용에 의하여 우선적으로 유도되는 반면에 pentacene 증착의 경우에는 러빙에 의하여 형성된 필름 표면의 microgroove 영향으로 배향이 유도되는 것을 알 수 있었다.

• Bulletin of the Korean Chemical Society
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• 제28권10호
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• pp.1651-1655
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• 2007

Rod-like polymerizable LC molecules having two different reactive groups, i.e. acryl and diacetylene groups were prepared. 4-Hydroxyphenyldiacetylenes were synthesized by the coupling reaction of 1-bromoalkynes with 4-ethynylphenol and then reacted with 4-(6-acryloyloxyalkyloxy)benzoic acid to give polymerizable LC molecules 4a-d. The mesomorphic properties of compounds 4a-d were investigated by differential scanning calorimetry, polarized optical microscopy and X-ray diffractometry. Compounds 4a-c exhibited smectic and nematic phases, but compound 4d having a longest alkyl tail among the series formed only a smectic phase. Photopolymerizability of acryl and diacetylene groups was investigated by IR spectroscopy. An anisotropic polymer film could be prepared by selective polymerization of acryl groups with 365 nm UV light in the presence of a photoinitiator (2,2-dimethoxy-2-phenylacetophenone). The subsequent reaction of diacetylene groups with 254 nm UV light disrupted the anisotropic structure, suggesting that these LC molecules could be used for imaging on the film.

• Macromolecular Research
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• 제17권4호
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• pp.271-275
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• 2009

This paper describes the out-of-plane order of a liquid crystalline(LC) methacrylate copolymer(3) comprised of a methacrylate(1) with a 4-styrylpyridine moiety as the photo-cyclodimerizable group and a benzoate moiety as the mesogenic group in the side chain, and another methacrylate(2) with a 4-(4-methoxyphenyl)benzoate moiety as the mesogenic group. The composition of 1 and 2 units in 3 was estimated to have a molar ratio of 54.2:45.8 by $^{1}H$ NMR spectroscopy. The X-ray diffraction study revealed that the copolymer forms a partial bilayer smectic structure. The copolymer gave rise to a high out-of-plane order parameter of about 0.74 in a wide LC temperature range of $110{\sim}160^{\circ}C$ after linearly polarized, UV light irradiation and subsequent annealing. Moreover, the external reflection IR analysis indicated that excess UV-light irradiation makes the out-of-plane LC structure of the copolymer appear in a higher and wider temperature range.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권2호
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• pp.1125-1128
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• 2007

The laminating technique for developing flexible liquid crystal display was demonstrated by using a thin UV curable polymer film and a plastic substrate with patterned polymer wall structure. We adopted the rigid wall structure to provide a solid mechanical support for the stable molecular alignment of liquid crystals (LCs) in the device. The cover film was prepared to have an ability of aligning LC molecules by patterning a micro-groove structure using the soft-lithographic process. These two substrates can be assembled tightly by the laminating and one-step UV irradiation process because of the adhesive nature of the used UV curable polymers. Proposed method can be used to fabricate the flexible LC display with simplicity and also be applicable for a cost-effective roll-to-roll process.

• 한국전기전자재료학회논문지
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• 제18권10호
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• pp.924-928
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• 2005

We synthesized the two types of photoalignment material of high thermal resistance with hydroxyl aromatic polyimide, and studied the liquid crystal (LC) aligning capabilities on the photopolymer layers. Also, electro-optical (EO) performances for the twisted-nematic (TN)-liquid crystal display (LCD) photoaligned with linearly polarized UV exposure were investigated. A good LC alignment with UV exposure on the two types of photopolymer surface can be obtained. The Voltage-transmittance (V-T) curve in the photoaligned TN cell with UV exposure was different from two type. The response time of photoaligned TN cell was measured about 21 ms in two alkyl chain and about 15 ms in four alkyl chain.