• Title/Summary/Keyword: LA-ICPMS

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LA-MC-ICPMS U-Pb Ages of the Detrital Zircons from the Baengnyeong Group: Implications of the Dominance of the Mesoproterozoic Zircons (신원생대 백령층군 사암의 쇄설성 저어콘 LA-MC-ICPMS U-Pb 연령: 중원생대 집중연령의 의미)

  • Kim, Myoung Jung;Park, Jeong-Woong;Lee, Tae-Ho;Song, Yong-Sun;Park, Kye-Hun
    • Economic and Environmental Geology
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    • v.49 no.6
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    • pp.433-444
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    • 2016
  • The U-Pb ages of detrital zircons from the Baengnyeong Group were determined by LA-MC-ICPMS, yielding condensed age population in the range from 1100 Ma to 1800 Ma corresponding to the Mesoproterozoic to late Paleoproterozoic. However, detrital zircons of ca.1800-2000 Ma or ca. 2500 Ma ages, which appear frequently in the lower Paleozoic Joseon Supergroup and the upper Paleozoic Pyeongan Supergroup are lacking in the Baengnyeong Group. Such characteristics are identical to those of the Neoproterozoic Sangwon System of North Korea, suggesting that the Baengnyeong Group might be the southwestern extension of the Sangwon System. The zircon age distribution patterns from the Impi Formation in the Gunsan area closely resemble those of the Baengnyeong Group, implying possible correlation of the Impi Formation to the Sangwon System. Therefore, the Mesoproterozoic detrital zircons reported from the Hwangangni Formation of the Okcheon Metamorphic Belt and the Myobong, Sambangsan and Sesong Formations of the Taebaeksan Basin might be derived from the provenances within the Korean peninsula.

A Preliminary Study for a Glass Geological Reference Material Using Obsidian (흑요암을 이용한 유리 지질 표준물질에 대한 예비 연구)

  • Jin, Mi-Eun;Jwa, Yong-Joo;Park, Sang Gu;Sun, Gwang Min
    • Korean Journal of Mineralogy and Petrology
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    • v.33 no.1
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    • pp.65-71
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    • 2020
  • Glass reference materials have been essentially used for precise geochemistry analytical techniques. In order to make up for the drawback of synthetic glass reference materials, which have the high uncertainty caused by the difference in composition of natural rocks, we introduce a glass geostandard using natural glass. The NK-B1G sample, which comes from the Baekdusan obsidian, is a natural glassy rock that contains only few crystals such as microlites or inclusions. We examined the feasibility of the sample as a reference material for microanalysis like EPMA or LA-ICPMS.

Producing of Bronze Artifacts Excavated from Gulsansa Temple Site in Gangneung: Technology and Provenance (강릉 굴산사지에서 출토된 청동기의 제작: 제작기술 및 원료산지)

  • Han, Woo Rim;Kim, So Jin;Lee, Eun Woo;Hwang, Jin Ju
    • Journal of Conservation Science
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    • v.35 no.3
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    • pp.187-196
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    • 2019
  • Bronzes excavated from a Gulsansa temple site in Gangneung were investigated in order to study the production of technology and provenance in this area. The bronze artifacts were discovered to consist of copper-tin or copper-tin-lead alloys using chemical analysis(EDS and EPMA). The excavated bronzes were manufactured using a casting or hammering process, and a bronze belt was gilded with gold foil. The provenance of 25 bronzes was studied using lead isotope analysis(TIMS and LA-MC-ICPMS). The results reveal the use of raw materials found near the excavated site. The object of this study was to investigate the manufacturing techniques and provenance in Gangneung without the need for a lot of data. Our results will contribute to the study of Gulsansa and bronze artifacts in Goryo(12-13th century).

Geology and U-Pb Age in the Eastern Part of Yeongdeok-gun, Gyeongsangbuk-do, Korea (경북 영덕군 동부 일원의 지질과 U-Pb 연령)

  • Kang, Hee-Cheol;Cheon, Youngbeom;Ha, Sangmin;Seo, Kyunghan;Kim, Jong-Sun;Shin, Hyeon Cho;Son, Moon
    • The Journal of the Petrological Society of Korea
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    • v.27 no.3
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    • pp.153-171
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    • 2018
  • This study focuses on the investigation of geologic distribution and stratigraphy in the eastern part of Yeongdeok-gun, based on Lidar imaging, detailed field survey, microscopic observations, SHRIMP and LA-MC-ICPMS U-Pb age dating, and a new geological map has been created. The stratigraphy of the study area is composed of the Paleoproterozoic metamorphic rocks consisting of banded gneisses of sedimentary origin and schists ($1841.5{\pm}9.6Ma$) of volcanic origin, Triassic Yeongdeok plutonic rocks ($249.1{\pm}2.3Ma$) and Pinkish granites ($242.4{\pm}2.4Ma$), Jurassic Changpo plutonic rocks ($193.2{\pm}1.9Ma{\sim}188.8{\pm}2.0Ma$) and Fine-grained granites ($192.9{\pm}1.7Ma$), Formations [Gyeongjeongdong Fm, Ullyeonsan Fm. (~108 Ma), Donghwachi Fm.] of the Early Cretaceous Gyeongsang Supergroup and acidic volcanic rocks and dykes erupted and intruded in the Late Cretaceous, Miocene intrusive rhyolitic tuffs ($23.1{\pm}0.2Ma{\sim}22.97{\pm}0.13Ma$) and sedimentary rocks of the Yeonghae basin, and the Quaternary sediments. The Triassic Pinkish granites, Jurassic Changpo plutonic rocks and Fine-grained granites are newly defined plutonic rocks in this study. Miocene intrusive rhyolitic tuffs bounded by the Yangsan Fault, which was first discovered in the north of Pohang city, are believed to play an important role in the understanding of the Miocene volcanic activity and the crustal deformation history on the Korean Peninsula. It is confirmed that The NNE-SSW-striking Yangsan Fault penetrating the central part of the study area and branch faults are predominant in the dextral movement and cutting all strata except the Quaternary sediments.

The Late Cretaceous Emplacement Age of Masan Hornblende-Biotite Granite (마산 각섬석-흑운모 화강암의 연령: 후기 백악기 정치연령)

  • Lee, Tae-Ho;Park, Kye-Hun;Kim, Jeongmin;Kim, Myoung Jung
    • The Journal of the Petrological Society of Korea
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    • v.26 no.1
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    • pp.1-11
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    • 2017
  • We have dated the K-Ar, Ar-Ar and U-Pb ages of the Masan hornblende-biotite granite in the southern Cretaceous Gyeongsang basin to constrain its emplacement age. The ~108 Ma hornblende K-Ar age obtained in the study is similar to the previously reported Rb-Sr age. However, the single grain total fusion $^{40}Ar/^{39}Ar$ dating on hornblende failed to yield statistically meaningful ages because the isotopic system was open during its alteration. Thus the hornblende K-Ar age in the study is also unlikely to be reliable. The single grain total fusion $^{40}Ar/^{39}Ar$ dating on biotite yielded an average age of $75.8{\pm}3.0Ma$. Apart from scattered data in the range of ~45-75 Ma, the average age increased to ~80 Ma. The SHRIMP and LA-MC-ICPMS U-Pb isotopic compositions of zircon from the Masan hornblende-biotite granite yielded its emplacement age as $87.6{\pm}2.7Ma$ and $86.8{\pm}0.4Ma$, respectively. It is thus likely that the ~80 Ma $^{40}Ar/^{39}Ar$ age of biotite might reflect the cooling age of Masan hornblende-biotite granite or the thermal influences from later intense igneous activities in the Gyeongsang basin.

A Study on the Precipitation Mechanism of Quartz Veins from Sangdong Deposit by Analyses of Vein Texture and Trace Element in Quartz (상동광산 석영맥의 조직 및 석영의 미량원소 분석을 통한 광맥 침전 기작 도출)

  • Youseong Lee;Changyun Park;Yeongkyoo Kim
    • Economic and Environmental Geology
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    • v.56 no.3
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    • pp.239-257
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    • 2023
  • Sangdong deposit, a W-Mo skarn deposit, is located in Taebaeksan mineralized district, hosting vertically developed scheelite-quartz veins that formed at the late ore-forming stage. In this study, we tried to examine the geochemical signatures of ore-forming fluids and vein-forming mechanisms by analyzing the micro-texture of quartz veins and trace element concentrations of quartz. As a result of texture analyses, quartz veins in the hanging wall orebody and the foot wall orebody commonly exhibit the blocky and the elongate blocky texture, respectively, whereas quartz veins in the main orebody show both textures. These textural differences indicate that quartz veins from the hanging wall orebody were precipitated by the primary hydrofracturing due to H2O saturation in the igneous body with relatively high temperature and pressure at a vein-skarn stage, and after that, repeated hydrofracturing caused the formation of quartz veins from the main orebody and foot wall orebody. The results of trace element concentrations show that Li++Al3+↔Si4+ is a main substitution mechanism. However, those of the foot wall orebody were clearly divided into a Li+-dominated substitution and a Na+-, K+-dominated substitution. Considering that quartz veins from the foot wall orebody commonly show the elongate blocky texture, such a distinction means that it is a result of repeated injections of fluid with the different composition. Ti concentrations of quartz from the hanging wall, main, and the foot wall orebody are 28.6, 8.2, and 15.7 ppm in average, respectively. Given a proportional relationship between the precipitation temperature and Ti concentrations, it seems that quartz veins from the hanging wall orebody were precipitated at the highest temperature. Al concentrations of the hanging wall, main, and the foot wall orebody having an inverse relationship with fluid pH are 162.3, 114.2, and 182.5 ppm in average, respectively. These results show that Al concentrations in vein-forming fluids were not changed dramatically. Moreover, these concentrations are extremely low in comparison with the other hydrothermal deposits. This indicates that quartz in overall ore veins at Sangdong deposit was precipitated from the constant condition with slightly acidic to near neutral pH.