• Applied Chemistry for Engineering
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• v.10 no.8
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• pp.1210-1215
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• 1999

Optimum conditions of the hydrogenation of PNA to pure PPD were determined in a three-phase slurry reactor with suspended Pd/C catalyst particles. Minimization of mass transfer resistances at the interfaces of both gas-liquid and liquid-catalyst particles and control of overall reaction rate on catalyst surface leaded to decrease the hydrogen starvation on reaction active sites and to reduce the side reactions during hydrogenation. The optimum temperature, pressure, and catalysst concentration were confirmed to be in the range of $60^{\circ}C$, 60~70 psig, and 1~2 g-cat/L, respectively. Reaction rate was zero order with respect to the concentration of PNA and 1st order with respect to the pressure of hydrogen(P). Overall rate expression of the reaction was $R_A=6.44{\times}10^6{\cdot}H{\cdot}P{\cdot}m{\cdot}$exp(-4659/T) where H is constant, m is concentration of catalyst, and T is temperature.

• KSBB Journal
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• v.14 no.5
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• pp.585-592
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• 1999

This study was aimed to enhance the Fe(II) oxidation rate using immobilized cells of Thiobacillus ferroxidans. For this purpose, a medium for the minimization of jarosite formation was developed first. Secondly, cell immobilization in celite beads was carried out. And then, repeated-batch and continuous operatons of Fe(II) oxidation by using immobilization cells were performed. In a series of flask cultures, three types of media were tested: media with a much lower salt concentration than that of the 9K medium; media which contained different nitrogen sources from that of the 9K medium, that is $(NH_4)_2HPO_4$, $NH_4Cl and HNO$_3$; media which contained $(NH_4)_2HPO_4$ as nitrogen and phosphate source, but without $K_2HPO_4$ as nitrogen and phosphate source in the 9K medium. As a result, the M16 medium which contained 3 g/L of $(NH_4)_2HPO_4$ as nitrogen and phosphate source was found to be the optimal one. It sustained good cell growth allowing no jarosite formation. In the repeated-batch operations, the rate of Fe(II) oxidation gradually increased to reach a maximum value as the batch was repeated. As a result of repeated-batch operations. a maximum Fe(II) oxidation rate was 2.33 g/L . h. In the continuous operations, the iron oxidation rate could be increased to 2.14 g/L .h at a dilution rate of 0.25 $h^{-1}$ which is greater than the maximum specific growth rate (0.12 $h^{-1}$) of the bacteria.

• The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.7 no.6
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• pp.42-50
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• 1993

In this paper the affect an inorganic filler and a f i n g up water absorption in epoxy composite material was represented. The results are summarized as follows ; 1. In the case of Sample 1, Sample 2 and a fillng up water absorption, the frequency depenence of E,' shows the straight characteristic underl4O0C. 2. Between lOOHz and 3kHz, the frequency dependency of tan8 is dominated by the loss of a dipole relaxation than the conductive loss for movement of a career. The effect of water absorption, is increased as the frequency is d e creased.

• Journal of Korean Society of Rural Planning
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• v.11 no.1 s.26
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• pp.1-8
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• 2005

The purpose of this study is to develop a simulation model of rural road path for infrastructure of green-tourism and public service in rural areas. This study makes an objective function for moving cost minimization considering car travel time according to road characteristics, which can route the optimal shortest road paths between the center places and all rear villages, based on GIS coverages of road-village network for connecting between center places and rural villages as input data of the model. In order to verify the model algorithm, a homogeneous hexagonal network, assuming distribution of villages with same population density and equal distance between neighborhood villages on a level plane area, was tested to simulate the optimal paths between the selected center nodes and the other rear nodes, so that the test showed reasonable shortest paths and road intensity defined in this study. The model was also applied to the actual rural area, Ucheon-myun, which is located on Hoengsung-gun, Kangwon-do, with 72 rural villages, a center village (Uhang, 1st center place) in the area, a county conte. (Hoengsung-eup, 2nd center place), and a city (Wonju, 3rd center place), as upper settlement system. The three kinds of conte. place, Uhang, Hoengsung-eup, and Wonju, were considered as center places of three scenarios to simulate the optimal shortest paths between the centers and rural villages, respectively. The simulation results on the road-village network with road information about pavement and width of road show that several spans having high intensity of road are more important that the others, while some road spans have low intensity of road.

• Journal of the Korea Organic Resources Recycling Association
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• v.2 no.1
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• pp.87-98
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• 1994

Sludge minimization in an water treatment plant can be achieved by optimizing a main water treatment process as well as by enhancing a thickening and a dewatering facilities. In this study, dewatering and drying techniques for reducing the quantity of the water sludge generated from the conventional water treatment plant in the local states were investigated by reducing its water content. Not only the types and dosages of polymers but also the mixing intensity of the mixtures of a concentrated sludge and polymers on the different pH were evaluated for the optimum dewatering conditions of the water sludge. Weight reduction of the water sludge was also tested at a given temperature range. The dewatering efficiency of the water sludge was not affected by the types of polymer but by mixing intensity(GT value) in this study. pH effect on dewaterbility of the water sludge took a major role at the neutral pH range. The optimal polymer dose was 1.5 mg-polymer/g-TSS(about 40mg/L as polymer). Dewaterability was enhanced at a lower mixing intensity(GTbelow 10,000 sec-1). Free water in the void of sludge cake was dried around $100^{\circ}C$, chemical bound water was evaporated around $320^{\circ}C$, and organic material was burned out at the range of 300 to $600^{\circ}C$. Ignition losses of the water sludge were varied 15 to 40 % as the raw water quality. The ignition loss due to the chemical bound water was 10-20% and the loss due to the organic material was 4-20% of the total ignition loss.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.10
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• pp.6296-6302
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• 2014

A new technique, which can increase the channel bandwidth in an optical wireless orthogonal frequency division multiplexing (OFDM) link based on a light emitting diode (LED), is proposed. The technique uses adaptive sampling to convert an OFDM signal to a sparse waveform. In compressive sensing (CS), a sparse signal that is sampled below the Nyquist/Shannon limit can be reconstructed successively with sufficient measurements. The data rate of the proposed CS-based visible light communication (VLC)-OFDM link increases from 30.72 Mb/s to 51.2 Mb/s showing an error vector magnitude (EVM) of 31 % at the quadrature phase shift keying (QPSK) symbol.

• Journal of Biomedical Engineering Research
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• v.31 no.6
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• pp.464-471
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• 2010

Compressed sensing can be used to reduce scan time or to enhance spatial resolution in MRI. It is now recognized that compressed sensing works well in reconstructing magnitude images if the sampling mask and the sparsifying transform are well chosen. Phase images also play important roles in MRI particularly in chemical shift imaging and magnetic resonance electrical impedance tomography (MREIT). We reconstruct MRI phase images using the compressed sensing technique. Through computer simulation and real MRI experiments, we reconstructed phase images using the compressed sensing technique and we compared them with the ones reconstructed by conventional Fourier reconstruction technique. As compared to conventional Fourier reconstruction with the same number of phase encoding steps, compressed sensing shows better performance in terms of mean squared phase error and edge preservation. We expect compressed sensing can be used to reduce the scan time or to enhance spatial resolution of MREIT.

• Journal of Korean Society on Water Environment
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• v.33 no.2
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• pp.187-196
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• 2017

To ensure hygienic safety of drinking water in a water storage tank, the concentrations of residual chlorine should be above a certain regulation level. In this study, we conducted model simulations to investigate the effects of temperature on residual chlorine in water storage tank conditions typically used in Seoul. For this, values of model parameters (decomposition rate constant, sorption coefficient, and evaporation mass transfer coefficient) were experimentally determined from laboratory experiments. The model simulations under continuous flow conditions showed that the residual chlorine concentrations were satisfied the water quality standard level (0.1 mg/L) at all the temperature conditions ($5^{\circ}C$, $10^{\circ}C$, $15^{\circ}C$, $20^{\circ}C$ and $25^{\circ}C$). Meanwhile, when the tanks had a no flow condition (i.e., no tap-water influent due to a sudden shut-down), the concentrations became lower than the regulatory level after certain periods. The findings from this modeling works simulating Seoul's water storage tanks suggested disappearance rate of residual chlorine could be reduced through the tanks design optimization with maintenance of low water temperature, minimization of air flow and volume, suppression of dispersion and the use of wall materials with low sorption ability.

• Archives of Pharmacal Research
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• v.18 no.1
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• pp.22-26
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• 1995

The solubility and dissolution rate of naproxen (NPX) complexed with 2-hydroxypropyl-.betha.-cyc-lodextrin (2-HP.betha.CD) using coprecipitation, evaporation, freeze-drying and kneading method were investigated. Solubility of NPX linearly increased (correlation cefficient, 0.995) as $2-HP\betaCD$ concentraction increased, resutling in $A_l$ type phase solubility curve. Inclusion complexes prepared by four different methods were compared by different methods were compared by dfferential scanning calorimetry(DSC). The NPX showed sharp endothemic peak around $156^{\circ}C$ but inclusion complexes by evaporation, freeze-drying and kneading method showed very broad peak without distinct phase transtion temperature. In contrast, inclusion complex prepared by coprecipitation method resulted in detectable peak around $156^{\circ}C$ which is similar to NPX, suggesting incoplete formation of indusion co plex. Dissolution rate of inclusion complexes prepared by evaporation, frezz-drying and kneding except coprecipitation method was largely enhanced in the simultaed gastric and intestinal fluid when compared to NPX powder and commercial $NA-XEN^\registered$tablet. However, about 65% of NPX in gstric fluid. in case of inclusion complex prepared by coprecipitation method, formation of inclusion complex appeared to be incoplete, resulting in no marked enhancement of dissolution rate. From these findings, inclusion complexes of poorly water-soluble NPX with $2-HP\betaCD$ were useful to increase soubility and dissolution rate, resting in enhancement of bioavailability and minimization of gastrointestinal toxicity of drug upon oral administration of inclusion complex.

• Journal of the Optical Society of Korea
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• v.20 no.6
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• pp.752-761
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• 2016

Hyperspectral images are often contaminated with stripe noise, which severely degrades the imaging quality and the precision of the subsequent processing. In this paper, a variational model is proposed by employing spectral-spatial adaptive unidirectional variation and a sparse representation. Unlike traditional methods, we exploit the spectral correction and remove stripes in different bands and different regions adaptively, instead of selecting parameters band by band. The regularization strength adapts to the spectrally varying stripe intensities and the spatially varying texture information. Spectral correlation is exploited via dictionary learning in the sparse representation framework to prevent spectral distortion. Moreover, the minimization problem, which contains two unsmooth and inseparable $l_1$-norm terms, is optimized by the split Bregman approach. Experimental results, on datasets from several imaging systems, demonstrate that the proposed method can remove stripe noise effectively and adaptively, as well as preserve original detail information.