• 제목/요약/키워드: L-moves

검색결과 71건 처리시간 0.028초

Geometrical Characteristics and Atomic Charge Variations of Pd(II) Complexes [Pd(L)Cl2] with an Axial (Pd·O) Interaction

  • Park, Jong-Keun;Cho, Yong-Guk;Lee, Shim-Sung;Kim, Bong-Gon
    • Bulletin of the Korean Chemical Society
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    • 제25권1호
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    • pp.85-89
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    • 2004
  • Geometrical structures of [Pd(L)$Cl_2$] with oxathia macrocycles have been calculated using ab initio secondorder Moller-Plesset (MP2) and Density Functional Theory (DFT) methods with triple zeta plus polarization (TZP) basis set level. In optimized Pd(L)$Cl_2$ complexes, Pd(II) locates at the center surrounded by a square planar array of two sulfurs on an oxathia macrocycle and two chlorides. The endo-Pd(II) complexes with an axial (Pd${\cdots}$O) interaction are more stable than the exo-Pd(II) complexes without the interaction. In the endo-Pd(II) complexes, the atomic charge of the oxygen atom moves to Pd(II) via the axial ($Pd{\cdots}$O) interaction and then, the charge transfer from Pd(II) to the S-atoms occurs stepwise via ${\pi}$-acceptors of the empty d-orbitals.

Dynamic Responses and Fuzzy Control of a Simply Supported Beam Subjected to a Moving Mass

  • Kong, Yong-Sik;Ryu, Bong-Jo;Shin, Kwang-Bok;Lee, Gyu-Seop;Lee, Hong-Gi
    • Journal of Mechanical Science and Technology
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    • 제20권9호
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    • pp.1371-1381
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    • 2006
  • This paper deals with the active vibration control of a simply-supported beam traversed by a moving mass using fuzzy control. Governing equations for dynamic responses of a beam under a moving mass are derived by Galerkin's mode summation method, and the effect of forces (gravity force, Coliolis force, inertia force caused by the slope of the beam, transverse inertia force of the beam) due to the moving mass on the dynamic response of a beam is discussed. For the active control of dynamic deflection and vibration of a beam under the moving mass, the controller based on fuzzy logic is used and the experiments are conducted by VCM (voice coil motor) actuator to suppress the vibration of a beam. Through the numerical and experimental studies, the following conclusions were obtained. With increasing mass ratio y at a fixed velocity of the moving mass under the critical velocity, the position of moving mass at the maximum dynamic deflection moves to the right end of the beam. With increasing velocity of the moving mass at a fixed mass ratio ${\gamma}$, the position of moving mass at the maximum dynamic deflection moves to the right end of the beam too. The numerical predictions of dynamic deflection of the beam have a good agreement with the experimental results. With the fuzzy control, more than 50% reductions of dynamic deflection and residual vibration of the tested beam under the moving mass are obtained.

고공환경 모사용 이차목 디퓨저의 배압에 따른 성능 특성 (A Study on Performance Characteristics of Second Throat Exhaust Diffuser with Back Pressure)

  • 김완찬;유이상;김태완;박진수;고영성;김민상
    • 대한기계학회논문집B
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    • 제41권9호
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    • pp.563-570
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    • 2017
  • 본 연구에서는 이차목 디퓨저의 배압에 따른 특성과 디퓨저 내부의 유동을 확인하기 위해서 실험과 수치해석을 통하여 살펴보았다. 디퓨저의 배압($P_a$)조건을 모사하기 위해 이젝터를 사용하였으며, 디퓨저와 이젝터는 상온 고압기체질소를 사용하였다. 그 결과, 노즐전단압력($P_0$)이 동일할 때 배압($P_a$)을 낮추어 압력비($P_0/P_a$)를 높게 할수록 압력회복이 디퓨저 후단에서 이루어짐을 확인하였다. 노즐전단압력($P_0$)이 다르더라도 압력비($P_0/P_a)$가 동일하다면 디퓨저 내부의 유동특성이 거의 동일함을 확인하였으며, 시동압력비($(P_0/P_a)_{st}$) 또한 일치함을 확인하였다.

Progressive Inelastic Deformation Characteristics of Cylindrical Structure with Plate-to-Shell Junction Under Moving Temperature Front

  • Lee, Hyeong-Yeon;Kim, Jong-Bum
    • Journal of Mechanical Science and Technology
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    • 제17권3호
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    • pp.400-408
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    • 2003
  • A study on the progressive inelastic deformation behavior of the 316 L stainless steel cylindrical structure with plate-to-shell junction under moving temperature front was carried out by structural test and analysis. The structural test intends to simulate the thermal ratcheting behavior occurring at the reactor baffle of the liquid metal reactor as free surface of hot sodium pool moves up and down under plant transients. The thermal ratchet load that heats the specimen up to 550$^{\circ}C$ was applied repeatedly and residual deformation was measured. The thermal ratcheting test was carried out with two types of cylindrical structures, one with plate to-shell junction and the other without the junction to investigate the effects of the geometric discontinuities on the global ratcheting deformation. The temperature distributions of the test specimens were measured and were used for the ratcheting analysis. The ratchet deformations were analyzed with the constitutive equation of the non-linear combined hardening model. The analysis results were in good agreement with those of the structural tests.

Photochromic 렌즈의 광변색 이동 (Change of color transfer of Photochromic lens)

  • 김용근;성정섭
    • 한국안광학회지
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    • 제8권1호
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    • pp.59-64
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    • 2003
  • Photochoromic lens에 광을 조사하면 darkening 상태와 fading상태에서photo-transmittance는 감소한다. 광의 조사를 제거하면 fading 상태가 되어 photo-transmittance는 원래 상태로 회복하는 가역과정을 갖는다. 자체 제작한 Photochoromic lens에서 darkening과 fading 과정에서 Photochromism의 분광측색계를 이용하여 CIE $L^*a^*b^*$의 색 좌표을 얻는다. darkening과 fading상태에서 색 좌표($a^*-b^*$)는 일차 곡선이고 (-) 기울기를 이며, 선형적으로 변한다. 색 좌표 이동량은 Blue ${\rightarrow}$ Yellow, Red ${\rightarrow}$ Green형태이다. fading상태에서 색 좌표는 darkening 상태보다 $b^*$ 값이 낮고, Photochromism 좌표의 이동은 darkening 상태와 반대로 이동한다. Photochoromic lens에 대한 Photochoromism 평가 방법은 darkening과 fading에 대한 색 좌표 이동으로 이용 할 수 있다.

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A Study of Comparing Speech Act Data from Two Differing Data-gathering Instruments

  • Suh, Jae-Suk
    • 영어어문교육
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    • 제13권3호
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    • pp.77-97
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    • 2007
  • To compare data on the speech act of requests from two different methods, a study was conducted in which both native and non-native speakers of English participated as subjects, and data were collected by means of actual e-mail writing and DCT (discourse completion test). The analysis of requests from the two different data-gathering methods showed that despite some similarities, considerable differences existed between e-mail and DCT requests in several important aspects of requests such as amount of talk, directness level, downgraders and supportive moves which play an important role in making a given request sound less imposing and more polite. Also it was shown that requests of non-native speakers differed considerably from requests of native speakers in terms of the four aspects of requests across type of data-gathering methods. Based on the findings, some suggestions were made for both further research and L2 classrooms.

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합성 고분자물질 A611P를 첨가한 기액 2상 수직상향의 유동특성에 관한 실험적 연구 (Experimental study on the flow characteristic by the co-polymer A6l1P additive in gas-liquid two-phase vertical up flow)

  • 차경옥;김재근;양회준
    • 설비공학논문집
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    • 제10권4호
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    • pp.398-410
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    • 1998
  • Two-phase flow phenomena are observed in many industrial facilities and make much importance of optimum design for nuclear power plant and the liquid transportation system. The particular flow pattern depends on the conditions of pressure, flow velocity, and channel geometry. However, the research on drag reduction in two-phase flow is not intensively investigated. Therefore, experimental investigations have been carried out to analyze the drag reduction and void fraction by polymer addition in the two-phase flow system. We find that the polymer solution changes the characteristic of two-phase flow. The peak position of local void friction moves from tile wall of the pipe to the center of the pipe when polymer concentration increase. And then we predict that it is closely related with the frau reduction.

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영상기법을 이용한 수직상향 기포유동에 관한 연구 (A Study on the Vertical upward Bubble Flow using Image Processing Technique)

  • 서동표;오율권
    • Journal of Advanced Marine Engineering and Technology
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    • 제27권5호
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    • pp.617-623
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    • 2003
  • In the present study, the characteristics of upward bubble flow were experimentally investigated in a liquid bath. The velocity of upward bubble flow was calculated for two different experimental conditions:1) bubble flow without kinetic energy 2) bubble flow with kinetic energy. Bubble flow without kinetic energy starts to undergo the effect of buoyancy l0cm away from the nozzle. Whereas. kinetic energy is dominant before 30 cm away from the nozzle in bubble flow but after this point kinetic energy and inertial force are applied on bubble flow at the same time In addition, as the flow rate increases the maximum velocity point moves to the nozzle. The velocity Profiles near free surface is extremely irregular due to surface flow. Gas volume fraction is high near the nozzle due to gas concentration. but decreases with the increasement of axial position. Gas volume fraction does not vary after the axial position, z=60 in spite of the increasement of flow.

승합차의 램프 디자인과 제작을 위한 이종재료의 접합 (A Study on Welding of Dissimilar Materials for Van-Ramp Design and Production)

  • 이정현;김인철
    • 한국생산제조학회지
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    • 제20권4호
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    • pp.434-439
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    • 2011
  • There are about 2.4million disabled in Korea, 2009. Also, Korean society entered into an aging society. Therefore disable and elderly are getting more involved in our society. This study proposes simple ramp design for wheel chair users and welding method and condition for manufacturing. In the middle of ramp, screw jack and motor are installed so that ramp can be moved left and right side. To make the ramp moves easily, ramp was fixed by installing LM guide on both sides. Ramp production for using Nd:YAG laser certain dissimilar welding in stainless steel sheet and cold reduced carbon steel. The output was fixed by 3kW, the speed was increased to 2~7m/min, Argon was used as shielding gas and the flow rate was changed to 10~30L/min. The proper welding condition is the output 3kW and welding speed 2~5m/min.

가진주파수 이동현상을 이용한 저주파 가진기의 개발 (Development of n Low Frequency Vibration Shaker Using Force Frequency Shifting)

  • Lee, Gun-Myung;L.Koss;Lee, Jung-Soo
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2002년도 추계학술대회논문초록집
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    • pp.324.2-324
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    • 2002
  • If a sinusoidal excitation force moves back and forth along a structure with a certain frequency, the structure will be excited with the difference frequency of these two frequencies. A low frequency vibration shaker has been developed using this force frequency shifting without actually moving a shaker. The shaker consists of an ordinary eccentric mass shaker, a plate, constant springs, and time varying dampers. The dampers are fumed on and off in a sequential manner to simulate a traveling slide of an excitation force. (omitted)

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