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A Study on Cation Extraction and Impurity Separation in Slag (슬래그 내 양이온 추출 및 불순물 분리 연구)

  • Lee, Ye Hwan;Kang, Hyerin;Jang, Younghee;Lee, Si-Jin;Kim, Sung Su
    • Clean Technology
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    • v.25 no.4
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    • pp.311-315
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    • 2019
  • The cation extraction and impurity separation were studied in order to investigate the recyclability of a slag produced from the steel refinery industry. Two types of slag (Slag-A, B) were collected and characterized in this study. The initial characterization by X-ray diffraction (XRD) and X-ray fluorescence (XRF) confirmed the existence of various kinds of ions in the slag such as Ca2+ (30 ~ 40%), Fe3+ (20 ~ 30%), Si4+ (15%), Al3+ (10%), Mn2+ (7%), and Mg2+ (3 ~ 5%). Inductively coupled plasma atomic emission spectroscopy (ICP-AES) analysis on the extracted slag using 2 M HCl as a solvent indicated that a higher concentration of Ca2+ was extracted as the S/L ratio was increased. The Ca2+ extraction concentration were found to be 8,940 mg L-1 (Slag-A) and 10,690 (Slag-B) mg L-1 when the S/L ratio for Ca2+ extraction was 0.1. However, the extract was strongly acidic ( < pH 1) at 0.1 S/L. Also the other ions (impurities) were extracted simultaneously in addition to Ca2+. To increase the purity of Ca2+ in order to transform the slag to a high value resource, a pH-swing was conducted. The impurities tended to precipitate at higher rate as the pH was increased. Notably, the Ca2+ rapidly precipitated above a certain pH and at a pH of 10.5, while the selectivity of Ca2+ was over 99%. It is expected that the aqueous solution in which high contents of Ca2+ was selectively dissolved in this study would be suitable for the carbonation process for reducing CO2 and for the production of calcium carbonate.

Changes in Right Ventricular Volume, Volume Load, and Function Measured with Cardiac Computed Tomography over the Entire Time Course of Tetralogy of Fallot

  • Hyun Woo Goo
    • Korean Journal of Radiology
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    • v.20 no.6
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    • pp.956-966
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    • 2019
  • Objective: To characterize the changes in right ventricular (RV) volume, volume load, and function measured with cardiac computed tomography (CT) over the entire time course of tetralogy of Fallot (TOF). Materials and Methods: In 374 patients with TOF, the ventricular volume, ventricular function, and RV volume load were measured with cardiac CT preoperatively (stage 1), after palliative operation (stage 2), after total surgical repair (stage 3), or after pulmonary valve replacement (PVR) (stage 4). The CT-measured variables were compared among the four stages. After total surgical repair, the postoperative duration (POD) and the CT-measured variables were correlated with each other. In addition, the demographic and CT-measured variables in the early postoperative groups were compared with those in the late postoperative and the preoperative group. Results: Significantly different CT-based measures were found between stages 1 and 3 (indexed RV end-diastolic volume [EDV], 63.6 ± 15.2 mL/m2 vs. 147.0 ± 38.5 mL/m2 and indexed stroke volume (SV) difference, 7.7 ± 10.3 mL/m2 vs. 32.2 ± 16.4 mL/m2; p < 0.001), and between stages 2 and 3 (indexed RV EDV, 72.4 ± 19.7 mL/m2 vs. 147.0 ± 38.5 mL/m2 and indexed SV difference, 5.7 ± 13.1 mL/m2 vs. 32.2 ± 16.4 mL/m2; p < 0.001). After PVR, the effect of RV volume load (i.e., indexed SV difference) was reduced from 32.2 mL/m2 to 1.7 mL/m2. Positive (0.2 to 0.8) or negative (-0.2 to -0.4) correlations were found among the CT-based measures except between the RV ejection fraction (EF) and the RV volume load parameters. With increasing POD, an early rapid increase was followed by a slow increase and a plateau in the indexed ventricular volumes and the RV volume load parameters. Compared with the preoperative data, larger ventricular volumes and lower EFs were observed in the early postoperative period. Conclusion: Cardiac CT can be used to characterize RV volume, volume load, and function over the entire time course of TOF.

Comparative Analysis of Lighting Intensity, Leaf Temperature, Transpiration Rate, and Vapor Pressure Deficit between the Top and Branching Point of Stem during Growing Period of Paprika Plant (파프리카 생장에 따른 줄기의 정부와 하부 간 광량, 엽온, 증산속도 및 수증기압포차 비교 분석)

  • Seung Mi Woo;Ho Cheol Kim
    • The Journal of the Convergence on Culture Technology
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    • v.9 no.6
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    • pp.1097-1101
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    • 2023
  • As paprika plants grew in a glass greenhouse from November 2022 to March 2023, the amount of light at each plant height, leaf temperature, transpiration rate, and water vapor pressure were measured. Accumulated leaf temperature was higher at the top of the plant than at the bottom. Over time, the leaf temperature measured around 11-13 AM changed from 26.55→23.21→22.80→26.67℃ in the lower part (pL), and from 26.52→24.48→24.55→27.78℃ in the upper part (pAs). And VPD changed from 1.45→0.94→0.74→1.46kPa in pL and from 1.11→0.86→0.71→1.28kPa in pAs. Accordingly, the transpiration rate changed from 4.25→0.17→4.08→0.52mmol·m-2·s-1 in pL, 7.61→2.45→1.94→4.39→0.52mmol·m-2·s-1 in pAs, and from pAs to pL. It was significantly higher than The difference between the lower and upper parts (pL-pAs) was higher in pAs than pL in leaf temperature, light intensity, and transpiration rate, but the water vapor pressure difference was higher in pL. In this way, paprika shows differences in the environment and photosynthetic factors between the upper and lower parts during the cultivation period, so it is judged that this needs to be taken into consideration in future research.

Effect of pH on UV Photodegradation of N-Nitrosamines in Water (수용액상 니트로스아민의 UV 광분해에서 pH 영향)

  • Shim, Jae-Goo;Aqeel, Afzal;Choi, Bo-Mi;Lee, Jung-Hyun;Kwak, No-Sang;Lim, Ho-Jin
    • Journal of Korean Society on Water Environment
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    • v.32 no.4
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    • pp.357-366
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    • 2016
  • N-nitrosamines are a class of carcinogenic chemicals that can pose significant hazards to the human life. Ultraviolet (UV) light irradiation is considered as one of the effective methods to reduce N-nitrosamines in the aqueous phase. This study aimed to investigate the pH influence on UV photodegradation of N-nitrosamines (i.e., N-nitrosodibutylamine (NDBA) and N-nitrosopyrrolidine (NPYR)) closely related to water treatment. Photodegradation rate constants of NDBA and NPYR remained between 3.26×10-2 L/W-min to 5.08×10-3 L/W-min and 1.14×10-2 L/W-min to 2.80×10-3 L/W-min at pH2-10, respectively. This study also focused on the formation of oxidized products (i.e., primarily NO2- and NO3-). Under slightly acidic and neutral conditions, NO2- formation was more prevalent than NO3- formation, while under strong acidic conditions, NO3- was more prevalent. There was no significant change in total organic carbon (TOC) and total nitrogen (TN), suggesting negligible loss of N-nitrosamines and degradation products from the system. NDBA was easily photodegraded than NPYR. This study also demonstrated that a lower pH is a favorable condition for photolytic degradation of N-nitrosamines in water.

Phosphate solubilizing effect by two Burkholderia bacteria isolated from button mushroom bed (양송이배지로부터 분리한 두 Burkholderia 속 세균에 의한 인산가용화 효과)

  • Oh, Jong-Hoon;Kim, Young-Jun;Yoon, Min-Ho
    • Journal of Mushroom
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    • v.18 no.3
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    • pp.208-213
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    • 2020
  • Burkholderia contaminans PSB-A and Burkholderia ambifaria PSB-B were isolated from button mushroom bed to estimate their phosphate solubility. The phosphate-solubilizing abilities of these strains were assessed by measuring the phosphorus content in a single and co-inoculation medium for 7 days. The co-inoculation of these two strains released the highest content of soluble phosphorus (166.3 ㎍ mL-1) into the medium, followed by single inoculation of B. contaminans PSB-A (143.73 ㎍ mL-1) and B. ambifaria PSB-B (127.1 ㎍ mL-1). The highest pH reduction, organic acid production, and glucose consumption were also observed in the co-inoculation medium. According to the plant growth promotion bioassay, co-inoculation enhanced the growth of romaine lettuce much more than the single inoculation (20.4% for leaf widths and 16.6% for root lengths). Although no significant difference was noted between single and co-inoculation of bacterial strains in terms of phosphorous release and plant growth, co-inoculation of PSB may have a beneficial effect on crop growth due to a synergistic effect between the strains.

Effect of soil stabilizer on the bioavailability of arsenic in paddy soil (안정화제가 논토양 내 비소의 생물유효도에 미치는 영향)

  • Ji-Hyock Yoo;Hui-Seon Kim;Mi-jin Kim;Jung-Ok Woo;Ho-yang Choi;Sung-Chul Kim
    • Journal of Applied Biological Chemistry
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    • v.65 no.4
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    • pp.349-355
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    • 2022
  • In this study, we sought to identify a soil stabilizer that can be applied to paddy fields vulnerable to arsenic (As) pollution. To this end, we conducted a pot experiment in which we evaluated the effects of different stabilizers on the bioavailability of As in paddy soil. As candidate stabilizers, we assessed calcium superphosphate (CSP), sulfur, and steel slag, which were applied at the rates of 0.7 and 1.4, 0.1 and 0.2, and 7.0 and 14.0 Ma ha-1, respectively. On day 67 after rice transplantation, we detected significantly lower concentrations of As in the solutions of paddy soil treated with 1.4 Ma ha-1 CSP (96.9 ㎍ L-1) and 0.2 Ma ha-1 sulfur (207.2 ㎍ L-1) compared with the As concentrations in control (314.5 ㎍ L-1) and steel slag-treated (268.6-342.4 ㎍ L-1) soil. Compared with the As concentrations in control brown rice (0.16 mg kg-1), concentrations in brown rice were lowest in the pots treated with 1.4 Ma ha-1 CSP (0.09 mg kg-1). Furthermore, in response to CSP treatments, we detected increases in the weight of rice grains (50.0-50.4 g/pot) compared with the control (40.4 g/pot) and other treatments (26.9-48.1 g/pot), which we speculate could be attributed to the reduction in As toxicity to rice owing to a decline in soil solution As contents and the fertilization effect of the CSP treatment. Collectively, our findings indicate a high-level application of CSP (1.4 Ma ha-1) to paddy soil has a comparatively beneficial effect in mitigating the bioavailability of As.

Improvement of proliferation efficiency of strawberry 'Maehyang' treated by coconut water in tissue culture ('매향' 딸기의 조직배양 시 coconut water 처리에 따른 기내 증식효율 향상)

  • Kim, Hye Jin;Choi, Mi Ja;Lee, Jong Nam;Suh, Jong Taek;Kim, Ki Deog;Kim, Yul Ho;Hong, Su Young;Kim, Su Jeong;Sohn, Hwang Bae
    • Journal of Plant Biotechnology
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    • v.47 no.3
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    • pp.242-247
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    • 2020
  • This experiment was performed to determine the concentration of coconut water that is most effective in promoting the growth of 'Maehyang' strawberry in tissue culture. Cultivars in this experiment consisted of 'Maehyang' grown in the presence of 0, 20, 40, 60, 80, 100 ml·L-1 of coconut water which was added to a medium mixed with BA 0.5 mg·L-1 and IBA 0.1 mg·L-1. Morphological variation tests and SSR detection with coconut water were conducted to determine variations in proliferation. The proliferation rate of 'Maehyang' strawberry improved with the coconut water treatment compared to non-treatment. In particular, the proliferation rate with 100 ml·L-1 coconut water treatment increased by about 4 times. When 'Maeyang' was treated with 100 ml·L-1 of coconut water, two morphological variants occurred without genetic variation. Therefore, the results suggest that 100 ml·L-1 of coconut water can be used to mass-produce "Maeyang" strawberry without causing genetic variations.

Electrochemical Corrosion Damage Characteristics of Austenite Stainless Steel and Nickel Alloy with Various Seawater Concentrations (오스테나이트계 스테인리스강과 니켈합금의 해수 농도 변화에 따른 전기화학적 부식 손상 특성)

  • Heo, Ho-Seong;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.20 no.5
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    • pp.281-288
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    • 2021
  • Due to advancement of the industry, operation of a device in a harsh environment is increasing. Especially, the marine environment contains Cl- ions which causes localized corrosion such as pitting and crevice corrosion of stainless steel and various metals. In this study, electrochemical corrosion behaviors of austenitic stainless steel (STS 316L) and nickel alloy (Inconel 600) with different seawater concentrations (fresh water, seawater, mixed water) were investigated. The STS 316L and Inconel 600 were etched in 10% oxalic acid and composed of an austenitic phase. Results of Tafel analysis in seawater showed that STS 316L and Inconel 600 presented the highest corrosion current densities of 7.75 × 10-4 mA/cm2 and 1.11 × 10-4 mA/cm2 and the most negative pitting potentials of 0.94 V and 1.06 V, respectively. The maximum damage depths and surface damage ratio by pitting corrosion increased with chloride concentration. The STS 316L had higher PREN than Inconel 600. However, the surface damage and weight loss of Inconel 600 were superior to STS 316L. It was difficult to compare the pitting resistance of STS 316L based on Fe and Inconel 600 based on Ni with PREN simply.

Ammonium Excess Promotes Proline Synthesis but Inhibits Glutathione Synthesis in Oilseed Rape (Brassica napus L.)

  • Hyunjae Lee;Seon-Hye Baek;Tae-Hwan Kim
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.43 no.2
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    • pp.109-115
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    • 2023
  • Ammonium (NH4+) serves as a nitrogen source, but its elevated levels can hinder plant growth and production. Excess NH4+ with α-ketoglutarate is assimilated into glutamate, a precursor of proline and glutathione (GSH). This study aimed to investigate the effects of excessive NH4+ on the regulation of proline and GSH synthesis. Detached leaves from oilseed rape (Brassica napus L.) were fed with 0, 50, 100, 500, and 1000 mM NH4Cl for 16 h. As the NH4+ concentrations increased, the leaves exhibited progressive wilting and yellowing. Furthermore, total carotenoid and chlorophyll concentrations declined in response to all NH4+ treatments, with the lowest levels observed in 1000 mM NH4+ treatment. Hydrogen peroxide (H2O2) concentration showed a minor increase at low NH4+ concentration (50 and 100 mM) treatments but a significant increase at high NH4+ (500 and 1000 mM), which was consistent with the localization of H2O2. Amino acid concentrations increased with increasing in NH4+ concentration, while the protein concentration displayed the opposite trend. Proline and cysteine concentrations exhibited a gradual increase in response to increasing NH4+ concentrations. However, GSH concentrations rose only in the 50 mM NH4+ treatment and decreased in the 500 and 1000 mM NH4+ treatments. These results indicate that excessive NH4+ is primarily assimilated into proline, while GSH synthesis is adversely affected.

Desalinization Effect of Pennisetum Alopecuroides and Characteristics of Leachate Depending on Calcium Chloride (CaCl2) Concentration

  • Yang, Ji;Yoon, Yong-Han;Ju, Jin-Hee
    • Journal of People, Plants, and Environment
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    • v.23 no.4
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    • pp.445-453
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    • 2020
  • Background and objective: Calcium chloride (CaCl2) and sodium chloride (NaCl) are commonly used as a deicing agent in South Korea and penetrate the soil on the roadside, causing damage to plants. This study was conducted to investigate the salinity reduction effect of Pennisetum alopecuroides and the chemical characteristics of soil leachate. Methods: The plants were treated with five different concentrations of CaCl2 (0, 1, 2, 5, and 10g·L-1) and were grouped into the Cont., C1, C2, C5, and C10 groups. CaCl2 of 200 m·L-1 was sprayed to each plant once every two weeks. The growth of P. alopecuroides (plant height, leaf length, leaf width and the number of leaves) was measured. The level of EC and pH, and exchangeable cations (K+, Ca2+, Na+, and Mg2+) in the leachate of soil was monitored. Results: The pH of soil leachate decreased as the CaCl2 concentration increased, and the EC increased significantly. The content of K+ did not change significantly until the concentration of CaCl2 reached 5 g·L-1, but the content of Ca2+, Na+, and Mg2+ significantly increased. The plant height, leaf length, and leaf width of P. alopecuroides showed the highest value in CaCl2 1 g·L-1 followed by CaCl2 2 g·L-1 and the control group. Root fresh weight was the highest in CaCl2 2 g·L-1. On the other hand, there was no change in the shoot fresh weight, dry weight and root dry weight, and P. alopecuroides growth inhibition at the concentration of 5 g·L-1 or higher in the plant height and leaf length. Conclusion: P. alopecuroides is relatively highly salt-tolerant and can improve the salt damaged soil by lowering the content of the salt-based exchangeable K+ ions.