• Title/Summary/Keyword: Korean liquid

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Synthesis and Mesomorphic Properties of New Achiral Liquid Crystals with 3-Alkoxy-2-(alkoxymethyl)-1-propoxy Swallow-Tails

  • Kang, Kyung-Tae;Kim, Jeong-Tak;Hwang, Ryeo-Yun;Park, Song-Ju;Lee, Seng-Kue;Lee, Jong-Gun;Kim, Yong-Bae
    • Bulletin of the Korean Chemical Society
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    • v.28 no.11
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    • pp.1939-1944
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    • 2007
  • New liquid crystalline (biphenylcarbonyloxy)benzoates with an achiral swallow-tail derived from 3-alkoxy-2- (alkoxymethyl)-1-propanol [(ROCH2)2CHCH2OH, R = Me, Et, Pr, Bu] were prepared. These liquid crystals exhibited the phase sequence (I-SmA-SmCalt-(SmCX)-Cr) and showed antiferroelectric-like Smectic C phase (SmCalt) at temperature lower, and temperature range broader than do the compounds containing a branched alkyl group as a swallow-tail. The temperature ranges of antiferroelectric phase were found to be 30-90 oC and crystallization temperatures were 4-60 oC. The binary mixture of an achiral swallow-tailed liquid crystal and a chiral antiferroelectric liquid crystal, (S)-MHPOBC showed antiferroelectric smectic C phase at temperature much lower than the single chiral antiferroelectric liquid crystal does.

Thermal and Electro-Optic Properties of a Side Chain Liquid Crystalline Polysilozanes cotaining a Low Molecuar Weight LIquid Crystal

  • Lee, Tae-Jeong;Kim, Eun-Yeong;Huh, Jae-Ho;Wang, Young-Soo;Kim, Han-Do
    • Proceedings of the Korean Fiber Society Conference
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    • 1997.10a
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    • pp.32-35
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    • 1997
  • Aggregation states ans electro-optic properties of a binary mixture by mixing a side chain type liquid crystalline polymer(LCP) and a low molecular weight liquid crystal(LMLC) have been studied. Side chain liquid crystalline polysiloxanes were synthesized from allyl bromide, p-hydroxy benzoic acid, p-cyanophenol, p-methoxyphenol and polysiloxanes. Low molecular weight liquid crystals were synthesized from allyl bromide, p-hydroxy benzoic acid and 4-cyano 4'-hydroxy biphenyl. And then, their properties were compared with blended liquid crystals. The thermal properties of the blended liquid crystals were evaluated using differential scanning calorimetry. The phase behavior of blended sample with temperature were also observed polarized microscope with hot stage. Thus, it seemed to us that a study of LC polysiloxanes with LMLC would be useful, especially in view of the fact that, systematic investigations have been carried out on the effects of changes in LCP/LMLC binary system on the properties of this relatively new type of liquid crystal.

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Analysis on the Economic Valuation of Semi-Liquid Manure for Cooperative Tank (가축분뇨공동이용을 위한 액비의 경제적 가치분석)

  • Yoo, Duck-Ki
    • Korean Journal of Organic Agriculture
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    • v.13 no.2
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    • pp.129-143
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    • 2005
  • Attempting to make an economic valuation of semi-liquid manure raises various complex questions. These are the valuation under different farming conditions, cost-benefit analysis in connection with the investment requirements of different semi-liquid manure systems, different storage capacities, transportation distances and treatment procedures. In the following, there questions will be discussed : 1. What value do the different types of semi-liquid manure have under different farming conditions? 2. Which storage capacities are economically justified? 3. Under which conditions is the transport of semi-liquid manure over long distances profitable?

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A Study on Curing Behaviors and Structures of Chiral Liquid Crystal-Polymer composite films (키랄네마틱액정-고분자 복합막의 경화거동과 내부구조에 관한 연구)

  • 남수용;김종원;김용욱
    • Journal of the Korean Graphic Arts Communication Society
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    • v.16 no.3
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    • pp.15-27
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    • 1998
  • Several aspects of polymer dispersed liquid crystal(PDLC) film properties make them interesting for display application. Most versions of PDLC materials are able to modulate light without the use of polarizers, which offers advantages in optical throughput(brightness) and viewing angle compared to polarizer-based display. In this papers, we attemped to doe minimum of remaining liquid crystals at polymer network for the liquid crystal-polymer composite (LCPC) films. In results, best phase separation behaviors turned out liquid crystal/monomer/oligomer mixture system.

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Thermal Inspection of GFRP using Liquid Crystal (액정을 이용한 GFRP의 열적시험법에 관한 연구)

  • Kim, Y.H.;Kwon, O.Y.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.10 no.2
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    • pp.50-55
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    • 1990
  • Flaws in GFRP(Glass Fiber Reinforced Plastics) were thermally detected using cholesteric liquid crystals. Presence of flaws changes the thermal conductivity of GFRP, and disturbs heat flow. When a uniform heat source is applied, the surface temperature of flawed region is different from that of sound region. The surface temperature distributions were measured by thermo-optic properties of liquid crystal. Since the colors of liquid crystal indicate temperature distribution of GFRP surface, the thermal disturbance by flaws could be detected. The locations of flaws in GFRP could be determined from the distribution of liquid crystal colors.

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A Calculation for the Viscosity of Liquid Metals

  • Kim, Won-Soo;Chair, Tong-Seek
    • Bulletin of the Korean Chemical Society
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    • v.11 no.5
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    • pp.446-449
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    • 1990
  • A phenomenological theory of viscosity which has been proposed by authors is applied to liquid metals for which the calculation is a severe test for liquid theories. The thermodynamic properties used in the calculations can be obtained by using the Roulette liquid theory. The calculated values of the viscosities for liquid metals are in good agreements with the observed values.

Developing 500 MHz NB 19F-13C Double Resonance Solid-State NMR Probe for in-situ Analysis of Liquid Crystal Display Panels

  • Choi, Sung-Sub;Jung, Ji-Ho;Park, Yu-Geun;Park, Tae-Joon;Park, Gregory Hyung-Jin;Kim, Yong-Ae
    • Bulletin of the Korean Chemical Society
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    • v.33 no.5
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    • pp.1577-1580
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    • 2012
  • The orientational and dynamic behavior of liquid crystal molecules on the alignment layer surfaces of liquid crystal display (LCD) devices is crucial to their performance, but there are only a few methods of experimentally elucidating the interactions between the liquid crystals and the alignment layers. Inspired by the natural and technical similarities between membrane proteins in lipid bilayers and liquid crystals in LCDs, we employed solid-state NMR methodologies originally developed for the study of membrane proteins in lipid bilayers for the in-situ analysis of liquid crystal display panels. In this article, we present a home-built 500 MHz narrowbore (NB) The orientational and dynamic behavior of liquid crystal molecules on the alignment layer surfaces of liquid crystal display (LCD) devices is crucial to their performance, but there are only a few methods of experimentally elucidating the interactions between the liquid crystals and the alignment layers. Inspired by the natural and technical similarities between membrane proteins in lipid bilayers and liquid crystals in LCDs, we employed solid-state NMR methodologies originally developed for the study of membrane proteins in lipid bilayers for the in-situ analysis of liquid crystal display panels. In this article, we present a home-built 500 MHz narrowbore (NB) $^{19}F-^{13}C$ double resonance solid-state NMR probe with a flat-square coil and the first application of this probe for the in-situ analysis of LCD panel samples. double resonance solid-state NMR probe with a flat-square coil and the first application of this probe for the in-situ analysis of LCD panel samples.

Liquid-Liquid Extraction for Recovery of Paclitaxel from Plant Cell Cultures by Adding Inorganic Salts (식물세포배양으로부터 파클리탁셀 회수를 위한 무기염이 첨가된 액-액 추출)

  • Ha, Geon-Soo;Kim, Jin-Hyun
    • Korean Chemical Engineering Research
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    • v.54 no.1
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    • pp.135-139
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    • 2016
  • We developed a liquid-liquid extraction method using an inorganic salt to dramatically improve the recovery efficiency of the anticancer agent paclitaxel from plant cell cultures. As a result of liquid-liquid extraction using a diverse types of inorganic salt (NaCl, KCl, $K_2HPO_4$, $NaH_2PO_4$, $NaH_2PO_4{\cdot}2H_2O$), NaCl gave the highest yield (~96%) and lowest partition coefficient (0.053) of paclitaxel. The optimal NaCl/solvent ratio, methylene chloride/MeOH ratio, and pure paclitaxel content for liquid-liquid extraction using NaCl were 1% (w/v), 26% (v/v), and 0.066% (w/v), respectively. Under the optimal conditions developed in the present method, most of the paclitaxel (~96%) was recovered from biomass by a single extraction step. In addition, this method facilitated 3-fold higher recovery efficiency of paclitaxel in a shorter extraction number than the conventional liquid-liquid extraction method.

Persistence of Salmonella enterica, Escherichia coli O157:H7, and Listeria monocytogenes in Soil, Liquid Manure Amended Soil, and Liquid Manure

  • Jung, Kyu-Seok;Kim, Min-Ha;Heu, Sung-Gi;Roh, Eun-Jung;Lee, Dong-Hwan;Lim, Jeong-A;Ryu, Jae-Gee;Kim, Kye-Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.47 no.6
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    • pp.432-436
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    • 2014
  • While searching for healthier diets, people became more attentive to agricultural organic products. However, organic foods may be more susceptible to microbiological contamination because of the use of livestock manure compost and liquid manure, potential sources of pathogenic bacteria. This study was undertaken to investigate the persistence of Salmonella enterica, Escherichia coli O157:H7, and Listeria monocytogenes in soil, liquid manure amended soil, and liquid manure. Loamy soil, liquid manure amended soil, and liquid manure were inoculated with S. enterica, E. coli O157:H7, and L. monocytogenes. Samples were incubated in consistent moisture content at $25^{\circ}C$. Samples had been periodically collected during 120 days depending on the given conditions. S. enterica and E. coli O157:H7 survived over 120 days in loamy soil and over 60 days in liquid manure amended soil, respectively. L. monocytogenes decreased faster than other pathogens in soil. S. enterica, E. coli O157:H7, and L. monocytogenes survived for up to 5 days in liquid manure. S. enterica and E. coli O157:H7 in soil decreased by 2 to $2.5log\;CFU\;g^{-1}$ for 120 days. S. enterica and E. coli O157:H7 in liquid manure amended soil decreased slowly for 21 days. However, S. enterica, E. coli O157:H7, and L. monocytogenes sharply decreased after 21 days. S. enterica, E. coli O157:H7, and L. monocytogenes in soil increased by 0.5 to $1.0log\;CFU\;g^{-1}$ for 7 days. Foodborne pathogens in soil and liquid manure amended soil gradually decreased over time.