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Platinum Nano-Dispersion via In Situ Processing - Preparation and catalytic Property of Porous $CaZrO_3/MgO/Pt$ Nanocomposite

  • Yoshikazu;Hwang, Hae-Jin;Naoki Kondo;Tatsuki Ohji
    • Journal of Powder Materials
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    • v.8 no.3
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    • pp.163-167
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    • 2001
  • A bulk porous $CaZrO_3/MgO$ composite with plantinum nano-dispersion was synthesized in air atmosphere through the combination of several in situ reactions, including the pyrolysis of $PtO_2$. A mixture of $CaMg(CO_3)_2$(dolomite), $ZrO_2$, $PtO_2$ and LiF (0.5 wt%, as an additive) was cold isostatically pressed at 200 MPa and sintered at $1100^{\circ}C$ for 2 h. The porous $CaZrO_3/MgO/Pt$ composite ($CaZrO_3/MgO$ : Pt=99 : 1 in volume) had a uniformly open-porous structure (porosity: 56%) with three-dimensional (3-D) network and a narrow pore-size distribution, similarly to the porous $CaZrO_3/MgO$ composites reported before. Catalytic Properties (viz., NO direct decomposition and NO reduction by $C_2H_4$) of the $CaZrO_3/MgO/Pt$ composite were investigated up to $900^{\circ}C$. In the absence of oxygen, the NO conversion rate reached ~52% for the direct decomposition and ~100% for the reduction by $C_2H_4$, respectively. The results suggest the possibility of the porous composite as a multifunctional filter, i.e., simultaneous hot gas-filtering and $de-NO_x$ in one component.

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Round-trip system dedicated to the Korea VLBI system for geodesy (KVG) (한국 측지 VLBI 시스템을 위한 라운드 Trip 시스템)

  • O, Hong-Jong;Kondo, Tetsuro;Kim, Du-Hwan;Lee, Jin-U;Kim, Myeong-Ho;Kim, Su-Cheol;Park, Jin-Sik;Ju, Hyeon-Hui
    • Proceedings of the Korean Society of Surveying, Geodesy, Photogrammetry, and Cartography Conference
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    • 2010.04a
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    • pp.201-206
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    • 2010
  • A project for construction of Korea Geodetic VLBI has officially started in Oct. 2008. The construction of all system will be completed by the end of 2011. The project was named Korea VLBI system for Geodesy (KVG), and its main purpose is to maintain the Korea Geodetic Datum. In case of the KVG system, an observation room where an H-maser frequency standard is located is in a building separated from an antenna by several tens of meters. Therefore KVG system will adopt a so-called round-trip system to transmit reference signals to the antenna with diminishing the effect of path length variations. KVG's round-trip system is designed not only available to use either metal or optical fiber cables, but also available to measure path length variations directly by using K5/VSSP32 sampler. We will present principle of round-trip system and the new type of round trip system for KVG.

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Successful onco-testicular sperm extraction from a testicular cancer patient with a single testis and azoospermia

  • Kuroda, Shinnosuke;Kondo, Takuya;Mori, Kohei;Yasuda, Kengo;Asai, Takuo;Sanjo, Hiroyuki;Yakanaka, Hiroyuki;Takeshima, Teppei;Kawahara, Takashi;Kato, Yoshitake;Miyoshi, Yasuhide;Uemura, Hiroji;Iwasaki, Akira;Yumura, Yasushi
    • Clinical and Experimental Reproductive Medicine
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    • v.45 no.1
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    • pp.44-47
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    • 2018
  • Onco-testicular sperm extraction is used to preserve fertility in patients with bilateral testicular tumors and azoospermia. We report the case of a testicular tumor in the solitary testis of a patient who had previously undergone successful contralateral orchiectomy and whose sperm was preserved by onco-testicular sperm extraction. A 35-year-old patient presented with swelling of his right scrotum that had lasted for 1 month. His medical history included a contralateral orchiectomy during childhood. Ultrasonography revealed a mosaic echoic area in his scrotum, suggesting a testicular tumor. The lesion was palpated within the normal testicular tissue along its edge and semen analysis showed azoospermia. Radical inguinal orchiectomy and onco-testicular sperm extraction were performed simultaneously. Motile spermatozoa were extracted from normal seminiferous tubules under microscopy and were frozen. Eventual intracytoplasmic sperm injection using the frozen spermatozoa is planned. Onco-testicular sperm extraction is an important fertility preservation method in patients with bilateral testicular tumors or a history of a previous contralateral orchiectomy.

Seasonal Variations of the Zodiacal Light toward the Ecliptic Poles at the Infrared Wavelengths

  • Pyo, Jeonghyun;Kim, Il-Joong;Jeong, Woong-Seob;Lee, Dae-Hee;Moon, Bongkon;Park, Youngsik;Park, Sung-Joon;Park, Won-Kee;Lee, Duk-Hang;Nam, Uk-Won;Han, Wonyong;Seon, Kwang-Il;Matsumoto, Toshio;Kim, Min Gyu;Lee, Hyung Mok
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.47.3-48
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    • 2016
  • The zodiacal light (ZL), combination of the sunlight scattered by and the infrared light emitted by the interplanetary dust (IPD) particles, changes with time due to the asymmetric distribution of the particles with respect to the Earth's orbit. Especially, the variation of the ZL brightness toward the ecliptic poles are useful to probe the properties of the global distribution of the IPD because we can evade the effect of the small scale structures, such as the asteroidal dust bands. The ecliptic poles are frequently visited by the infrared (IR) space telescopes owing to their sun-synchronous orbits or for specific purposes. We collect and analyze the observations toward the ecliptic poles by COBE/DIRBE, AKARI, and MIRIS, covering the wavelengths from about 1 to $25{\mu}m$. The observed seasonal variations of the ZL are modeled with a simple IPD cloud model to derive cloud parameters. The parameters are compared with those of the empirical cloud models by Kelsall et al. (1998) and Kondo et al. (2016), and the discrepancies are discussed.

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Measurement of Gamma-ray Yield from Thick Carbon Target Irradiated by 5 and 9 MeV Deuterons

  • Araki, Shouhei;Kondo, Kazuhiro;Kin, Tadahiro;Watanabe, Yukinobu;Shigyo, Nobuhiro;Sagara, Kenshi
    • Journal of Radiation Protection and Research
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    • v.42 no.1
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    • pp.16-20
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    • 2017
  • Background: The design of deuteron accelerator neutron source facilities requires reliable yield estimation of gamma-rays as well as neutrons from deuteron-induced reactions. We have so foar measured systematically double-differential thick target neutron yields (DDTTNYs) for carbon, aluminum, titanium, copper, niobium, and SUS304 targets. In the neutron data analysis, the events of gamma-rays taken simultaneously were treated as backgrounds. In the present work, we have re-analyzed the experimental data for a thick carbon target with particular attention to gamma-ray events. Materials and Methods: Double-differential thick target gamma-ray yields from carbon irradiated by 5 and 9 MeV deuterons were measured using an NE213 liquid organic scintillator at the Kyushu University Tandem accelerator Laboratory. The gamma-ray energy spectra were obtained by an unfolding method using FORIST code. The response functions of the NE213 detector were calculated by EGS5 incorporated in PHITS code. Results and Discussion: The measured gamma-ray spectra show some pronounced peaks corresponding to gamma-ray transitions between discrete levels in residual nuclei, and the measured angular distributions are almost isotropic for both the incident energies. Conclusion: PHITS calculations using INCL, GEM, and EBITEM models reproduce the spectral shapes and the angular distributions generally well, although they underestimate the absolute gamma-ray yields by about 20%.

COMBUSTION CHARACTERISTICS OF A MICRO-SOLID PROPELLANT ROCKET ARRAY THRUSTER

  • Kazuyuki Kondo;Shuji Tanaka;Hiroto Habu;Tokudome, Shin-ichiro;Keiichi Hori;Hirobumi Saito;Akihito Itoh;Masashi Watanabe;Masayoshi Esashi
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.593-596
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    • 2004
  • We are developing a micro-solid propellant rocket array thruster for simple attitude control of a 10 kg class micro-spacecraft. The prototype has ø 0.8 mm solid propellant micro-rockets arrayed at a pitch of 1.2 mm on a 22 x 22 mm substrate. In previous studies, an impulse thrust of 4.6 x 10$^{-4}$ Ns was obtained in vacuum, but we found the problems of unacceptably low ignition success rate and incomplete combustion. This paper describes experiments to improve the ignition rate. In order to achieve this goal, we tried to solidify paste-like ignition aid (RK) on the ignition heaters with strong adhesion. To make the paste-like RK, isoamyl acetate was added to RK powder. We tested 9 rockets, but only 2 rockets were ignited with huge ignition energy. This is because the heat con-duction between the ignition heater and the RK was too low to ignite the RK, since dried RK had a lot of pores. Also, a large cavity was sometimes found just above the ignition heater.

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Robustness Examination of Tracking Performance in the Presence of Ionospheric Scintillation Using Software GPS/SBAS Receiver

  • Kondo, Shun-Ichiro;Kubo, Nobuaki;Yasuda, Akio
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • v.2
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    • pp.235-240
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    • 2006
  • Ionospheric scintillation induces a rapid change in the amplitude and phase of radio wave signals. This is due to irregularities of electron density in the F-region of the ionosphere. It reduces the accuracy of both pseudorange and carrier phase measurements in GPS/satellite based Augmentation system (SBAS) receivers, and can cause loss of lock on the satellite signal. Scintillation is not as strong at mid-latitude regions such that positioning is not affected as much. Severe effects of scintillation occur mainly in a band approximately 20 degrees on either side of the magnetic equator and sometimes in the polar and auroral regions. Most scintillation occurs for a few hours after sunset during the peak years of the solar cycle. This paper focuses on estimation of the effects of ionospheric scintillation on GPS and SBAS signals using a software receiver. Software receivers have the advantage of flexibility over conventional receivers in examining performance. PC based receivers are especially effective in studying errors such as multipath and ionospheric scintillation. This is because it is possible to analyze IF signal data stored in host PC by the various processing algorithms. A L1 C/A software GPS receiver was developed consisting of a RF front-end module and a signal processing program on the PC. The RF front-end module consists of a down converter and a general purpose device for acquiring data. The signal processing program written in MATLAB implements signal acquisition, tracking, and pseudorange measurements. The receiver achieves standalone positioning with accuracy between 5 and 10 meters in 2drms. Typical phase locked loop (PLL) designs of GPS/SBAS receivers enable them to handle moderate amounts of scintillation. So the effects of ionospheric scintillation was estimated on the performance of GPS L1 C/A and SBAS receivers in terms of degradation of PLL accuracy considering the effect of various noise sources such as thermal noise jitter, ionospheric phase jitter and dynamic stress error.

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heat Budget over the South-Western Part of the Japan Sea in the Month of January and Cold Water Mass in the Korea Strait (1월의 동해 남서해역에서의 열수지와 대한해협의 냉수괴)

  • Han, Young Ho
    • 한국해양학회지
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    • v.7 no.1
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    • pp.19-23
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    • 1972
  • Based on the data collected during January of 1963, 1964 and 1965, heat transfer from the sea to the air over the south-western part of the Japan Sea was evaluated by the formula of Jacobs. The mean sensible heat transfer and the rate of evaporation in the mild winter of 1964 were 360ly day$\^$-1/ and 8.1mm day$\^$-1/, respectively. However, these values increased as much as 690ly day$\^$-1/ and 14.4mm day$\^$-1/ in the severe winter of 1963. The heat hudget of the Japan Sea in January were related to the magnitude of cold water mass formed in August in the Korea Strait.

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The distribution and population status of Quercus myrsinifolia (Fagaceae) on the Korean peninsula (한반도 가시나무(참나무과)의 분포 및 자생지 현황)

  • Lee, Jung-Hyun;Lee, Dong-Hyuk;Choi, Hyeok-Jae;Suyama, Yoshihisa;Kondo, Toshiaki;Isagi, Yuji;Choi, Byoung-Hee
    • Korean Journal of Plant Taxonomy
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    • v.44 no.3
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    • pp.165-170
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    • 2014
  • Most evergreen Quercus species are typical, dominant members of Korean evergreen forests. However, little is known about the distribution status of Q. myrsinifolia Blume there. To enhance our knowledge about their natural range in Korea, we conducted field surveys based on specimen records and an extensive literature search. We also determined their exact number as a first step in planning their conservation. The results indicated that these trees are strictly limited to Jin Island, and 169 mature individuals were the maximum number and occurred in only three subpopulations on that island. Previous misidentifications and perhaps mislabeled locations for plant specimens were the main reasons for earlier confusion about distribution. We believe that these results can provide guidance when making specific recommendations for management interventions. These discoveries also demonstrate the value in having reliable information about plant specimens in general. We also speculated about what makes this species particularly vulnerable to local extinction.

Plasma Etching Process based on Real-time Monitoring of Radical Density and Substrate Temperature

  • Takeda, K.;Fukunaga, Y.;Tsutsumi, T.;Ishikawa, K.;Kondo, H.;Sekine, M.;Hori, M.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.93-93
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    • 2016
  • Large scale integrated circuits (LSIs) has been improved by the shrinkage of the circuit dimensions. The smaller chip sizes and increase in circuit density require the miniaturization of the line-width and space between metal interconnections. Therefore, an extreme precise control of the critical dimension and pattern profile is necessary to fabricate next generation nano-electronics devices. The pattern profile control of plasma etching with an accuracy of sub-nanometer must be achieved. To realize the etching process which achieves the problem, understanding of the etching mechanism and precise control of the process based on the real-time monitoring of internal plasma parameters such as etching species density, surface temperature of substrate, etc. are very important. For instance, it is known that the etched profiles of organic low dielectric (low-k) films are sensitive to the substrate temperature and density ratio of H and N atoms in the H2/N2 plasma [1]. In this study, we introduced a feedback control of actual substrate temperature and radical density ratio monitored in real time. And then the dependence of etch rates and profiles of organic films have been evaluated based on the substrate temperatures. In this study, organic low-k films were etched by a dual frequency capacitively coupled plasma employing the mixture of H2/N2 gases. A 100-MHz power was supplied to an upper electrode for plasma generation. The Si substrate was electrostatically chucked to a lower electrode biased by supplying a 2-MHz power. To investigate the effects of H and N radical on the etching profile of organic low-k films, absolute H and N atom densities were measured by vacuum ultraviolet absorption spectroscopy [2]. Moreover, using the optical fiber-type low-coherence interferometer [3], substrate temperature has been measured in real time during etching process. From the measurement results, the temperature raised rapidly just after plasma ignition and was gradually saturated. The temporal change of substrate temperature is a crucial issue to control of surface reactions of reactive species. Therefore, by the intervals of on-off of the plasma discharge, the substrate temperature was maintained within ${\pm}1.5^{\circ}C$ from the set value. As a result, the temperatures were kept within $3^{\circ}C$ during the etching process. Then, we etched organic films with line-and-space pattern using this system. The cross-sections of the organic films etched for 50 s with the substrate temperatures at $20^{\circ}C$ and $100^{\circ}C$ were observed by SEM. From the results, they were different in the sidewall profile. It suggests that the reactions on the sidewalls changed according to the substrate temperature. The precise substrate temperature control method with real-time temperature monitoring and intermittent plasma generation was suggested to contribute on realization of fine pattern etching.

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