• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 추계학술대회 논문집
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• pp.475-478
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• 1999

The thermal properties of epoxy resin/siloxane for the electrical insulation were investigated by using dynamic DSC run method. As the heating rate increased, the peak temperature on dynamic DSC curve increased. From the linear relation on the Kissinger plot the curing reaction activation energy and pre-exponential factor could be obtained. The curing activation energy from the straight line of the Kissinger plot was 46.72 kJ/mol.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제51권10호
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• pp.473-478
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• 2002

Accelerated thermal aging conditions of polymeric materials were studied by Kissinger equation with TGA analysis. The activation energy was obtained from the slope of straight line of each specimen at the different TGA heating rate. Estimating activation energy from Kissinger equation was acquired, and the resulting calculation showed that 3.59, 3.0, 3.86, 3.73 for the PEEK, polyimide, polysulfone and Viton, respectively. The studied polymeric specimens are used for electrical penetration assembly in nuclear power plant. Accelerated aging time and temperature were also determined corresponding to actual service temperature and 41 years.

• 한국환경과학회:학술대회논문집
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• 한국환경과학회 2008년도 추계학술발표회 발표논문집
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• pp.488-490
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• 2008

등온 및 비등온 TGA 열분석을 이용하여 TTSP를 이용하여 실험적으로 Shift factor(Acceleration factor) ${\alpha}_T$를 구하고 이로부터 마스터 커브 (master curve)를 도출할 수 있었고, 실험에 사용된 개질된 NR고무재료는 Arrhenius식을 잘 따르는 것이 확인되었으며, 이로부터 TTSP에 의한 촉진시험 결과의 신빙성을 확인할 수 있었다. 한편, 등온 TGA 실험으로부터 얻은 활성화에너지는 37.70 kJ/mol인 반면, 비등온 TGA로부터 Kissinger plot에 의해 얻은 활성화에너지는 166.20 kJ/mol이었는데, 이는 저온과 고온에서 서로 다른 분해기구에 의해 중량 감소가 일어나기 때문인 것으로 생각 되었다.

• The Korean Journal of Ceramics
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• 제5권4호
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• pp.375-378
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• 1999

In tho XRD study of $56ZrF_4 \cdot34BaF_2 \cdot4AIF_3 \cdot(6-x)LaF_3 \cdotxLnF_3$ glassdLn=Ce, Nd, Gd, Th), halo pattern charactarktic fo an amorphous sample appeared. When the halo peak angle ($\theta_p$) was converted into a wavenumber with $Qp=4\pi sinG\pi/\lambda(\lambda$ is the wavolongth of the radialion used), it was found that the Qp values varied almost liuearly with the concentration 01 $LnF_3$. The emissiou spect1.a of $Ce^{3-}$-containing fluoride glasses nnder 273 nm excitation had a peak maximum at ea. 300 nm $(Ce^{3+}$ 5d-4f- transition). The maximal intensity of the fluorescence was observed when the $CeF_3$, content was extremely low (ca. 1 mol%j. DTA measurement revealed tbat these fluoride glasses had two crystallization temperatures. In $56ZrF_4. 34BaF_2. 4NF_3. (6-x)LaF_3 .xNdF_3$ glasses, the actmation energies of crystallization obtained from a Kssinger plot were 1.7 and 5.0 eV for the glass with x=2, and 1.9 and 5.6 eV for the glass with x=4.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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• pp.548-551
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• 1999

The cure characteristics of metal particle filled DGEBA/MDA/SN/ zeolite epoxy resin composite system for EMI shielding were investigated by dynamic DSC run method and FT-lR spectroscopy. As the heating rate increased, the peak temperature on dynamic DSC curve increased because of the rapid cure reaction. From the straight line of the Kissinger plot, the curing reaction activation energy and pre-exponential factor could be obtained. As the post-curing time at 15$0^{\circ}C$ increased, the glass increased the glass transition temperature or the thermal stability increased. When the post curing time is too long, the system filled with metallic Al particle can be thermally oxidized by the catalytic reaction of metal filler and the thermal stability of the composite for the EMI shielding application may be decreased.

• Elastomers and Composites
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• 제43권1호
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• pp.18-24
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• 2008

사슬연장제로 사용되는 디올형 올리고머를 상온주형용의 폴리우레탄(PU) 엘라스토머의 반응 및 물성조절제로 사용하였다. 기본 수지에 대해 one-shot 방식으로 혼합된 디올형 올리고머는 반응속도 지연효과를 나타내었으며 혼합 농도가 증가함에 따라 지수적으로 반응속도가 감소하는 현상을 나타내었다. Kissinger의 열분석에 관한 연구 결과는 본 연구에서의 해석에서 도 ln $(q/T^2_p)$ vs. $(1/T_p)$ 플롯이 직선성을 보이고 계산된 활성화에너지 $E_a$값이 44.80 kJ/mol로서 일반적인 주형용 폴리우레탄 생성반응에서의 활성화에너지와 유사한 값을 보임으로서 매우 유효하게 적용될 수 있었다. 기계적인 성질에 있어서도 약 20 phr 정도에 이르기까지의 조절제 농도에서는 뚜렷한 강도의 저하가 이루어지고 그 이후에는 점차적으로 낮아지는 것으로 관찰되었으며, 조절제가 약 20 phr 이상 혼입되는 경우에는 항복점의 구분이 매우 약화되고 고무탄성체의 특징인 저강도 고신율의 거동을 보이는 특징적인 현상이 관찰되었다. 또한 파단강도의 경우 조절제의 함량이 증가할수록 지수적으로 강도가 감소하는 경향을 나타내어 조절제의 혼합 농도조건에 따라 강도변화가 매우 민감함을 보여 주었다.

• 한국분말재료학회지
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• 제26권2호
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• pp.107-111
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• 2019

The activation energy to create a phase transformation or for the reaction to move to the next stage in the milling process can be calculated from the slop of the DSC plot, obtained at the various heating rates for mechanically activated Al-Ni alloy systems by using Kissinger's equation. The mechanically activated material has been called "the driven material" as it creates new phases or intermetallic compounds of AlNi in Al-Ni alloy systems. The reaction time for phase transformation by milling can be calculated using the activation energy obtained from the above mentioned method and from the real required energy. The real required energy (activation energy) could be calculated by subtracting the loss energy from the total input energy (calculated input energy from electric motor). The loss energy and real required energy divided by the reaction time are considered the "metabolic energy" and "the effective input energy", respectively. The milling time for phase transformation at other Al-Co alloy systems from the calculated data of Al-Ni systems can be predicted accordingly.

• 한국결정성장학회지
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• 제2권2호
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• pp.20-32
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• 1992

$Na_2O-CaO-MgO-Al_2O_3-SiO_2$계를 기본조성으로 하여 $Na_2O$에 $Li_2O 0.05wt%, $K_2O$를, CaO에 MgO 12.0wt%, ZnO 6.0%를 각각 치환하여 조성을 선정하였다. 기본 유리조성의 결정상은 wollastonite이고, 치환된 조성들은 diopside, diopside.tremolite의 혼정이 나타났다. $Na_2O$를 $Li_2O$로 치환한 시편은 열팽창계수가 감소하였지만 CaO를 ZnO로 치환한 시편은 열팽창 계수가 증가하였다. 곡강도에 있어서는 치환에 따라 모두 증가시켰다. 핵행성제로 $ZrO_2와 $CaF_2$를 각각 1~2wt%의 변화를 시켜본 결과 핵형성제 $ZnO_2$와 $CaF_2$가 1:1, 1:2인 시편은 $1000~1050^{\circ}C$온도에서 급격한 결정성장을 보였으며 1:2시편이 가장 낮은 열팽창 계수값을 나타냈다. 곡강도는 모두 $1000~1050^{\circ}C$의 결정화 온도 범위에서 높은 강도를 나타내었다. 결정화에 필요한 활성화 에너지는 Ozawa와 Kissinger식으로 plot하여 각각 55.24kcal/mol과 53.05kcal/mol이다.

• 한국자동차공학회논문집
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• 제21권6호
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• pp.183-194
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• 2013

Liquid urea based SCR has been used in the market to reduce NOx in the exhaust emission of the diesel engine vehicle. This system has several problems at low temperature, which are freezing below $-12^{\circ}C$, solid deposit formation in the exhaust, and difficulties in dosing system at exhaust temperature below $200^{\circ}C$. Also, it is required complicated exhaust packaging equipment and mixer due to supply uniform ammonia concentration. In order to solve these issues, solid urea, ammonium carbonate, and ammonium carbamate are selected as ammonia sources for the application of solid SCR. In this paper, basic research on reaction rate of three ammonia-transporting materials was performed. TGA (Thermogravimetric Analysis) and DTA (Differential Thermal Analysis) tests for these materials are carried out for various heating conditions. From the results, chemical kinetic parameters such as activation energy and frequency factor are obtained from the Arrhenius plot. Additionally, from test results of DSC (Differential Scanning Calorimeter) for these materials, chemical kinetic parameters using the Kissinger method are calculated. Activation energies of solid SCR from this experiment are compared with proper data of literature study, then obtained data of this experiment are used for the design of reactor and dosing system for candidate vehicle.

• 한국재료학회지
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• 제27권10호
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• pp.513-517
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• 2017

An optimum route to fabricate a hybrid-structured W powder composed of nano and micro size powders was investigated. The mixture of nano and micro W powders was prepared by a ball milling and hydrogen reduction process for $WO_3$ and W powders. Microstructural observation for the ball-milled powder mixtures revealed that the nano-sized $WO_3$ particles were homogeneously distributed on the surface of large W powders. The reduction behavior of $WO_3$ powder was analyzed by a temperature programmed reduction method with different heating rates in Ar-10% $H_2$ atmosphere. The activation energies for the reduction of $WO_3$, estimated by the slope of the Kissinger plot from the amount of reaction peak shift with heating rates, were measured as 117.4 kJ/mol and 94.6 kJ/mol depending on reduction steps from $WO_3$ to $WO_2$ and from $WO_2$ to W, respectively. SEM and XRD analysis for the hydrogen-reduced powder mixture showed that the nano-sized W particles were well distributed on the surface of the micro-sized W powders.