• Bulletin of the Korean Chemical Society
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• v.30 no.8
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• pp.1887-1890
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• 2009

• Bulletin of the Korean Chemical Society
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• v.31 no.6
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• pp.1793-1796
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• 2010

• Bulletin of the Korean Chemical Society
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• v.31 no.6
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• pp.1785-1788
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• 2010

• Bulletin of the Korean Chemical Society
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• v.32 no.10
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• pp.3783-3786
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• 2011

• Bulletin of the Korean Chemical Society
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• v.33 no.7
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• pp.2427-2430
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• 2012

• Bulletin of the Korean Chemical Society
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• v.16 no.8
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• pp.742-747
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• 1995

• Journal of the Korean institute of surface engineering
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• v.41 no.6
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• pp.255-263
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• 2008

Generally, deposition mechanism of diamond particle is mainly embedding effect in the kinetic spray process. Accordingly, in spite of high cost, helium gas was employed as process gas to get high diamond fraction in the composite coating. In this study, the deposition behavior of bronze/diamond by kinetic spray process was compared using different process gas (helium and nitrogen). Bare (mean size of $5{\mu}m$, $20{\mu}m$) and nickel coated diamond (mean size of $26{\mu}m$) were deposited on Al 6061-T6 substrate with fixed process temperature and pressure. For comparison with experimental results, plastic deformation behavior of nickel layer was simulated by finite element analysis (using ABAQUS/Explicit 6.7-2). The size, broken ratio, and fraction of diamond in the composite coating were analyzed through scanning electron microscopy and image analysis method. The uniform distribution and deposition efficiency of diamond particles in the coating layer could be achieved by tailoring the physical properties of the feedstock.

• Journal of the Korean Chemical Society
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• v.43 no.1
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• pp.85-91
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• 1999

The second order rate constants for the hydrolysis of substituted phenyl N,N-diethyl-P-benzylphosphonamidates (2,4-$(NO_2)_2$, 4-$NO_2$, 4-CN, 4-Cl, 4-H)in 20% dioxane-water (v/v) have been determined by UV/Vis spectrophotometric method at various temperatures. The activation parameters (Ea, ${\Delta}H^{\neq}$,${\Delta}S^{\neq}$) were calculated from the rate constants and the reaction constant ($\rho$) was also estimated by Hammett equation. The activation entropies of the title reactions show considerably negative values, this result is not consistent with a dissociative mechanism (EA) in which a positive or a slightly negative value of the entropy of activation should be expected. Further, kinetic evidence for an associative mechanism (AE) was obtained from the linear free energy relationship. By the results of kinetic study for the alkaline hydrolysis of substituted phenyl N,N-diethyl-P-benzylphosphonamidates, it may be concluded that these reactions proceed through an associative mechanism.

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.6
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• pp.74-80
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• 2008

A combustion of CAI engine is purely dominated by fuel chemical reactions. In order to simulate the combustion of CAI engine, it should be considered the effect of fuel components and chemical kinetics. So it needs enormous computational power. To overcome this problem reduced problem of needing massive computational power, chemical kinetic mechanism and multi-zone method is proposed here in this paper. A reduced chemical kinetic mechanism for a gasoline surrogate was used in this study for a CAI combustion. This gasoline surrogate was modeled as a blend of iso-octane, n-heptane, and toluene. For the analysis of CAI combustion, a multi-zone method as combustion model for a CAI engine was developed and incorporated into the computational fluid dynamics code, STAR-CD, for computing efficiency. This coupled multi-zone model can calculate 3 dimensional computational fluid dynamics and multi-zoned chemical reaction simultaneously in one time step. In other words, every computational cell interacts with the adjacent cells during the chemical reaction process. It can enhance the reality of multi-zone model. A greatly time-saving and yet still relatively accurate CAI combustion simulation model based on the above mentioned two efficient methodologies, is thus proposed.

• Journal of Digital Convergence
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• v.18 no.12
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• pp.543-548
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• 2020

The purpose of this study is to implement various movements of multiple objects using a small number of power devices in producing a kinetic design, achieving an effect similar to a work comprised of multiple objects controlled using multiple power devices. While it is more typical to control various objects using multiple power devices, the use of multiple devices leads to higher costs and heavier overall weight. In addition, more power is required to operate the multiple power devices. This study applied a mechanism that allows multiple objects to perform various movements using a small number of power devices. The mechanism significantly reduces overall weight and power consumption. In addition, various movements could be expressed by increasing the rows and columns of objects through the use of the camshaft structure that changed the position and shape of the cam and the use of bevel gears. The significance of this study lies in presenting a new method of controlling multiple objects for designers involved in kinetic design.