• Title/Summary/Keyword: Kinetic Method

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Estimation of the Kinetic Energy of Raindrops for Hourly Rainfall Considering the Rainfall Particle Distribution (강우입자분포를 고려한 시강우의 강우에너지 산정 연구)

  • Kim, Seongwon;Jeong, Anchul;Lee, Giha;Jung, Kwansue
    • Journal of the Korean GEO-environmental Society
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    • v.19 no.12
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    • pp.15-23
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    • 2018
  • The occurrence of soil erosions in Korea is mostly driven by flowing water which has a close relationship with rainfalls. The soil eroded by rainfalls flows into and deposits in the river and it polluted the water resources and making the rivers become difficult to be managed. Recently, the frequency of heavy rainfall events that are more than 30 mm/hr has been increasing in Korea due to the influence of climate change, which creating a favourable condition for the occurrence of soil erosion within a short time. In this study, we proposed a method to estimate the distribution of rainfall intensity and to calculate the energy produced by a single rainfall event using the cumulative distribution function that take into account of the physical characteristics of rainfall. The raindrops kinetic energy estimated by the proposed method are compared with the measured data from the previous studies and it is noticed that the raindrops kinetic energy estimated by the rainfall intensity variation is very similar to the results concluded from the previous studies. In order to develop an equation for estimating rainfall kinetic energy, rainfall particle size data measured at a rainfall intensity of 0.254~152.4 mm/hr were used. The rainfall kinetic energy estimated by applying the cumulative distribution function tended to increase in the form of a power function in the relation of rainfall intensity. Based on the equation obtained from this relationship, the rainfall kinetic energy of 1~80 mm/hr rainfall intensity was estimated to be $0.03{\sim}48.26Jm^{-2}mm^{-1}$. Based on the relationship between rainfall intensity and rainfall energy, rainfall kinetic energy equation is proposed as a power function form and it is expected that it can be used in the design of short-term operated facility such as the sizing of sedimentation basin that requires prediction of soil loss by a single rainfall event.

Effect of Hip Adduction Position on the Vastus Medialis Oblique and Vastus Lateralis During Closed Kinetic Chain Exercise in Sitting Posture

  • Cha, Yong-su;Jeon, Hye-seon;Yi, Chung-hwi;Kwon, Oh-yun;Choi, Bo-ram
    • Physical Therapy Korea
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    • v.23 no.2
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    • pp.75-83
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    • 2016
  • Background: Several studies have discussed diverse exercise methods considered to be useful for the selective contraction of the vastus medialis oblique (VMO) muscle for the treatment of patellofemoral pain syndrome. Some studies have reported that exercise methods, including hip adduction, in closed kinetic chain exercises are more effective in terms of the muscle activation of the VMO and the timing of the muscle's initial contraction. We focused on isometric contraction during a closed kinetic chain exercise with hip adduction. Objects: The purpose of this study was to examine muscle activation in the VMO and the vastus lateralis (VL) and the onset time difference between their initial contractions via closed kinetic chain isometric quadriceps femoris exercises including hip adduction. Methods: In total, 36 healthy subjects adopted two hip positions during isometric contraction of the quadriceps femoris in a closed kinetic chain exercise (hip neutral and hip adduction position). Statistical analyses were conducted using a paired t-test (${\alpha}=.05$). Results: Isometric contraction of the quadriceps femoris in a closed kinetic chain exercise caused a greater increase in VMO muscle activity in the hip adduction position [$52.68{\pm}22.21$ percentage of maximal voluntary isometric contraction (%MVIC)]than the hip neutral position ($43.43{\pm}19.85%MVIC$). The onset time difference (VL-VMO) decreased more in the hip adduction position ($-82.14{\pm}34.2ms$) than the hip neutral position ($73.94{\pm}2.94ms$). Conclusion: We recommend this exercise as a clinically useful therapeutic method for patients with patellofemoral pain syndrome due to weakening of the VMO muscle and lateral inclination of the patella.

Simultaneous Kinetic Spectrophotometric Determination of Sulfite and Sulfide Using Partial Least Squares (PLS) Regression

  • Afkhami, Abbas;Sarlak, Nahid;Zarei, Ali Reza;Madrakian, Tayyebeh
    • Bulletin of the Korean Chemical Society
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    • v.27 no.6
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    • pp.863-868
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    • 2006
  • The partial least squares (PLS-1) calibration model based on spectrophotometric measurement, for the simultaneous determination of sulfite and sulfide is described. This method is based on the difference between the rate of the reaction of sulfide and sulfite with Malachite Green in pH 7.0 buffer solution and at 25 ${^{\circ}C}$. The absorption kinetic profiles of the solutions were monitored by measuring the decrease in the absorbance of Malachite Green at 617 nm in the time range 10-180 s after initiation of the reactions with 2 s intervals. The experimental calibration matrix for partial least squares (PLS-1) calibration was designed with 24 samples. The cross-validation method was used for selecting the number of factors. The results showed that simultaneous determination could be performed in the range 0.030-1.5 and 0.030-1.2 $\mu$g m$L ^{-1}$ for sulfite and sulfide, respectively. The proposed method was successfully applied to simultaneous determination of sulfite and sulfide in water samples and whole human blood.

Analysis of Thermal Degradation Process if Commercial Rubber for Environmentally Benign Process (범용고무의 환경친화적 처리를 위한 열분해 공정 해석)

  • 김형진;정수경
    • Journal of environmental and Sanitary engineering
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    • v.15 no.4
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    • pp.123-133
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    • 2000
  • The kinetic analysis was carried out for commercial rubbers such as NR, IR, BR, SBR 1500, and SBR 1700. Kinetic analysis for the commercial rubbers was performed using the thermogravimetric method, with which the activation energies of NR obtained by Kissinger, Friedman, and Ozawa's method were 195.0, 198.3 and 186.3kJ/mol, whereas that of SBR 1500 were 246.4, 247.5 and 254.8kJ/mol, respectively. It was shown that the yield of pyrolytic oil was generally increased with final temperature increasing, yet slightly decreased or increased over $700^{\circ}C$. Considering the effect of heating rate, it was found that the yield of pyrolytic oil was not consistent for each sample. The number average molecular weight of SBR 1500 was in the range of 740~2486. The calorific value of SBR 1500 was 39~40kJ/g, which were made comparative study of the conventional fuel such as kerosene, diesel, light fuel, and heavy fuel. Therefore it was essential that the selection of the suitable kinetic model and the mathematical solution because of the difference in parameters obtained from each method. It was proposed that the range of $600~700^{\circ}C$ in final temperature and high heating rate due to short run time. It was suggested that the pyrolytic oil be available to use to the fuel.

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The study on kinetic value for simulation in fluidized catalytic gasification (유동층에서의 촉매 석탄가스화 공정 모델 모사를 위한 kinetics에 대한 연구)

  • Jang, Dong-Ha;Jeon, Young-Shin;Kim, Hyung-Taek
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.74.1-74.1
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    • 2011
  • As a demand for energy, many studies are increasing about energy resource. One of these resources is coal which reserves of underground. A lot of research to use coal is going on as method of IGCC (Integrated Gasification Combined Cycle). In addition, SNG(Substitute Natural Gas) and IGFC (Integrated Gasification Fuel Cell) are also being developed for fuel & electricity. This technology which uses synthesis gas after gasification is to produce electricity from the Fuel Cell. At this point, important thing is the components of synthesis gas. The main objective is to increase the proportion of methane and hydrogen in synthesis gas. The catalytic gasification is suitable to enhance the composition of methane and hydrogen. In this study, Exxon Predevelopment catalyst gasification study was served as a good reference and then catalytic gasification simulation process is conducting using Aspen Plus in this research. For this modelling, kinetic value should be calculated from Exxon's report which is used for modeling catalytic gasification. Catalytic gasification model was performed by following above method and was analyzed by thermodynamic method through simulation results.

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A New Method of Estimation of Kinetic Parameters for Enzyme-Catalyzed Reactions (酵素觸媒反應의 速度變數決定의 새로운 方法)

  • Suh Junghun
    • Journal of the Korean Chemical Society
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    • v.23 no.2
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    • pp.104-110
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    • 1979
  • A new least square method for analysis of the whole time course of enzyme-catalyzed reactions is presented. This method requires only a programmable calculator with small capacity and is applicable to both uninhibited reactions and reactions inhibited by products or added compounds. This method fits the data to the nonlinear plot of substrate concentration vs. time, and, consequently, estimates the kinetic parameters better than the least square method based on linearly transformed equations.

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Kinetic Spectrophotometric Determination of Trace Amounts of Sulfide

  • Barzegar, Mohsen;Jabbari, Ali;Esmaeili, Majid
    • Bulletin of the Korean Chemical Society
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    • v.24 no.9
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    • pp.1261-1264
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    • 2003
  • A method for the determination of trace amount of sulfide based on the addition reaction of sulfide with methyl green at pH 7.5 and $25{\circ}C$ is described. The reaction is monitored spectrophotometrically by measuring the decrease in absorbance of the dyestuff at 637 nm by the initial rate and fixed time method. The calibration graph is linear in the range 30-1200 ppb. The theoretical limit of detection was 0.014 ppm. Seven replicate analysis of a sample solution containing 0.70 ppm sulfide gave a relative standard deviation of 1.5%. The interfering effects of various ions on sulfide determination have been reported and procedures for removal of interference have been described. The proposed method was applied successfully to the determination of sulfide in tap and wastewater samples.

Kinetic Analysis of Energetic Materials Using Differential Scanning Calorimetry (DSC를 이용한 고에너지 물질의 반응속도식 추출과 활용)

  • Kim, Yoocheon;Park, Jungsoo;Yang, Seungho;Park, Honglae;Yoh, Jai-Ick
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.1
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    • pp.33-41
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    • 2015
  • The kinetic analysis of energetic materials using Differential Scanning Calorimetry (DSC) is proposed. Friedman Isoconversional method is applied to DSC experiment data and AKTS software is used for analysis. The proposed kinetic scheme has considerable advantage over the standard method based on One-Dimenaionl Time to Explosion (ODTX). Reaction rate and product mass fraction simulation are conducted to validate extracted kinetic scheme. Also a slow cook-off simulation is implemented on $B/KNO_3$ for validating the applicability of the extracted kinetics scheme to a practical thermal experiment.

Kinetic Theory Analysis for Thin-Film Bearings (기체분자운동론을 이용한 박막 베어링 해석)

  • Chung Chan Hong
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2004.11a
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    • pp.162-170
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    • 2004
  • A kinetic theory analysis is used to study the ultra-thin gas flow field in gas slider hearings. The Boltzmann equation simplified by a collision model is solved by means of a finite difference approximation with the discrete ordinate method. Calculations are made for the flow field inside stepped and straight slider bearings. The results are compared well with those from the DSMC method. Special attention has been paid to the effect of the pressure build-up in front of a hearing, which has never been assessed before. It has been shown that the pressure build-up at the inlet is about $4.5\%$ of the operating pressure and the resulting load capacity is about $25\%$ higher for the case considered in the present study.

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A study on the non-linear analysis of the elastic catenary cable considering kinetic damping (동적감쇠를 고려한 탄성 현수선 케이블의 비선형 해석에 관한 연구)

  • 한상을;정명채;이진섭
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2000.10a
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    • pp.331-338
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    • 2000
  • In this paper, a non-linear finite element formulation for the spatial cable-net structures is simulated and using this formulation, the characteristics of structural behaviors for the elastic catenary cable are examined In the simulating procedure for the elastic catenary cable, nodal forces and tangential stiffness matrices are derived using catenary parameters of the exact solutions by a governing differential equation of catenary cable, cable self-weights and unstressed cable length. Dynamic Relaxation Method that considers kinetic damping is used for the structure analysis and Newton Raphson Method is used to verify the accuracy of solutions. In the analysis of two dimensional cable, the results obtain from the elastic catenary elements are shown more accurate than does of truss elements and in the case of spatial cable-net structures, Dynamic Relaxation Method is more stable to be converged than Newton Raphson Method.

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