• Bulletin of the Korean Chemical Society
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• v.30 no.2
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• pp.355-362
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• 2009

The chemical modification of multi-wall carbon nanotubes (MWNTs) is an emerging area in material science. In the present study, hydroxyl functionalized oxovanadium(IV) Schiff-base; N,N'-bis(4-hydroxysalicylidene)-ethylene-1, 2-diamineoxovanadium(IV), [VO($(OH)_2$-salen)]; has been covalently anchored on modified MWNTs. The new modified MWNTs ([VO($(OH)_2$-salen)]-MWNTs]) have been characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron (XPS), UV-Vis, Diffuse reflectance (DRS), FT-IR spectroscopy and elemental analysis. The analytical data indicated a composition corresponding to the mononuclear complex of tetradentate Schiff-base ligand. The characterization of the data showed the absence of extraneous complex, retention of MWNTs and covalently anchored on modified MWNTs. Liquid-phase oxidation of cyclohexane with $H_2O_2$ to a mixture of cyclohexanone, cyclohexanol and cyclohexane-1,2-diol in $CH_3$CN have been reported using oxovanadium(IV) Schiff-base complex covalently anchored on modified MWNTs as catalysts. This catalyst is more selective toward cyclohexanol formation.

• Advances in nano research
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• v.8 no.1
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• pp.69-82
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• 2020

In this study, the free and forced vibration analysis of micro sandwich plate with porous core layer and magneto-electric face sheets based on modified couple stress theory and first order shear deformation theory under simply supported boundary conditions is illustrated. It is noted that the core layer is composed from balsa wood and also piezo magneto-electric facesheets are made of BiTiO₃-CoFe₂O₄. Using Hamilton's principle, the equations of motion for micro sandwich plate are obtained. Also, the Navier's method for simply support boundary condition is used to solve these equations. The effects of applied voltage, magnetic field, length to width ratio, thickness of porous to micro plate thickness ratio, type of porous, coefficient of porous on the frequency ratio are investigated. The numerical results indicate that with increasing of the porous coefficient, the non-dimensional frequency increases. Also, with an increase in the electric potential, the non-dimensional frequency decreases, while and with increasing of the magnetic potential is vice versa.

• Smart Structures and Systems
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• v.25 no.3
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• pp.337-343
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• 2020

In this paper, we focused on the self-healing concrete using new nano-capsules. Three types of nano-capsules with respect to availability, high strength and temperature tolerance are used; type 1 is URF and polyethylene (PE) as shell and nano titanium oxide (TiO₂) as core, type 2 is URF and PE as shell and nano silica oxide (SiO₂) as core, type 3 is PE as shell and nano silica oxide (SiO₂) as core. The concrete samples mixed by nano-capsules with three percents of 0.5, 1 and 1.5. Based on experimental tests and the compressive strength of samples, the URF-PE-SiO₂ is selected for additional tests of compressive strength before and after recovery, ultrasonic test, ion chlorine and water penetration depths. After careful investigation, it is concluded that the optimum value of URF-PE-SiO₂ nano-capsules is 0.5% since leads to higher compressive strength, ultrasonic test, ion chlorine and water penetration depths.

• Steel and Composite Structures
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• v.33 no.1
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• pp.93-109
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• 2019

In the present study, vibration analysis of double bonded micro sandwich cylindrical shells with saturated porous core and carbon/boron nitride nanotubes (CNT/BNNT) reinforced composite face sheets under multi-physical loadings based on Cooper-Naghdi theory is investigated. The material properties of the micro structure are assumed to be temperature dependent, and each of the micro-tubes is placed on the Pasternak elastic foundations, and mechanical, moisture, thermal, electrical, and magnetic forces are effective on the structural behavior. The distributions of porous materials in three distributions such as non-linear non-symmetric, nonlinear-symmetric, and uniform are considered. The relationship including electro-magneto-hydro-thermo-mechanical loadings based on modified couple stress theory is obtained and moreover the governing equations of motion using the energy method and the Hamilton's principle are derived. Also, Navier's type solution is also used to solve the governing equations of motion. The effects of various parameters such as material length scale parameter, temperature change, various distributions of nanotube, volume fraction of nanotubes, porosity and Skempton coefficients, and geometric parameters on the natural frequency of double bonded micro sandwich cylindrical shells are investigated. Increasing the porosity and the Skempton coefficients of the core in micro sandwich cylindrical shell lead to increase the natural frequency of the structure. Cylindrical shells and porous materials in the industry of filters and separators, heat exchangers and coolers are widely used and are generally accepted today.

• Structural Engineering and Mechanics
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• v.71 no.5
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• pp.485-502
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• 2019

In this research, the nonlinear static, buckling and vibration analysis of viscoelastic micro-composite beam reinforced by various distributions of boron nitrid nanotube (BNNT) with initial geometrical imperfection by modified strain gradient theory (MSGT) using finite element method (FEM) are presented. The various distributions of BNNT are considered as UD, FG-V and FG-X and also, the extended rule of mixture is used to estimate the properties of micro-composite beam. The components of stress are dependent to mechanical, electrical and thermal terms and calculated using piezoelasticity theory. Then, the kinematic equations of micro-composite beam using the displacement fields are obtained. The governing equations of motion are derived using energy method and Hamilton's principle based on MSGT. Then, using FEM, these equations are solved. Finally the effects of different parameters such as initial geometrical imperfection, various distributions of nanotube, damping coefficient, piezoelectric constant, slenderness ratio, Winkler spring constant, Pasternak shear constant, various boundary conditions and three material length scale parameters on the behavior of nonlinear static, buckling and vibration of micro-composite beam are investigated. The results indicate that with an increase in the geometrical imperfection parameter, the stiffness of micro-composite beam increases and thus the non-dimensional nonlinear frequency of the micro structure reduces gradually.

• Geomechanics and Engineering
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• v.18 no.2
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• pp.215-224
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• 2019

Excavation of long tunnels by shielded TBMs is a safe, fast, and efficient method of tunneling that mitigates many risks related to ground conditions. However, long-distance tunneling in great depth through adverse geological conditions brings about limitations in the application of TBMs. Among various harsh geological conditions, squeezing ground as a consequence of tunnel wall and face convergence could lead to cluttered blocking, shield jamming and in some cases failure in the support system. These issues or a combination of them could seriously hinder the performance of TBMs. The technique of excavation has a strong influence on the tunnel response when it is excavated under squeezing conditions. The Golab water conveyance tunnel was excavated by a double-shield TBM. This tunnel passes mainly through metamorphic weak rocks with up to 650 m overburden. These metamorphic rocks (Shales, Slates, Phyllites and Schists) together with some fault zones are incapable of sustaining high tangential stresses. Prediction of the convergence, estimation of the creeping effects and presenting strategies to overcome the squeezing ground are regarded as challenging tasks for the tunneling engineer. In this paper, the squeezing potential of the rock mass is investigated in specific regions by dint of numerical and analytical methods. Subsequently, several operational solutions which were conducted to counteract the challenges are explained in detail.

• Computers and Concrete
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• v.23 no.5
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• pp.361-376
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• 2019

In this research, bending analysis of a micro sandwich skew plate with isotropic core and piezoelectric composite face sheets reinforced by carbon nanotube on the elastic foundations are studied. The classical plate theory (CPT) are used to model micro sandwich skew plate and to apply size dependent effects based on modified strain gradient theory. Eshelby-Mori-Tanaka approach is considered for the effective mechanical properties of the nanocomposite face sheets. The governing equations of equilibrium are derived using minimum principle of total potential energy and then solved by extended Kantorovich method (EKM). The effects of width to thickness ratio and length to width of the sandwich plate, core-to-face sheet thickness ratio, the material length scale parameters, volume fraction of CNT, the angle of skew plate, different boundary conditions and types of cores on the deflection of micro sandwich skew plate are investigated. One of the most important results is the reduction of the deflection by increasing the angle of the micro sandwich skew plate and decreasing the deflection by decreasing the thickness of the structural core. The results of this research can be used in modern construction in the form of reinforced slabs or stiffened plates and also used in construction of bridges, the wing of airplane.

• Smart Structures and Systems
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• v.26 no.6
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• pp.721-733
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• 2020

The present study investigates the employing of piezoelectric patches in active control of a sandwich plate. Indeed, the active control and optimal patch distribution on this structure are presented together. A sandwich plate with honeycomb core and composite reinforced by carbon nanotubes in facesheet layers is considered so that the optimum position of actuator/sensor patches pair is guaranteed to suppress the vibration of sandwich structures. The sandwich panel consists of a search space which is a square of 200 × 200 mm with a numerous number of candidates for the optimum position. Also, different dimension of square and rectangular plates to obtain the optimal placement of piezoelectric actuator/senor patches pair is considered. Based on genetic algorithm and LQR, the optimum position of patches and fitness function is determined, respectively. The present study reveals that the efficiency and performance of LQR control is affected by the optimal placement of the actuator/sensor patches pair to a large extent. It is also shown that an intelligent selection of the parent, repeated genes filtering, and 80% crossover and 20% mutation would increase the convergence of the algorithm. It is noted that a fitness function is achieved by collection actuator/sensor patches pair cost functions in the same position (controllability). It is worth mentioning that the study of the optimal location of actuator/sensor patches pair is carried out for different boundary conditions of a sandwich plate such as simply supported and clamped boundary conditions.

• Advances in nano research
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• v.10 no.3
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• pp.235-251
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• 2021

In the current study, the free vibrational behavior of a Porous Micro (PM) beam which is integrated with Functionally Graded Piezoelectric (FGP) layers with initial curvature is considered based on the two trigonometric shear deformation theories namely SSDBT and Tan-SDBT. The structure's mechanical properties are varied through its thicknesses following the given functions. The curved microbeam is exposed to electro-mechanical preload and also is rested on a Pasternak type of elastic foundation. Hamilton's principle is used to extract the motion equations and the MCST is used to capture the size effect. Navier's solution method is selected as an analytical method to solve the motion equations for a simply supported ends case and by validating the results for a simpler state with previously published works, effects of different important parameters on the behavior of the structure are considered. It is found that although increasing the porosity reduces the natural frequency, but enhancing the volume fraction of CNTs increasing it. Also, by increasing the central angle of the curved beam the vibrations of the structure increases. Designing and manufacturing more efficient smart structures such as sensors and actuators are of the aims of this study.

• Earthquakes and Structures
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• v.22 no.3
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• pp.277-287
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• 2022

The ancient underground cities are a collection of self-supporting spaces that have been manually excavated in the soil or rock in the past. Because these structures have a very high cultural value due to their age, the study of their stability under the influence of natural hazards, such as earthquakes, is very important. In this research, while introducing the underground city of Ouyi Nushabad located in the center of Iran as one of the largest man-made underground cities of the old world, the analysis of dynamic stability is performed. For this purpose, the dynamic stress-displacement analysis has been performed through numerical modeling using the finite element software PLAXIS. At this stage, by simulating the Khorgo earthquake as one of the large-scale earthquakes that occurred in Iran, with a magnitude of 6.9 on the Richter scale, dynamic analysis by time history method has been performed on three selected sections of underground spaces. This study shows that the maximum amount of horizontal and vertical dynamic displacement is 12.9 cm and 17.7 cm, respectively, which was obtained in section 2. The comparison of the results shows that by increasing the cross-sectional area of the excavation, especially the distance between the roof and the floor, in addition to increasing the amount of horizontal and vertical dynamic displacement, the obtained maximum acceleration is intensified compared to the mapping acceleration applied to the model floor. Therefore, preventive actions should be taken to stabilize the excavations in order to prevent damage caused by a possible earthquake.