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검색결과 565건 처리시간 0.025초

터보냉동기의 HCFC-123 누출에 대한 수치해석 연구 (Numerical Study on the HCFC-123 Leak in Turbo Chiller by using CFD)

  • 서회경;송세욱;황양인;하현철
    • 한국가스학회지
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    • 제18권5호
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    • pp.85-90
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    • 2014
  • 대용량의 공기조화용으로 널리 사용되는 터보냉동기는 냉매로 HCFC-123 가스를 주로 사용하며, HCFC-123은 CFC계 프레온의 대체 냉매제로 독성은 낮으나 환기가 원활하지 않는 밀폐공간이나 작업공간에서 산소결핍으로 인한 질식재해를 유발할 수 있는 것으로 보고되고 있다. 본 연구에서는 2011년 대형할인마트 기계실 내부 터보냉동기 냉매 누출로 인해 작업자 4명이 질식 등의 사유로 사망한 재해 사례를 대상으로 전산유체역학을 이용하여 HCFC-123 누출에 따른 산소농도를 예측함으로써 프레온 가스 누출사고에 대한 원인을 조사하고 대응책을 제시하여 동종 재해의 재발 방지에 도움이 되고자 한다.

반도체 제조 공정에서 발생 가능한 부산물 (Exposure Possibility to By-products during the Processes of Semiconductor Manufacture)

  • 박승현;신정아;박해동
    • 한국산업보건학회지
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    • 제22권1호
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    • pp.52-59
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    • 2012
  • Objectives: The purpose of this study was to evaluate the exposure possibility of by-products during the semiconductor manufacturing processes. Methods: The authors investigated types of chemicals generated during semiconductor manufacturing processes by the qualitative experiment on generation of by-products at the laboratory and a literature survey. Results: By-products due to decomposition of photoresist by UV-light during the photo-lithography process, ionization of arsine during the ion implant process, and inter-reactions of chemicals used at diffusion and deposition processes can be generated in wafer fabrication line. Volatile organic compounds (VOCs) such as benzene and formaldehyde can be generated during the mold process due to decomposition of epoxy molding compound and mold cleaner in semiconductor chip assembly line. Conclusions: Various types of by-products can be generated during the semiconductor manufacturing processes. Therefore, by-products carcinogen such as benzene, formaldehyde, and arsenic as well as chemical substances used during the semiconductor manufacturing processes should be controlled carefully.

공기 중 석면표준시료를 이용한 전처리 방법 비교 연구 (Comparative study of clearing methods for air-borne asbestos analysis)

  • 이광용;신정아;정지연;이인섭;박두용
    • 한국산업보건학회지
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    • 제21권2호
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    • pp.99-102
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    • 2011
  • Objectives: Acetone/triacetine method for clearing cellulose ester membrane (CEM) filter has been a popular method for air-borne asbestos analysis. However, as a weakness of this method, it is time consuming to analyses asbestos samples after sampling. Crystalclear method can be used to analyses asbestos samples promptly after sampling. Although a strength of crystal clear method exists, there was little valid studied for the method. This study was conducted to compare acetone/triacetine method with crystalclear one for analysing asbestos sample. Methods: Test samples made in three different concentration ranges(low, medium and high concentration) were analysed by phase contrast microscopy after acetone/triacetine and crystalclear method treatment respectively. Results: We did not find statistical difference in analysed results between two methods, which were conducted in three different concentrations ranges. Conclusions: We concluded that crystalclear method can be used as clearing method for air-borne asbestos analysis instead of acetone/triacetine method.

석면분석 정도관리용 표준시료 개발연구 I - 석면분석 정도관리용 표준시료 제조장치 개발 및 시료제조 방법 확립 - (Development of Asbestos Quality Control Sample for Proficiency Analytical Testing 1 - Development of Manufacturing Apparatus and Sample Preparing Procedure for Asbestos Quality Control Sample -)

  • 이광용;이종한;정시정;박두용
    • 한국산업보건학회지
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    • 제19권2호
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    • pp.81-87
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    • 2009
  • Final purpose of this study was designed to develop the quality control(QC) sample for proficiency analytical testing of asbestos. This study consisted of two parts; first, development of manufacturing apparatus and sample preparing procedure for asbestos quality control(QC) sample: second, validation of the QC samples made by our developed method as asbestos proficiency analytical testing sample. The main results of the first part research are as followed We developed the apparatus for manufacturing the asbestos QC sample, consisted of filter hold, filter holder manifolder, vacuum system, and vacuum pump. The most proper filter of making the QC samples was a cellulose ester membrane filter with 25 mm diameter, pore size 0.8 um. And we presented the optimal procedure for preparing the asbestos QC sample by using the developed apparatus. We will verify the manufactured asbestos QC samples by this method, and present the validation results to confirm the reliability as a asbestos QC sample in next paper.

Comparative Study on the EC50 Value in Single and Mixtures of Dimethylformamide, Methyl Ethyl Ketone, and Toluene

  • Kim, Ki-Woong;Won, Yong Lim;Park, Dong Jin;Kim, Doh-Hee;Song, Kwan Young
    • Toxicological Research
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    • 제30권3호
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    • pp.199-204
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    • 2014
  • The aim of this research was to improve our understanding of human toxicity due to exposure to DMF, MEK, or TOL individually as compared to exposure to DMF-MEK or DMF-TOL mixtures, by comparing $EC_{50}$ values as well as the morphological changes in HepG2 cells treated with these substances. We found that there was marked cell necrosis in the groups treated with mixtures than in those treated with the compounds alone, and that the amount of cell death and the $EC_{50}$ value were more dependent on MEK and TOL than on DMF. Moreover, analysis of the changes in effective concentration curves revealed that MEK had an antagonistic effect on the human toxicity of DMF, whereas TOL had a synergistic effect. Accordingly, these results suggest that in workplaces involved in the manufacture of synthetic leather, mixtures of DMF and TOL should be avoided as much as possible in order to minimize environmental toxicity and protect the health of the workers.

직무의 질적 수준이 건강수준과 직무만족도에 미치는 영향 (The impact of job quality on health status and job satisfaction)

  • 김기식;이경용;조윤호
    • 대한안전경영과학회지
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    • 제17권3호
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    • pp.185-193
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    • 2015
  • There are so many definition of good work but generally job quality can be useful to analyze the good work. Good work may include some factors about health or working environment. This paper was planned to investigate the level of job quality in Korean employees. Especially comparison of health status between low an high job quality can be analyzed. Korean Working Conditions Survey was used. The various job characteristics were categorized into 6 component of job quality using factor analysis. Statistically mean difference test and cross-tabulation analysis were used to identify the difference of health status and distribution of the level of job quality. The result has shown the different distribution of the level of job quality by the economic sectors and occupations statistically significant. The positive cases of all of six components of job quality was 2.1% of Korean employees and the negative cases of all six components of job quality was 1.5%. The subjective general health status was correlated with job quality but work-related stress was negatively correlated with the level of job quality. This study was heuristic one, more depth analysis will be needed to identify the relationship and causation of job quality and health status.

AcciMap, STAMP, FRAM을 이용한 반응기 세척 작업 중 화재 사고 분석 (Analysis of a Fire Accident during a Batch Reactor Cleaning with AcciMap, STAMP and FRAM)

  • 서동현;배계완;최이락;한우섭
    • 한국안전학회지
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    • 제36권4호
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    • pp.62-70
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    • 2021
  • Representative systematic accident analysis methods proposed so far include AcciMap, STAMP, and FRAM. This study used these three techniques to analyze a fire accident case that occurred during routine manufacturing work in a domestic chemical plant and compared the results. The methods used different approaches to identify the cause of the accident, but they all highlighted similar causal factors. In addition to technical issues, the three accident analysis methods identified factors related to safety education, risk assessment, and the operation of the process safety management system, as well as management philosophy and company culture as problems. The AcciMap and STAMP models play complementary roles because they use hierarchical structures, while FRAM is more effective in analyses centered on human and organizational functions than in technical analyses.

고속도로 톨게이트 요금수납원의 작업환경 유해인자 노출평가 (Exposure Assessment of Cashiers at Expressway Tollbooths)

  • 박해동;강준혁;김준범
    • 한국산업보건학회지
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    • 제31권1호
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    • pp.13-21
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    • 2021
  • Objectives: The purpose of this study was to evaluate the exposures of cashiers who work at expressway tollbooths. Methods: We measured temperature(temp.), relative humidity(RH), and contaminants with direct reading instruments at ten expressway toll gate in September 2015. Elemental carbon was collected on the quartz filters and analyzed with an OCEC analyzer. Results: The average levels for temp., RH, carbon monoxide, carbon dioxide, dust(PM10), and black carbon were respectively 24.6~27.8℃, 32.3~65.3%, 0.5~1.2 ppm, 456~559 ppm, 12~111 ㎍/㎥, and 3.1~10.1 ㎍/㎥ at each tollbooth. The concentrations of elemental carbon within the tollbooth(1.8~7.2 ㎍/㎥) were lower than outdoors(2.5~10.0 ㎍/㎥), but exhibited a high correlation(r2=0.855). The exposure levels for carbon monoxide, black carbon, and elemental carbon in the tollbooths were significantly higher than the offices. The concentrations of black carbon and elemental carbon showed a high correlation(r2=0.756). Conclusions: The levels of contaminants were below the occupational exposure limits in the expressway tollbooth. There were ventilation and air conditioning systems in the booths, but it is necessary to maintain and use the systems properly.

직업적인 크롬 노출이 혈중 Homocysteine, Folate와 Vitamin B12 농도에 미치는 영향 (Effects of Occupational Chromium Exposure on Plasma Homocysteine, Folate and Vitamin B12 Concentration)

  • 김기웅;김규상;박인정;강성규;오성수;정효석;장성근
    • 한국산업보건학회지
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    • 제16권3호
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    • pp.245-253
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    • 2006
  • We evaluated the relations among exposure and urinary levels of Cr, folate, vitamin $B_{12}$ and Hcy levels in the workers chronically exposure to Cr. Subjects were 104 male employees, 65 workers exposed to Cr in 9 electroplating plants and 39 office workers who had never been occupationally exposed to hazardous substances including Cr. The geometric mean(GM) of Cr in workplace was $0.069{\pm}0.101mg/m^3$ and urinary Cr was $0.483{\pm}0.394mg/g$ creatinine and airborne Cr concentration was significantly correlated to the urinary concentration of Cr(r=0.900, p=0.000). The geometric mean concentration of urinary Cr in control group was $0.301{\pm}0.255mg/g$ creatinine. In comparing the workers exposed to Cr with controls, significantly higher mean plasma levels were found of Hcy($11.3{\pm}4.9$ vs $9.4{\pm}4.7{\mu}mol/{\ell}$, p=0.05), but vitamin $B_{12}$ levels ($181.8{\pm}68.7$ vs $216.0{\pm}64.3nmol/{\ell}$, p=0.01) was significantly decreased. Hcy concentrations correlated positively with airborne Cr concentrations(r=0.287, p=0.004) and urinary Cr concentrations(r=0.244, p=0.015) but folate concentrations correlated negatively with airborne(r=-0.234, p=0.020) and urinary Cr concentrations(r=-0.640, p=0.090), respectively. No correlations were observed between vitamin $B_{12}$, airborne and urinary Cr concentrations. Also, Hcy concentrations correlated positively with vitamin $B_{12}$(r=0.295, p=0.0020 and negatively with folate concentrations(r=-0.196, p=0.046). The various biological(i.e. age and serum indicates) or lifestyle factors(i.e. medication, smoking, alcohol and coffee intake), also taken into account as potential confounders, did not influence the correlations found. Thus, this study found evidence that Cr might be associated with elevated plasma levels of Hcy. Furthermore, elevated plasma levels of Hcy were significantly associated with folate and vitamin $B_{12}$ concentration.

수직 배관 내의 농도변화에 따른 분진폭발 특성 (Characteristics of Flames Propagating Through Combustible Particles Concentration in a Vertical Duct)

  • 한우섭;한인수;최이락;이정석;이수희
    • Korean Chemical Engineering Research
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    • 제49권1호
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    • pp.41-46
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    • 2011
  • 본 연구에서는 수직 배관 내에서 석송자 농도 변화에 따른 분진화염전파 특성을 상세히 조사하였다. 이를 위해 디지털비디오카메라와 PIV(Particle Image Velocimetry)를 사용하여 높이 120 cm, 단면 12 cm의 정방형 수직 덕트 내를 전파하는 분진화염의 입자거동을 해석하였다. 그 결과, 배관 내에 동일 평균농도의 분진운이 존재하는 경우 상방전파보다 하방 전파에 의한 화염전파속도가 크며 농도 약 300 g/$m^3$까지의 경우에는 분진농도가 증가할수록 그 비율이 증가하였다. 후방 화염(Post flame)은 배관 측벽과 화염면 사이를 통과하여 전파화염 후방에 유입된 미연소 입자의 발화에 의한 것으로 배관의 밀폐조건과 관계없이 발생하였다. 또한 후방 화염의 발생 빈도는 농도의 증가와 함께 증가하는 것을 알았다.