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Fabrication and Properties of SiC Candle Filter by Vacuum Extrusion and Ramming Process (II) (진공 압출성형 및 래밍성형 공정에 의한 탄화규소 캔들 필터 제조 및 특성 (II))

  • Han, In-Sub;Seo, Doo-Won;Kim, Se-Young;Hong, Ki-Seog;Woo, Sang-Kuk;Kim, Young-Wook
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.515-523
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    • 2010
  • Porous SiC candle filter preforms were fabricated by extrusion and ramming process. To fabricate SiC candle filter preform, commercially available F180 mesh ($85\;{\mu}m$) $\alpha$-SiC powder and $44\;{\mu}m$ mullite, $CaCO_3$ powder were used as the starting materials. The candle type preforms were fabricated by vacuum extrusion and ramming process, and sintered at $1400^{\circ}C$ 2 h in air atmosphere. Corrosion test of the sintered candle filter specimens as forming method was performed at $600^{\circ}C$ for 2,400 h in simulated IGCC syngas atmosphere. The effect of forming method on mechanical properties, pore distribution, microstructure and crystalline phase was investigated.

Fabrication and Properties of the SiC Candle Filter by Vacuum Extrusion and Ramming Process (진공 압출성형 및 래밍성형 공정에 의한 탄화규소 캔들 필터 제조 및 특성)

  • Shin, Myung-Kwan;Han, In-Sub;Seo, Doo-Won;Kim, Se-Young;Woo, Sang-Kuk;Lee, Seoung-Won;Kim, Young-Wook
    • Journal of the Korean Ceramic Society
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    • v.46 no.6
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    • pp.662-667
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    • 2009
  • Porous SiC candle filter preforms were fabricated by extrusion and ramming process. To fabricate SiC candle filter preform, commercially available 85 ${\mu}m\;{\alpha}-$-SiC powder and 44 ${\mu}m$ mullite, CaC$O_3$ powder were used as the starting materials. The candle type preforms were fabricated by vacuum extrusion and ramming process, and sintered at $1400{^{\circ}C}$ 2 h in air atmosphere. The effect of forming method on porosity, density, strength (flexural and compressive strength) and microstructure was investigated. Also, corrosion test of the sintered candle filter specimens as forming method was performed at $600{^{\circ}C}$ in IGCC syngas atmosphere. The sintered SiC filter which was formed by ramming process has more higher density and exhibit higher strength than extruded filter. Its maximum density and 3-point bending strength were 2.00 g/$cm^3$ and 45 MPa, respectively.

The Operation Characteristics of a Sea Water Source Heat Pump System (해수열원 히트펌프 시스템의 운전특성)

  • Chang, Ki-Chang;Baik, Young-Jin;Ra, Ho-Sang;Kim, Ji-Young;Lee, Jae-Hoon
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.1353-1357
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    • 2008
  • A sea water source cascade heat pump was designed and tested in this study. The system was designed to perform a single stage operation in summer, as well as a cascade operation in winter to ensure the high temperature lift. A steady-state simulation model was developed to analyze and optimize its performance. The simulation results show that the R717 exhibits best performance among combinations considered in this study. A R410A also exhibits the highest performance among HFCs with the smallest compressor displacement. A 15-RT R410A-R134a pilot system was installed in the 5-story commercial building at Samcheok City by the East Sea. A scroll type R410A compressor, a reciprocating type R134a compressor, plate type condenser/ evaporator/ cascade heat exchanger and two electronic expansion valves were used to build a pilot. A titanium plate type heat exchanger is also used for the heat exchanging with a sea water. The heat source/sink water is supplied from the well below the seashore in the depth of 5 m. In the initial test of the system, supply water temperature was rising up to $67^{\circ}C$ using a sea water heat source of $9^{\circ}C$, while an ambient temperature was $4.5^{\circ}C$.

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A Study on The Operation Characteristics of 2-Stage Compression Heat Pump using Treated sewage (하수처리수를 이용한 2단 압축 열펌프 시스템의 운전특성에 관한 연구)

  • Kim, Ji-Young;Baik, Young-Jin;Lee, Young-Soo;Chang, Ki-Chang;Ra, Ho-sang
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.299-303
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    • 2008
  • The treated sewage temperature is about $5^{\circ}C$ lower in summer and $5{\sim}10^{\circ}C$ higher in winter than ambient air. It can be used heat pump heat source and is good heat source on high performance of heat pump. In this study, to develop 100RT 2-stage compression heat pump use treated sewage water heat source and system applies to sewage disposal plant. Although heat pump is better performance, the large temperature difference between load and source makes the performance degradation of a heat pump. To solve this problem screw 2-stage compression is considered. The experiment was focused on the system operating performance variations over supply water and treated sewage water a temperature in the field. The results show that system of heating performance is higher then general heat pump and is enough to supply a hot water of $70^{\circ}C$.

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Synthesis and Characterization of Sulfonated Poly (Arylene ether Sulfone) Multi-Block Copolymer for PEMFC Application (고분자연료전지용 설폰산화 폴리아릴렌에테르설폰 멀티블록공중합체의 합성 및 특성 분석)

  • Ahn, Jinju;Choi, Young-Woo;Yang, Tae-Hyun;Kim, Chang-Soo;Bae, Byungchan
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.5
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    • pp.461-467
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    • 2012
  • Multi-block sulfonated poly (arylene ether sulfone) (SPES) membranes were synthesized by post-sulfonation and its properties characterized. Two types of oligomers, F-terminated and OH-terminated telechelic oligomers, were synthesized by controlling the feed ratio of dihydroxyl- and difluoro-monomers. Their number of repeating unit (X and Y) was analyzed by GPC and $^1H$ NMR. Copolymerization with F-terminated and OH-terminated telechelic oligomers via nucleophilic aromatic substitution, gave high-molecular-weight multi-block PESs. Each block length was controlled to have different values with X5Y10, X10Y10, X20Y10 and X20Y20. Successful polymerization and its successful sulfonation was confirmed by GPC and $^1H$ NMR. RH dependence of proton conductivity of multi-block SPES membranes was comparable to that of Nafion 212 at high RH conditions.

A Review on R&D and Commercialization of Oil Recovery from Waste Plastics by Pyrolysis (폐합성수지(廢合成樹脂)류의 열분해(熱分解) 유화(油化) 기술(技術) 동향(動向))

  • Shin, Dae-Hyun;Nho, Nam-Sun;Kim, Sung-Soo;Kim, Kwang-Ho;Jeon, Sang-Gu
    • Resources Recycling
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    • v.19 no.1
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    • pp.3-12
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    • 2010
  • Recently, the waste energy utilization has become the main interest in energy industries, due to high oil prices, the low carbon, green growth policy and the RPS (Renewable Portfolio Standards) of our government. Therefore, energy guzzling companies such as district heating companies, textile industries are replacing energy to RDP/RPF. Especially, a lot of big companies are carrying out survey to commercialize the waste plastics pyrolysis technologies developed in Korea. In this paper, status of the pyrolysis technology of Korea were reviewed overall including basis of technology, waste plastics resources, research & development, and commercialization.

Study on a Separator for the All-vanadium Redox Flow Battery (바나듐 레독스-흐름 전지용 격막에 관한 연구)

  • Lee, Sang-Ho;Kim, Joeng-Geun;Choi, Sang-Il;Hwang, Gab-Jin;Jin, Chang-Soo
    • Membrane Journal
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    • v.19 no.2
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    • pp.129-135
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    • 2009
  • The cation exchange membrane using the block co-polymer of polysulfone and polyphenylenesulfidesulfone was prepared for a separator of all-vanadium redox flow battery. The membrane property of the prepared cation exchange membrane was measured. The thermal stability of the prepared cation exchange analyzed by TG showed a more stable than that of Nafion117. The lowest measured membrane resistance, equilibrated in 1mol/L $H_2SO_4$ aqueous solution, $0.96{\cdot}cm^2$ at 3 cc of CSA (chlorosulfuricacid) which was introduction agent of ion exchange group. Electrochemical property of all-vanadium redox flow battery using the prepared cation exchange membrane was measured. Electromotive force in 100% of state of charge was 1.4 V which was that of all-vanadium redox flow battery, and cell resistance in charge and discharge at each state of charge had a low value compared with that of all-vanadium redox flow battery using Nafion117.

Fabrication of a-Si:H/c-Si Hetero-Junction Solar Cells by Dual Hot Wire Chemical Vapor Deposition (양면동시증착 열선-CVD를 이용한 a-Si:H/c-Si 이종접합 태양전지 제조)

  • Jeong, Dae-Young;Song, Jun-Yong;Kim, Kyung-Min;Lee, Hi-Deok;Song, Jin-Soo;Lee, Jeong-Chul
    • Korean Journal of Materials Research
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    • v.21 no.12
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    • pp.666-672
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    • 2011
  • The a-Si:H/c-Si hetero-junction (HJ) solar cells have a variety of advantages in efficiency and fabrication processes. It has already demonstrated about 23% in R&D scale and more than 20% in commercial production. In order to further reduce the fabrication cost of HJ solar cells, fabrication processes should be simplified more than conventional methods which accompany separate processes of front and rear sides of the cells. In this study, we propose a simultaneous deposition of intrinsic thin a-Si:H layers on both sides of a wafer by dual hot wire CVD (HWVCD). In this system, wafers are located between tantalum wires, and a-Si:H layers are simultaneously deposited on both sides of the wafer. By using this scheme, we can reduce the process steps and time and improve the efficiency of HJ solar cells by removing surface contamination of the wafers. We achieved about 16% efficiency in HJ solar cells incorporating intrinsic a-Si:H buffers by dual HWCVD and p/n layers by PECVD.

Effects of NO and $SO_2$ on Growth of $Highly-CO_2-Tolerant$ Microalgae

  • Lee, Jung-Hwa;Lee, Jin-Suk;Shin, Chul-Seung;Park, Soon-Chul;Kim, Seung-Wook
    • Journal of Microbiology and Biotechnology
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    • v.10 no.3
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    • pp.338-343
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    • 2000
  • The growth capabilities of three $highly-CO_2-tolerant$ microalgae under high concentrations of $CO_2$ were compared for their tolerance to $SO_2$ and NO, the major inhibitory compounds present in flue gases. Although all strains showed good growth with 15% $CO_2$, Chlorella KR-1 exhibited the most desirable properties for $CO_2$ fixation among the strains compared. While Chlorella sp. HA-1 exhibited the best tolerance to NO among the other strains tested, Chlorella sp. KR-1 showed higher tolerance to $SO_2$ than the other two strains tested.

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Effect on Stratification due to Diffuser Shape in a Thermal Storage Tank (온도 성층축열조 가시화 및 실증분석에 관한 고찰)

  • Lee Young-Soo;Lee Sang-Nam;Kim Jong-Ryul
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.11
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    • pp.990-997
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    • 2005
  • The stratified effect was investigated with three different types of diffuser shape in a thermal storage tank with variation of diffuser diameter, velocity, Froude number etc. Its effect was estimated by the degree of stratification. No matter of diffuser diameter and shape, the degree of stratification was the best as the Froude number gets closer to 1. In the case of a curved diffuser, when its diameter is a quarter of tank diameter and ejection velocity in a diffuser is approximately 0.2 m/s, the Froude number was almost 1. In the case of a flatted diffuser, when ejection velocity was 0.05 m/s, the Froude number was 1.5. Both cases which Froude number were nearer 1, showed the good degree of stratification.