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Direct Ethanol Fuel Cell (DEFC) Fabricated with Ceramic Membrane (세라믹 멤브레인 활용 직접 에탄올 연료전지)

  • Jeong, Jae Geun;Yun, Young Hoon
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.4
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    • pp.419-424
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    • 2014
  • Direct ethanol fuel cell has been fabricated with ceramic membrane. A porous silicon carbide (SiC) membrane having approximately 30% porosity has been applied for a direct ethanol proton exchange membrane (DE-PEM) fuel cell. A horizontal type cell having Pt ($18mg/cm^2$) catalyst layer on both side of the ceramic membrane was used for the demonstration test. The ethanol oxidation based-fuel cell stack showed very high voltage (1.289V) and measurable current level (68mA) even though at room temperature.

Comparative Thermodynamic Analysis of Organic Rankine Cycle and Ammonia-Water Rankine Cycle (유기랭킨사이클과 암모니아-물 랭킨사이클의 열역학적 성능의 비교 해석)

  • KIM, KYOUNG HOON;KIM, MAN-HOE
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.5
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    • pp.597-603
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    • 2016
  • In this paper a comparative thermodynamics analysis is carried out for organic Rankine cycle (ORC) and ammonia-water Rankine cycle (AWRC) utilizing low-grade heat sources. Effects of the working fluid, ammonia concentration, and turbine inlet pressure are systematically investigated on the system performance such as mass flow rate, pressure ratio, turbine-exit volume flow, and net power production as well as the thermal efficiency. Results show that ORC with a proper working fluid shows higher thermal efficiency than AWRC, however, AWRC shows lower mass flow rate of working fluid and lower pressure ratio of expander than ORC.

Characterization of Pitch Derived from Petroleum Residue and Coal-tar (석유계 잔사유 및 coal-tar의 핏치 개질 특성)

  • KIM, JIHONG;KIM, HYEONGGI
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.5
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    • pp.612-619
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    • 2016
  • Pitch synthesis reaction was studied based on the effect for chemical composition of feedstock. Feedstock was selected as pyrolyzed fuel oil (PFO) and coal-tar (CT), which are by-products in petroleum and steel industry. Pitch was prepared at $420^{\circ}C$ for 180 minutes on atmospheric pressure by thermal treatment. Thermal stability and softening point (SP) of the prepared pitches were investigated and their molecular weight distribution was analyzed by MALDI-TOF. PFO has various aliphatic compounds and coal-tar has high aromaticity with 3 wt% of primary quinoline insolubles. The thermal property of PFO was enhanced with polymerization reaction during the thermal treatment with increased molecular weight range. But CT was inferior to PFO because of side reaction by hetero elements. CTP was appeared molecular weight by 0~200 m/z.

Effects of Linear Alkylbenzene Sulfonate on Hydrogen Fermentation of Food Waste (음식물류 폐기물의 수소 발효 시 linear alkylbenzene sulfonate의 영향)

  • LEE, CHAE-YOUNG;CHOI, JAE-MIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.5
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    • pp.510-516
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    • 2016
  • This study examines the effects of linear alkylbenzene sulfonate on hydrogen fermentation of food waste. The hydrogen production rate was similar with different linear alkylbenzen sulfonate (LAS) concentrations. The maximum hydrogen yield increased with increasing LAS concentration. The highest maximum hydrogen yield was $0.550{\pm}0.005mol$ H2/mol hexose at LAS for 5.52 mg/L. But the maximum hydrogen yield decreased above LAS for 11.05 mg/L. The concentration of acetate in control reactor was increased, but it decreased with increasing LAS concentration in other reactors.

Utilization and Quality Standard of Fast Pyrolysis Bio-Oil (급속 열분해 바이오 오일의 활용 및 품질기준)

  • PARK, JO YONG;DOE, JIN-WOO
    • Transactions of the Korean hydrogen and new energy society
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    • v.31 no.2
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    • pp.223-233
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    • 2020
  • Fast pyrolysis is one of the most promising technologies for converting biomass to liquid fuels. Pyrolysis bio-oil can replace petroleum-based fuels used in various thermal conversion devices. However, pyrolysis bio-oil is completely different from petroleum fuels. Therefore, in order to successfully use pyrolysis bio-oil, it is necessary to understand the fuel characteristics of pyrolysis bio-oil. This paper focuses on fuel characteristics and upgrading methods of pyrolysis bio-oil and discusses how these fuel characteristics can be applied to the use of pyrolysis bio-oils. In addition, the fuel quality standards of fast pyrolysis bio-oil were examined.

Estimation of the Amount of Electric Power Saved in the Carbon Dioxide Liquefaction Process using LNG Cold Heat (LNG 냉열을 활용한 이산화탄소 액화공정에서 절감되는 전력량의 산출)

  • LEE, JIHWAN;CHO, JUNGHO
    • Transactions of the Korean hydrogen and new energy society
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    • v.31 no.2
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    • pp.259-264
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    • 2020
  • In this study, comparison study has been performed between two-stage compression and a vapor-recompression refrigeration cycle and a liquefaction using LNG cold heat. When using a first method using two-stage compression and a refrigeration cycle, at least three compressors are required, however when using LNG cold heat, no compressor is required since carbon dioxide can be pumped after condensing with the heat exchange with -160℃ of LNG. Through this study, we can save more than one hundred million KRW annually by using LNG cold heat instead of using gas compression and refrigeration cycle.

An Analysis of Wind Data for Development of Energy Independent Village (에너지 자립 마을 개발을 위한 공력 실증 데이터 분석)

  • ALI, SAJID;JANG, CHOON-MAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.6
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    • pp.614-620
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    • 2019
  • In the present study, the wind characteristics were analyzed according to the time averages to evaluate the performance of small wind turbines required for the development of energy independent village. Measuring data of wind speed were recorded between January 2016 and April 2016 every second. Experimental data is averaged out using 5, 10, 15, 20 and 30 minute time steps. Throughout the experimental data analysis, 5 minutes averaged data is used to analyze the performance of the wind turbine, because it produces a minimum turbulence intensity in wind speed. The measuring power of the wind turbine is less than the designed value due to the unsteady nature wind of sudden changes in magnitude of wind speed and wind angle. Detailed wind conditions are also analysed using two variable Weibull probability density functions.

A Study on Safety Improvement for Mobile Hydrogen Refueling Station by HAZOP Analysis (위험과 운전 분석을 통한 이동식 수소충전소 안전성 향상에 관한 연구)

  • BYUN, YOON-SUP
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.5
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    • pp.299-307
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    • 2021
  • In order to expand the supply of hydrogen vehicles, the first thing to be done is to build an infrastructure to supply hydrogen. There are fixed and mobile types of hydrogen refueling stations that can supply hydrogen. Mobile hydrogen refueling stations have the advantage of supplying hydrogen to two or three areas, so the introduction of mobile hydrogen refueling stations is considered at the initial stage of hydrogen vehicle dissemination. However, mobile hydrogen refueling stations have greater risks than fixed hydrogen refueling stations due to the hazard associated with movement and intensive installation of facilities in vehicle, so stricter design standards to lower the risk must be applied. Therefore, in this study, basic data for establishing safety standards for mobile hydrogen refueling stations were proposed by suggesting improvements such as the location of emergency shutoff valves, the number of gas detectors etc., using HAZOP analysis.

A Study on the Initial Performance Degradation of Hydrogen-Fueled Ceramic Fuel Cell with Atomic Layer-Deposited Thin-Film Electrolyte (수소연료를 이용하는 원자층증착 박막전해질 세라믹연료전지의 초기성능 저하에 관한 연구)

  • JI, SANGHOON
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.5
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    • pp.410-416
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    • 2021
  • The initial electrochemical performance of ceramic fuel cell with thin-film electrolyte was evaluated in terms of peak power density ratio, open circuit voltage ratio, and activation/ohmic resistance ratios at 500℃. Hydrogen and air were used as anode fuel and cathode fuel, respectively. The peak power density ratio reduced as ~17% for 40 minutes, which rapidly decreased in the early stage of the performance evaluation but gradually decreased. The open circuit voltage ratio decreased with respect time; however, its time behavior was remarkably different with the reduction behavior of the peak power density ratio. The activation resistance ratio increased as ~15% for 40 minutes, which was almost similar with the time behavior of the peak power density ratio.

Techno-Economic Analysis and Life-Cycle Assessment for the Production of Hydrogen from Biogas (바이오가스 기반 수소 생산공정에 대한 경제성 및 환경성 분석)

  • KIM, HYUNWOO;BAEK, YOUNGSOON;WON, WANGYUN
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.5
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    • pp.417-429
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    • 2021
  • Due to fossil fuel depletion and environmental pollution, H2 production from organic waste has received an increased attention. In this study, we present an integrated process for the H2 production from biogas and evaluate the economic feasibility and sustainability via rigorous techno-economic analysis (TEA) and life-cycle assessment (LCA). Through the TEA, we determine the minimum H2 selling price using discounted cash flow analysis and investigate the main cost drivers. The environmental impact of the proposed process is quantified via LCA.