• Title/Summary/Keyword: KCL-2

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Analysis on the Distribution Environmental Loads of the Parcel Packaging Delivered by Means of E-Commerce in Korea (전자상거래 유통물류 패키징의 국내 물류환경부하 분석)

  • Suh, Sanguk;Lim, Mijin;Oh, Jae Young
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.23 no.2
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    • pp.103-108
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    • 2017
  • The amount of delivered parcels have been increasing according to the change and expansion of consumption pattern through e-commerce, and they are required to minimize breakout or failure under the delivery. In this study, we measured and analyzed the distribution environment data (vibration and impact) occurred in the packaging, which were prepared with 5 types by the weight and dimension, distributed from Seoul to Busan in Korea by 2 parcel delivery service companies through e-commerce order. Date showed the parcels had 3-5 times of drop impact and 0.3-0.7 m of drop height on average, and 0.8 Grms of vibration acceleration from equivalent equation to the vertical direction. The significant gap in service quality was not found between 2 parcel delivery service companies. This study is expected to be useful for designing the suitable packaging in order to enhance safe transportation of the delivered packaging, and furthermore useful for developing Korean testing method for Field-to-Lab simulation.

Cellular Pathways in Agonist-induced Gallbladder Muscle Contraction in the Cat (고양이의 담낭근 수축에 있어서 세포내 기전)

  • Rhim, Byung-Yong;Kim, Chi-Dae;Kim, Dong-Heon;Biancani, Piero;Behar, Jose
    • The Korean Journal of Pharmacology
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    • v.32 no.1
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    • pp.67-74
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    • 1996
  • Cholecystokinin octapeptide (CCK-8), acetylcholine (ACh) and KCl caused a dose dependent contraction in muscle cells enzymatically digested from cat gallbladder. Maximal contraction was obtained at concentration of $10^{-9}M$ for CCK-8, $10^{-5}M$ for ACh and 20mM for KCl. CCK-8 induced contraction was unaffected in calcium free physiological salt solution (PSS) and was completely blocked by strontium substitution for calcium (p<0.001). In contrast, KCl evoked contraction was blocked in calcium free PSS (p<0.01) but was unaffected by strontium replacement of calcium. The contraction elicited by ACh was only slightly reduced in calcium free PSS (p<0.05) and was unaltered by strontium. Muscle cells permeabilized with saponin contracted in response to inositol 1,4.5-trisphosphate $(IP_3)$ and CCK-8. The contraction was blocked by the calmodulin antagonist CGS 9343B (p<0.001), whereas heparin completely blocked the effect of $IP_3$ (p<0.001). The protein kinase C (PKC) antagonist H7 had no effect on either agonist. We conclude that CCK-8 induced gallbladder muscle contraction is mediated by $IP_3$ dependent intracellular calcium release from intracellular stores and a calmodulin dependent pathway; ACh may utilize both extracellular and intracellular calcium. KCl causes muscle contracrion through influx of extracellular calcium and a calmodulin independent machanism.

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A Study of the Surface Tension of Some Electrolytic Solutions (몇가지 電解質溶液의 表面張力에 관한 硏究)

  • Sakong, Yull;Hwang, Jung-Euy;Son, Moo-Yong
    • Journal of the Korean Chemical Society
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    • v.8 no.1
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    • pp.1-4
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    • 1964
  • Relative surface tensions of aqueous solutions of KCl, KI and NaI have been measured at 25$^{circ}C$(30$^{circ}C$ for KCl) over a concentration range of 0.0001 to 3M solution. It was observed that there was a minimum in the surface tension-concentration curve for the extremely dilute solutions. Appearance of the minimum has been reported for the other salt solutions so far reported. At moderate and high concentration, these three salts increase the surface tension of water almost linearly as concentration increased, and behaved as a typical "capillary inactive substance", whereas they acted as a capillary active substance in very dilute solutions. Since the Onsager-Samaras equation for the surface tension as a function did not agree with the experimental data, the following empirical equations for the whole concentration range used were obtained. ${\sigma}_r\;=\;1\;+\;0.00072{\sqrt{c}}\;-\;0.0011c\;+\;0.023c^2\; for\;KCl\;at\;30^{\circ}C$ ${\sigma}_r\;=\;1\;+\;0.0077{\sqrt{c}}\;-\;0.0015c\;+\;0.024c^2\;for\;KI\;at\;25^{\circ}C$ ${\sigma}_r\;=\;1\;+\;0.00011{\sqrt{c}}\;-\;0.0090c\;+\;0.077c^2\;for\;NaI\;at\;25^{\circ}C$

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Fundamental Study on a Distillation Separation of a LiCl-KCl Eutectic Salt from Rare Earth Precipitates (희토류 침전물로부터 LiCl-KCl 공융염의 증류 분리에 관한 기초연구)

  • Yang, Hee-Chul;Eun, Hee-Chul;Kim, In-Tae
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.8 no.1
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    • pp.65-70
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    • 2010
  • The distillation rate on LiCl-KCl eutectic salt under different vacuums from 0.5-50 mmHg was first investigated by using both a non-isothermal and a isothermal thermogravimetric (TG) analysis. Based on the non-isothermal TG data, distillation rate equations as a function of the temperature could be derived. Calculated flux by these model flux equations was in agreement with the distillation rate obtained from isothermal TG analysis. A distillation rate of $10^{-4}-10^{-5}$ mole $cm^{-2}sec^{-1}$ is obtainable at temperatures less than 1300K and vacuums of 0.5-50 mmHg. About a 99% salt distillation efficiency was obtained after an hour at a temperature above 1150 K under 50 mmHg in a small scale distillation test system. An increase in the vaporizing surface area is relatively effective for removing residual salt in the remaining particles, when compared to that for the vaporizing time. Over 99.95% of total distillation efficiency was obtained for a 1-h distillation operation by increasing the inner surface area from $4.52cm^2$ to $12.56cm^2$.

The Influence of Electrolytes on the Dyeing Properties of Congo Red on Cotton Fibers (Congo Red로 염색한 면섬유의 염색성에 미치는 전해질의 영향)

  • Lee, Young-Hee;Park, Joon-Myung;Sung, Woo-Kyung;Kim, Kyung-Hwan
    • Textile Coloration and Finishing
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    • v.3 no.2
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    • pp.34-42
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    • 1991
  • The effects of electrolyte on dyeing properties of cotton fiber with Congo Red have been studied at 90, 70 and $40^{\circ}C$. Each dyeing carried into an infinite bath with $1\times10^{-4}$ mol/l of Congo Red and with various concentration of electrolytes. The results obtained from this study were as follow; 1. The equilibrium adsorption of dye $(C_\infty)$ values decreased with increasing dyeing temperature, $C_\infty$ values increased in the order KCl>NaCl>LiCl. 2. The values of apparent diffusion coefficients $(D_a)$ increased with increasing dyeing temperature, but $D_a$ values decreased in the order KCl$D_a$ values decreased with increasing electrolyte concentration. 4. Effect of electrolytes decreased with increasing dyeing temperature. 5. The values of standard affinities of dyeing $(-\triangle\mu^{\circ})$, the standard heats of dyeing $(-\triangleH^{\circ})$, and the standard entropies $(-\triangleS^{\circ})$, increased in the order KCl>NaCl>LiCl. 6. Equilibrium adsorption isotherm curve were Freundlich type, and in the Equation y=a.x$^{n}$ , the values of a and n increased in the order KCl>NaCl>LiCl. 7. The value of $-\triangle\mu^{\circ}$, $-\triangleH^{\circ}$, and $-\triangleS^{\circ}$, decreased with increasing electrolyte concentration.

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Electrochemical Behavior of Li-B Alloy Anode - Liquid Cadmium Cathode (LCC) System for Electrodeposition of Nd in LiCl-KCl

  • Kim, Gha-Young;Shin, Jiseon;Kim, Tack-Jin;Shin, Jung-Sik;Paek, Seungwoo
    • Journal of the Korean Electrochemical Society
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    • v.18 no.3
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    • pp.102-106
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    • 2015
  • The performance of Li-B alloy as anode for molten salt electrolysis was firstly investigated. The crystalline phase of the prepared Li-B alloy was identified as $Li_7B_6$. The potential profile of Li-B alloy anode was monitored during the electrodeposition of $Nd^{3+}$ onto an LCC (liquid cadmium cathode) in molten LiCl-KCl salt at $500^{\circ}C$. The potential of Li-B alloy was increased from -2.0 V to -1.4 V vs. Ag/AgCl by increasing the applied current from 10 to $50mA{\cdot}cm^{-2}$. It was found that not only the anodic dissolution of Li to $Li^+$ but also the dissolution of the atomic lithium ($Li^0$) into the LiCl-KCl eutectic salt was observed, following the concomitant reduction of $Nd^{3+}$ by the $Li^0$ in Li-B alloy. It was expected that the direct reduction could be restrained by maintaining the anode potential higher that the deposition potential of neodymium.

A STUDY ON THE CORROSION OF AMALGAMS IN CHLORIDE SOLUTION (Chloride용액에서의 아말감부식에 대한 연구)

  • Um, Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.23 no.1
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    • pp.502-514
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    • 1998
  • The purpose of this study is to observe the corrosion characteristcs of four dental amalgams(CAULK FINE CUT, CAULK SPHERICAL, DISPERSALLOY, TYTIN) and to determine a function of chloride concentration through the anodic polarization curve obtained by using a potentiostat. After each amalgam alloy and Hg being triturated, the triturated mass was inserted into the cylinderical metal mold, and condensed by hydrolic pressure. Each specimen was removed from the metal mold. 24 hours after condensation, specimens were polished with the emery paper and stored at room temperature for 6 months. The anodic polarization curves were employed to compare the corrosion behaviours of the amalgam m KCl and KCl-NaCl solution, which had chlonde concentration of 0.4 g/l, 0.8 g/l, 1.2 gil, and 1.6 gil at $37^{\circ}C$ with 3-electrode potentiostat. After the immersion of specimen in electrolyte for 1 hour, the potential scan was begun. The potential scan range was - 1500mV ~+800mV(vs. S.C.E.) in the working electrode and the scan rate was 50mV/sec. The results were as follows, 1. The corrosion potential. the potential of anodic current peak, and transpassive potential in the solution of high chloride concentration shifted to more cathodic direction than those in the solution of low concentration, and the current density in the solution of high chloride concentration was higher than that in the solution of low concentration. 2. The corrosion potential, the potential of anodic current peak, and transpassive potential for CAULK FINE CUT amalgam were the most cathodic among the others, and the current density were the highest among the others. 3. In the solution of low chloride concentration, the corrosion potential, the potential of anodic current peak, and transpassive potential for DISPERSALLOY were the most anodic among the others, however in the solution of high chloride concentration, those for TYTIN were the most anodic among the others. 4. The anodic polarization curve for CAULK SPHERICAL was similar to that for high copper amalgams.

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The Fission Yeast Gene Encoding Monothiol Glutaredoxin 5 Is Regulated by Nitrosative and Osmotic Stresses

  • Kim, Hong-Gyum;Park, Eun-Hee;Lim, Chang-Jin
    • Molecules and Cells
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    • v.20 no.1
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    • pp.43-50
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    • 2005
  • Glutaredoxin (Grx) is a small, heat-stable redox protein acting as a multi-functional glutathione (GSH)-dependent disulfide oxidoreductase. We have cloned the monothiol Grx5 gene from the genomic DNA of the fission yeast Schizosaccharomyces pombe. It has 1,904 bp, with one intron, and encodes a putative protein of 146 amino acids with a molecular mass of 16.5 kDa. Recombinant Grx5 produced functional Grx in S. pombe cells. NO-generating sodium nitroprusside (SNP, 1.0 and 2.0 mM) and potassium chloride (KCl, 0.2 and 0.5 M) increased the synthesis of ${\beta}$-galactosidase from a Grx5-lacZ fusion gene, and transcription of Grx5 was also enhanced by SNP and KCl. Synthesis of ${\beta}$-galactosidase from the Grx5-lacZ fusion was lower in Pap1-negative TP108-3C cells than in wild type KP1 cells, and when Pap1 was overproduced in KP1 cells, the level of ${\beta}$-galactosidase increased. We also found that Pap1 is involved in the induction of Grx5 by SNP and KCl. S. pombe Grx5 may play a crucial role in responses to nitrosative and osmotic stresses.

Electrochemical Properties of Polypyrrole-Glucose Oxidase Enzyme Electrode with Different Dopants (Polypyrrole-Glucose Oxidase 효소전극의 배위자 크기에 따른 전기화학적 특성)

  • 김현철;구할본
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.2
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    • pp.141-146
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    • 2002
  • We synthesized polypyrrole (PPy) by electrolysis of the pyrrole monomer solution containing support electrolyte, KCl and/or p-toluene sulfonic acid sodium salt (p-TS). The electrochemical behavior, was investigated using cyclic voltammetry and AC impedance. In the case of using electrolyte p-TS, the oxidation potential of the PPy was about -02 V vs Ag/AgCl reference electrode, while the potential was about 0 V for using electrolyte KCl. The falloff of the oxidation potential gave a sign of an improvement in the electron hopoing mechanism on the backbone. The AC impedance plot gave a hint of betterment of mass transport. PPy doped with p-TS improved in mass transport or diffusion. That was because the PPy doped with p-TS was more porous than PPy with KCl. We attained an effect of good kinetic parameters, in the case of PP-GOx enzyme electrodes doped with p-TS, which were determined by 58 mmol dm$\^$-3/ for apparent Michaelis constant and by 581 ㎂ for maximum current respectively.

Elucidation of Electrode Reaction of EuCl3 in LiCl-KCl Eutectic Melts through CV Curve Analysis

  • Kim, Tack-Jin;Jung, Yong-Ju;Kim, Si-Hyung;Paek, Seung-Woo;Ahn, Do-Hee
    • Bulletin of the Korean Chemical Society
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    • v.32 no.3
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    • pp.863-866
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    • 2011
  • The electrode reaction of $Eu^{3+}$ in a LiCl-KCl eutectic melt has been re-examined using cyclic voltammetry (CV). In this work, for the first time, the kinetic details of a $Eu^{3+}/Eu^{2+}$ redox system have been completely elucidated, along with the thermodynamic property, through a curve fitting applied to experimental CV data, which were obtained in a wide scan rate range of 0.5 to 10 V/s. The simulated results showed an excellent fit to all experimental CV data simultaneously, even though the curve fittings were performed within a large dynamic range of initial transfer coefficient values, formal potentials, and standard rate constants. As a result, a proper formal potential, transfer coefficient, and standard rate constant for the $Eu^{3+}/Eu^{2+}$ redox system were successfully extracted using the CV curve fitting.